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Nonlinear spectroscopy and microscopy techniques are ubiquitous in a wide range of applications across physics and biology. However, these usually rely on high-powered pulsed laser systems. A promising alternative is to exploit entangled…

Entangled two-photon absorption (ETPA) could form the basis of nonlinear quantum spectroscopy at very low photon fluxes, since, at sufficiently low photon fluxes, ETPA scales linearly with the photon flux. When different pairs start to…

Quantum Physics · Physics 2023-12-04 Frank Schlawin

When a low flux of time-frequency-entangled photon pairs (EPP) illuminates a two-photon transition, the rate of two-photon absorption (TPA) can be enhanced considerably by the quantum nature of photon number correlations and frequency…

The phenomenon of Entangled Two-Photon Absorption (ETPA) presents a persistent controversy in the literature, evidenced by a wide disparity in the reported values for the $\sigma_E$ cross-sections. Much of this discrepancy is attributed to…

Quantum Physics · Physics 2025-12-02 Pablo Yepiz-Graciano , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

Entangled two-photon absorption (ETPA) has recently become a topic of lively debate, mainly due to the apparent inconsistencies in the experimentally-reported ETPA cross sections of organic molecules. In this work, we provide a thorough…

Entangled two-photon absorption (ETPA) may be a viable technique to continuously drive an excited state population in plasma for high-bandwidth spectroscopy measurements of localized plasma turbulence or impurity density. Classical…

Recent investigations suggest that the use of non-classical states of light, such as entangled photon pairs, may open new and exciting avenues in experimental two-photon absorption spectroscopy. Despite several experimental studies of…

We introduce a method for determining the sensitivity of any given Entangled Two-Photon Absorption (ETPA) measurement. By modeling all signal and noise contributions to the measurement, we derive a single numerical value that describes the…

Quantum Physics · Physics 2025-12-23 René Pollmann , Franz Roeder , Christine Silberhorn , Benjamin Brecht

Recently, different experimental methods intended to detect the entangled two-photon absorption (ETPA) phenomenon in a variety of materials have been reported. The present work explores a different approach on which the ETPA process is…

Quantum Physics · Physics 2023-04-26 Freiman Triana-Arango , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

Entangled two-photon absorption spectroscopy (TPA) has been widely recognized as a powerful tool for revealing relevant information about the structure of complex molecular systems. However, to date, the experimental implementation of this…

Quantum Physics · Physics 2019-07-10 Roberto de J. León-Montiel , Jiří Svozilík , Juan P. Torres , Alfred B. U'Ren

While two-photon absorption (TPA) and other forms of nonlinear interactions of molecules with isolated time-frequency-entangled photon pairs (EPP) have been predicted to display a variety of fascinating effects, their potential use in…

Excitation with entangled photon pairs may lead to an increase in the efficiency of two-photon absorption at low photon flux. The corresponding process, entangled two-photon absorption (E2PA), has been investigated in numerous theoretical…

Two-photon absorption (TPA) and other nonlinear interactions of molecules with time-frequency-entangled photon pairs (EPP) has been predicted to display a variety of fascinating effects. Therefore, their potential use in practical…

Quantum Physics · Physics 2021-09-15 Michael G. Raymer , Tiemo Landes , Andrew H. Marcus

Entangled photons exhibit non-classical light-matter interactions that create new opportunities in materials and molecular science. For example, in entangled two-photon absorption, the intensity-dependence scales linearly as if only one…

Optics · Physics 2020-05-15 Szilard Szoke , Hanzhe Liu , Bryce P. Hickam , Manni He , Scott K. Cushing

Recently, different experimental methods to investigate the entangled two-photon absorption (ETPA) process in a variety of materials have been reported. The present work reports on a different approach on which the ETPA process is detected…

Quantum Physics · Physics 2022-02-15 Freiman Triana-Arango , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

It has been proposed that entangled two-photon absorption (E2PA) can be observed with up to 10 orders of magnitude lower photon flux than its classical counterpart. However, there is a significant controversy regarding the magnitude of this…

We closely replicated and extended a recent experiment ("Spatial properties of entangled two-photon absorption," Phys. Rev. Lett. 129, 183601, 2022) that reportedly observed enhancement of two-photon absorption rates in molecular samples by…

Quantum Physics · Physics 2024-04-26 Tiemo Landes , Brian J. Smith , Michael G. Raymer

Recently different experimental schemes have been proposed to study the elusive phenomenon of entangled two-photon absorption (ETPA) in nonlinear materials. The attempts to detect ETPA using transmission-based schemes have led to results…

Quantum Physics · Physics 2023-10-13 Freiman Triana-Arango , Roberto Ramírez-Alarcón , Gabriel Ramos-Ortiz

Two-photon excited fluorescence (TPEF) is a standard technique in modern microscopy but still affected by photo-damage of the probe. It was proposed that TPEF can be enhanced by using entangled photons, but has proven to be challenging.…

Quantum Physics · Physics 2013-10-17 Andreas Jechow , Michael Seefeldt , Henning Kurzke , Axel Heuer , Ralf Menzel

The phenomena of subthreshold photoemission and absorption under coherent and entangled-photon-pair illumination are reviewed, and the generation and properties of entangled-photon pairs are surveyed. Three prominent forms of subthreshold…

Quantum Physics · Physics 2026-05-05 Malvin Carl Teich , Mark C. Booth , Francesco Lissandrin , Bahaa E. A. Saleh
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