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Binding energies calculated from using the Bethe-Salpeter equation in the simplest ladder approximation significantly differ from those obtained in the non-relativistic standard instantaneous approximation. While they should a priori be…

Nuclear Theory · Physics 2007-05-23 G. Le Gorrec , B. Desplanques

The proposed method of the free energy calculation is based on the approximation of the energy distribution in the microcanonical ensemble by the Gaussian distribution. We hope that our approach will be effective for the systems with…

Disordered Systems and Neural Networks · Physics 2015-06-23 Boris Kryzhanovsky , Leonid Litinskii

We present a simple yet accurate numerical approach to compute the free energy of binding of multivalent objects on a receptor-coated surface. The method correctly accounts for the fact that one ligand can bind to at most one receptor. The…

Soft Condensed Matter · Physics 2016-05-05 Nicholas B. Tito , Stefano Angioletti-Uberti , Daan Frenkel

The molecular distributions obtained from canonical Monte Carlo simulations can be used to find an approximate interaction energy. This serves as the basis of a method for estimating the binding free energy for a ligand to a protein which…

Chemical Physics · Physics 2007-05-23 Charles F. F. Karney , Jason E. Ferrara , Clay D. Spence

A method is presented for calculating binding energies and other properties of extended interacting systems using the projected density of transitions (PDoT) which is the probability distribution for transitions of different energies…

Strongly Correlated Electrons · Physics 2009-10-31 Roger Haydock

Solvation free energies are efficiently predicted by molecular density functionnal theory (MDFT) if one corrects the overpressure introduced by the usual homogeneous reference fluid approximation. Sergiievskyi et al. [Sergiievskyi et al.,…

Statistical Mechanics · Physics 2015-11-17 Volodymyr Sergiievskyi , Guillaume Jeanmairet , Maximilien Levesque , Daniel Borgis

Based on the reduced density matrix method, we compare two different approaches to calculate the dynamics of the electron transfer in systems with donor, bridge, and acceptor. In the first approach a vibrational substructure is taken into…

Quantum Physics · Physics 2009-10-31 M. Schreiber , D. Kilin , U. Kleinekathoefer

We present a simulation protocol that allows for efficient sampling of the degrees of freedom of a solute in explicit solvent. The protocol involves using a non-equilibrium umbrella sampling method, in this case the recently developed…

Chemical Physics · Physics 2010-03-16 Volodymyr Babin , Celeste Sagui

The static-exchange model (SEM) and the modified static-exchange model (MSEM) recently introduced by Ray [1] is applied to study the elastic collision between two hydrogen-like atoms when both are in ground states considering the system as…

Atomic Physics · Physics 2016-06-29 Hasi Ray

We consider the interacting Bose gas in the thermodynamic limit in a large box in $\R^d$ at positive temperature $1/\beta\in(0,\infty)$ with particle density $\sim\rho\in(0,\infty)$. We follow a path-integral approach and adopt from \cite…

Probability · Mathematics 2026-04-17 Wolfgang König

The interacting quantum Bose gas is a random ensemble of many Brownian bridges (cycles) of various lengths with interactions between any pair of legs of the cycles. It is one of the standard mathematical models in which a proof for the…

Probability · Mathematics 2022-01-14 Orphée Collin , Benedikt Jahnel , Wolfgang König

The thesis consists of two projects. In the first project, we present a software that analyses RNA secondary structures and compares them. The goal of this software is to find the differences between two secondary structures (experimental…

Biomolecules · Quantitative Biology 2012-12-18 Asaf Farhi

In the molecular dynamics calculations for the free energy of ions and ionic molecules, we often encounter wet charged molecular systems where electrical neutrality condition is broken. This causes a problem in the evaluation of…

Biological Physics · Physics 2020-07-15 Ryo Urano , Wataru Shinoda , Noriyuki Yoshii , Susumu Okazaki

A recently developed statistical mechanical Quasi-Chemical Theory (QCT) has led to significant insights into solvation phenomena for both hydrophilic and hydrophobic solutes. The QCT exactly partitions solvation free energies into three…

Statistical Mechanics · Physics 2009-11-13 David M. Rogers , Thomas L. Beck

Recent progress in simulation methodologies and in computer power allow first principle simulations of condensed systems with Born-Oppenheimer electronic energies obtained by Quantum Monte Carlo methods. Computing free energies and…

Statistical Mechanics · Physics 2015-05-30 Elisa Liberatore , Miguel A. Morales , David M. Ceperley , Carlo Pierleoni

Free-energy differences between pairs of end-states can be estimated based on molecular dynamics (MD) simulations using standard pathway-dependent methods such as thermodynamic integration (TI), free-energy perturbation, or Bennett's…

Flexible loads are a resource for the Balancing Authority (BA) of the future to aid in the balance of power supply and demand. In order to be used as a resource, the BA must know the capacity of the flexible loads to vary their power demand…

Systems and Control · Electrical Eng. & Systems 2020-10-07 Austin R. Coffman , Prabir Barooah

In this paper we present a numerical method for hydrodynamic models that arise from time dependent density functional theories of freezing. The models take the form of compressible Navier-Stokes equations whose pressure is determined by the…

Numerical Analysis · Mathematics 2016-01-20 Arvind Baskaran , Zhen Guan , John Lowengrub

We revisit the differential energy distribution of steady-state dynamical models. It has been shown that the differential energy distribution of steady-state spherical models does not vary strongly with the anisotropy profile, and that it…

Astrophysics of Galaxies · Physics 2021-09-27 Maarten Baes , Herwig Dejonghe

The binding-energy differences for $^{163}\mathrm{Ho}^{q+}$ and $^{163}\mathrm{Dy}^{q+}$ ions with ionization degrees $q = 38$, $39$, and $40$ are calculated. The calculations are performed using the large-scale relativistic…

Atomic Physics · Physics 2023-08-28 I. M. Savelyev , M. Y. Kaygorodov , Y. S. Kozhedub , I. I. Tupitsyn , V. M. Shabaev
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