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The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

Thermodynamic fluctuation theory originated with Einstein who inverted the relation $S=k_B\ln\Omega$ to express the number of states in terms of entropy: $\Omega= \exp(S/k_B)$. The theory's Gaussian approximation is discussed in most…

Statistical Mechanics · Physics 2015-05-19 George Ruppeiner

Following our earlier work on the Ruppeiner geometry of an anyon gas [B. Mirza and H. Mohammadzadeh, Phys. Rev. E {\bf 78,} 021127 (2008)], we will derive nonperturbative thermodynamic curvature of a two-dimensional ideal anyon gas. At…

Statistical Mechanics · Physics 2009-07-29 Behrouz Mirza , Hosein Mohammadzadeh

I evaluate the thermodynamic curvature $R$ for fourteen pure fluids along their liquid-vapor coexistence curves, from the critical point to the triple point, using thermodynamic input from the NIST Chemistry WebBook. In this broad overview,…

Statistical Mechanics · Physics 2015-06-11 George Ruppeiner

We here show that, even in the absence of "regularizing" microscopic effects (viz. slip at the wall or the disjoining pressure/precursor films), no singularities in fact arise for a moving contact line surrounded by the pure vapor of the…

Fluid Dynamics · Physics 2013-05-30 Alexey Rednikov , Pierre Colinet

Using contact geometry we give a new characterization of a simple but important class of thermodynamical systems which naturally satisfy the first law of thermodynamics (total energy preservation) and the second law (increase of entropy).…

The thermodynamic Ricci curvature scalar $R$ has been applied in a number of contexts, mostly for systems characterized by 2D thermodynamic geometries. Calculations of $R$ in thermodynamic geometries of dimension three or greater have been…

Statistical Mechanics · Physics 2020-12-02 George Ruppeiner , Alex Seftas

This paper studies the thermodynamics and Ruppeiner geometry of D-dimensional RN black holes. We analyze the thermodynamic curvature scalar $R$ in various thermodynamic ensembles. It is found that in an ensemble of fixed charge (canonical…

General Relativity and Quantum Cosmology · Physics 2025-12-05 Wen-Xiang Chen

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

In this work the curvature of Weinhold (thermodynamical) metric is studied in the case of systems with two thermodynamical degrees of freedom. Conditions for the Gauss curvature $R$ to be zero, positive or negative are worked out. Signature…

Mathematical Physics · Physics 2007-05-23 Manuel Santoro , Serge Preston

It is developed a Riemannian reformulation of classical statistical mechanics for systems in thermodynamic equilibrium, which arises as a natural extension of Ruppeiner geometry of thermodynamics. The present proposal leads to interpret…

Statistical Mechanics · Physics 2010-11-19 L Velazquez

Despite its importance in geological sciences, our understanding of interactions between gas and condensed phases (comprising solids and liquids) remains clouded by the fact that, often, only indirect evidence remains for their occurrence.…

Earth and Planetary Astrophysics · Physics 2019-02-14 Paolo A. Sossi , Bruce Fegley

This paper is devoted to consideration of the theory of collisionless statistical systems with interparticle scalar interaction. The mathematical model of such systems is constructed and the exact solution of Vlasov equation for isotropic…

General Relativity and Quantum Cosmology · Physics 2016-04-27 Yu. G. Ignat'ev

In this paper, we consider the dynamics of a tagged point particle in a gas of moving hard-spheres that are non-interacting among each other. This model is known as the ideal Rayleigh gas. We add to this model the possibility of…

Mathematical Physics · Physics 2019-09-04 Alessia Nota , Raphael Winter , Bertrand Lods

In the view of the Gliner vacuum, we remove the deformations in the first law of mechanics for regular black holes, where one part of deformations associated with black hole mass will be absorbed into enthalpy or internal energy, and the…

General Relativity and Quantum Cosmology · Physics 2022-12-22 Chen Lan , Yan-Gang Miao

New methods are presented which enables one to analyze the thermodynamics of systems with long-range interactions. Generically, such systems have entropies which are non-extensive, (do not scale with the size of the system). We show how to…

General Relativity and Quantum Cosmology · Physics 2009-11-07 Jonathan Oppenheim

In this article we develop Poincar\'e ideas about a heat balance of ideal gas considered as a collisionless continuous medium. We obtain the theorems on diffusion in nondegenerate completely integrable systems. As a corollary we show that…

Chaotic Dynamics · Physics 2007-05-23 V. V. Kozlov

There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for…

Statistical Mechanics · Physics 2022-11-30 Robert Hołyst , Karol Makuch , Anna Maciołek , Paweł J. Żuk

The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature since every material absorbs and…

Classical Physics · Physics 2009-01-14 A. Paglietti

The Fermi liquid theory may provide a good description of the thermodynamic properties of an interacting particle system when the interaction between the particles contributes to the total energy of the system with a quantity which may…

Quantum Gases · Physics 2012-07-19 Dragos-Victor Anghel