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We investigate a diffuse-interface model that describes the dynamics of incompressible two-phase viscous flows with surfactant. The resulting system of partial differential equations consists of a sixth-order Cahn-Hilliard equation for the…

Analysis of PDEs · Mathematics 2023-07-28 Andrea Di Primio , Maurizio Grasselli , Hao Wu

Using a regularized delta function to distribute surfactant interfacial concentration can simplify the computation of the surface gradient operator $\nabla_s$, enabling the phase-field model to effectively simulate Marangoni flows involving…

Fluid Dynamics · Physics 2024-10-01 Haohao Hao , Xiangwei Li , Tian Liu , Huanshu Tan

In this paper we consider a layer of incompressible viscous fluid lying above a flat periodic surface in a uniform gravitational field. The upper boundary of the fluid is free and evolves in time. We assume that a mass of surfactants…

Analysis of PDEs · Mathematics 2016-06-10 Chanwoo Kim , Ian Tice

We propose a model for surfaces in mixtures of oil, water and surfactants with strong electric dipoles. The dipole interactions give rise to a non-local interaction with negative stiffness between surface elements. We show that, for large…

Soft Condensed Matter · Physics 2007-05-23 M. C. Diamantini , H. Kleinert , C. A. Trugenberger

Existence and regularity of minimizers for a geometric variational problem is shown. The variational integral models an energy contribution of the interface between two immiscible fluids in the presence of surfactants and includes a…

Analysis of PDEs · Mathematics 2021-12-14 Christopher Brand , Georg Dolzmann , Alessandra Pluda

Surfactants are often used to stabilise two-dimensional (2D) materials in environmentally friendly solvents such as water. Aqueous-surfactant solutions prevent agglomeration of nanosheets through steric and electrostatic repulsion,…

Materials Science · Physics 2021-11-05 Diego Tomohisa Pérez-Álvarez , Philip Davies , Jason Stafford

We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…

Soft Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

A theoretical study is presented of surface waves at a monomolecular surfactant film between an isotropic liquid and a nematic liquid crystal for the case when the surfactant film is in the isotropic two-dimensional fluid phase and induces…

Soft Condensed Matter · Physics 2008-04-15 S. V. Lishchuk

A number of recent experiments have showed that surfactants can modify the growth mode of an epitaxial film, suppressing islanding and promoting layer-by-layer growth. Here a set of coupled equations are introduced to describe the coupling…

Condensed Matter · Physics 2016-11-03 Albert-Laszlo Barabasi

A thin liquid film covered with an insoluble surfactant in the vicinity of a first-order phase transition is discussed. Within the lubrication approximation we derive two coupled equations to describe the height profile of the film and the…

Pattern Formation and Solitons · Physics 2009-07-15 M. H. Köpf , S. V. Gurevich , R. Friedrich

This paper is devoted to the numerical study of droplet impact on solid substrates in presence of surfactants. We formulate the problem in an energetically variational framework and introduce an incompressible Cahn-Hilliard-Navier-Stokes…

Fluid Dynamics · Physics 2022-12-20 Chenxi Wang , Ming-Chih Lai , Zhen Zhang

We investigate liquid layers adsorbed at spherical and corrugated cylindrical substrates. The effective Hamiltonians for the liquid-gas interfaces fluctuating in the presence of such curved substrates are derived via the mean-field density…

Soft Condensed Matter · Physics 2015-05-13 F. Dutka , M. Napiorkowski

The hydrodynamic stability behaviour of a two-layer falling film is explored with a floating flexible plate on the top surface. The stress balance at the surface is modeled using a modified membrane equation. There is an insoluble…

Fluid Dynamics · Physics 2023-05-18 Md. Mouzakkir Hossain , Sukhendu Ghosh , Harekrushna Behera

Surface phase transitions in surfactant adsorption layers are known to affect the dynamic properties of foams and to induce surface nucleation in freezing emulsion drops. Recently, these transitions were found to play a role in several…

Soft Condensed Matter · Physics 2019-11-12 Nikolai Denkov , Slavka Tcholakova , Diana Cholakova

Surface-active agents (surfactants) release potential energy as they migrate from one of two adjacent fluids onto their fluid-fluid interface, a process that profoundly impacts the system's energy and entropy householding. The continuum…

Fluid Dynamics · Physics 2024-05-29 T. B. van Sluijs , S. K. F. Stoter , E. H. van Brummelen

We present a finite element based variational interface-preserving and conservative phase-field formulation for the modeling of incompressible two-phase flows with surface tension dynamics. The preservation of the hyperbolic tangent…

Computational Physics · Physics 2021-03-17 Xiaoyu Mao , Vaibhav Joshi , Rajeev Jaiman

We briefly review the effects of selective solvation of ions in aqueous mixtures, where the ion densities and the composition fluctuations are strongly coupled. We then examine the surface tension \gamma of a liquid-liquid interface in the…

Soft Condensed Matter · Physics 2015-06-04 Akira Onuki , Takeaki Araki

The diffuse-interface model for two-phase flows with soluble surfactants has garnered considerable attention due to its ability to circumvent the need for Robin boundary condition in the bulk surfactant transport equation. However, the…

Fluid Dynamics · Physics 2025-04-29 Haohao Hao , Xiangwei Li , Luyun Xu , Tian Liu , Huanshu Tan

In this work, we propose a novel scalar-transport model for the simulation of scalar quantities that are confined to the interface in two-phase flows. In a two-phase flow, the scalar quantities, such as salts and surfactants, can reside at…

Fluid Dynamics · Physics 2023-11-21 Suhas S. Jain

The behavior of thin liquid films is known to be strongly affected by the presence of surfactants at the interfaces. The detailed mechanism by which the latter enhance film stability is still a matter of debate, in particular concerning the…

Soft Condensed Matter · Physics 2019-07-24 Lorène Champougny , Benoit Scheid , Frédéric Restagno , Jan Vermant , Emmanuelle Rio