Related papers: The absolute seawater entropy: Part I. Definition
The possible distinction between inanimate and living matter has been of interest to humanity since thousands of years. Clearly, such a rich question can not be answered in a single manner, and a plethora of approaches naturally do exist.…
Water is one of the key chemical elements in planetary structure modelling. Due to its complex phase diagram, equations of state cover often only parts of the pressure - temperature space needed in planetary modelling. We construct an…
The entropy change of a (non-equilibrium) Markovian ensemble is calculated from (1) the ensemble phase density $p(t)$ evolved as iterative map, $p(t) = \mathbb{M}(t) p(t- \Delta t)$ under detail balanced transition matrix $\mathbb{M}(t)$,…
Entropy is one of the key thermodynamic variables reflecting changes in the state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this…
Fisher information, Shannon information entropy and Statistical Complexity are calculated for the interface of a normal metal and a superconductor, as a function of the temperature for several materials. The order parameter $\Psi({\bf r})$…
1. Strong and weak notions of erasure are distinguished according to whether the single erasure procedure does or does not leave the environment in the same state independently of the pre-erasure state. 2. Purely thermodynamic…
A typical strategy of realizing an adiabatic change of a many-particle system is to vary parameters very slowly on a time scale $t_\text{r}$ much larger than intrinsic equilibration time scales. In the ideal case of adiabatic state…
A revised phase diagram for water shows three distinct fluid phases. There is no continuity of liquid and gas and no critical point on Gibbs density surface. A liquid state, water, spans all temperatures. A thermodynamic rigidity function,…
Statistical mechanics relies on the complete though probabilistic description of a system in terms of all the microscopic variables. Its object is to derive therefrom static and dynamic properties involving some reduced set of variables.…
The static energy encodes all possible information about the thermodynamics and potential energy (and all related forces) of stratified geophysical fluids. In this paper, we develop a systematic methodology, called static energy…
In order to study as a whole a wide part of entropy measures, we introduce a two-parameter non-extensive entropic form with respect to the $h$-derivative, which generalizes the conventional Newton--Leibniz calculus. This new entropy,…
The principal methods for the definition of thermodynamic entropy are discussed with special reference to those developed by Carath\'eodory, the Keenan School, Lieb and Yngvason, and the present authors. An improvement of the latter method…
Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…
A new five point potential for liquid water, TIP5P/2018, is presented along with the techniques used to derive its charges from ab initio per-molecule electrostatic potentials in the liquid phase using the split charge equilibration (SQE)…
We calculate the off-equilibrium hydrostatic pressure for the O(N) Phi^{4} theory to the leading order in 1/N. The present paper, the first of a series, concentrates on the calculation of pressure in the non-equilibrium but translationally…
Antarctic meltwater is expected to increase throughout the coming centuries and impact sea level, ocean circulation, and the coupled climate evolution. This motivates interest in understanding the ocean response to Antarctic freshwater…
The problems of conditional entropy's definition and the formula to compute conditional entropy are analyzed from various perspectives, and the corrected computing formula is presented. Examples are given to prove the conclusion that…
The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…
All the existing entropy stable (ES) schemes for relativistic hydrodynamics (RHD) in the literature were restricted to the ideal equation of state (EOS), which however is often a poor approximation for most relativistic flows due to its…
We formulate, under general conditions, the problem of maximisation of the total entropy of the system, assumed to be in a composable form, for fixed total value of the constrained quantity. We derive the general form of the composability…