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We report first-principles calculations which demonstrate that vacancies can combine with hydrogen impurities in bulk aluminum and play a crucial role in the embrittlement of this prototypical ductile solid. Our studies of hydrogen-induced…

Materials Science · Physics 2009-11-11 Gang Lu , Efthimios Kaxiras

Hydrogen radical attacks and subsequent hydrogen migrations are considered to play an important role in the atomic-scale mechanisms of diamond chemical vapour deposition growth. We perform a comprehensive analysis of the reactions involving…

Screw dislocations in bcc metals display non-planar cores at zero temperature which result in high lattice friction and thermally activated strain rate behavior. In bcc W, electronic structure molecular statics calculations reveal a…

Ti exhibits complex plastic deformation controlled by active dislocation and twinning systems. Understandings on dislocation cores and twin interfaces are currently not complete or quantitative, despite extensive experimental and simulation…

Materials Science · Physics 2024-03-28 Tongqi Wen , Anwen Liu , Rui Wang , Linfeng Zhang , Jian Han , Han Wang , David J. Srolovitz , Zhaoxuan Wu

The interaction between screw dislocations and oxygen interstitial atoms is studied with ab initio calculations in hexagonal close-packed titanium. Our calculations evidence a strong repulsion when the solute atoms are located in the…

Materials Science · Physics 2018-11-27 Nermine Chaari , David Rodney , Emmanuel Clouet

Smectic liquid crystals are charcterized by layers that have a preferred uniform spacing and vanishing curvature in their ground state. Dislocations in the smectics play an important role in phase nucleation, layer reorientation, and…

Soft Condensed Matter · Physics 2017-06-28 Hillel Aharoni , Thomas Machon , Randall D. Kamien

Interpretation of thermal hardening phenomenon at high strain rate has recently become a critical problem in shock wave physics. In this letter, this problem is addressed from a viewpoint of dislocation generation, and a novel conclusion is…

Materials Science · Physics 2018-10-05 Songlin Yao , Xiaoyang Pei , Jidong Yu , Yuying Yu , Qiang Wu

We develop a model for the gliding of dislocations and plasticity in solid He-4. This model takes into account the Peierls barrier, multiplication and interaction of dislocations, as well as classical thermally and mechanically activated…

Revealing statistics of H-defect interactions provides insights into significant ductility loss due to the particular strain partitioning in H-charged structural alloys. Experimental investigation of these interactions is extremely…

Materials Science · Physics 2025-01-22 Matthew J. Melfi , S. Mohadeseh Taheri-Mousavi

Body-centred cubic (BCC) transition metals tend to be brittle at low temperatures, posing significant challenges in processing and major concerns for damage tolerance. The brittleness is largely dictated by the screw dislocation core; the…

Materials Science · Physics 2022-09-27 Rui Wang , Lingyu Zhu , Subrahmanyam Pattamatta , David J. Srolovitz , Zhaoxuan Wu

Zirconium alloys are widely used as the fuel cladding material in pressurised water reactors, accumulating a significant population of defects and dislocations from exposure to neutrons. We present and interpret synchrotron microbeam X-ray…

The strength of body-centered cubic materials is traditionally known to be governed by screw dislocations. However, recent findings reveal that in certain refractory complex concentrated alloys, edge dislocations can instead control…

Plasticity in hexagonal close-packed zirconium is mainly controlled by the glide of dislocations with 1/3<1-210> Burgers vectors. As these dislocations cannot accommodate deformation in the [0001] direction , twinning or glide of <c+a>…

Materials Science · Physics 2020-09-07 Thomas Soyez , Daniel Caillard , Fabien Onimus , Emmanuel Clouet

Hydrogen embrittlement (HE) poses a significant challenge in the mechanical integrity of iron and its alloys. This study explores the influence of hydrogen atoms on two distinct grain boundaries (GBs), $\Sigma37$ and $\Sigma3$, in…

Materials Science · Physics 2024-07-04 Aynour Khosravi , Jun Song , Normand Mousseau

Understanding crack tip - dislocation interaction is critical for improving the fracture resistance of semi-brittle materials like room-temperature plastically deformable ceramics. Here, we use a modified double cleavage drilled compression…

Materials Science · Physics 2025-10-17 Oliver Preuß , Zhangtao Li , Enrico Bruder , Philippe Carrez , Yinan Cui , Jürgen Rödel , Xufei Fang

Hydrogen is a crucial source of green energy and has been extensively studied for its potential usage in fuel cells. The advent of two-dimensional crystals (2DCs) has taken hydrogen research to new heights, enabling it to tunnel through…

Materials Science · Physics 2023-08-08 Ismail Eren , Yun An , Agnieszka B. Kuc

Strain relief in lattice mismatched heteroepitaxy is mediated by formation and/or propagation of dislocations. Due to their technological significance, the process of strain relief in materials with face-centred cubic (fcc) lattices has…

Materials Science · Physics 2007-05-23 Atul Konkar

Dislocation climb mobilities, assuming vacancy bulk diffusion, are derived and implemented in dislocation dynamics simulations to study the coarsening of vacancy prismatic loops in fcc metals. When loops cannot glide, the comparison of the…

Materials Science · Physics 2011-06-29 Botond Bakó , Emmanuel Clouet , Laurent Dupuy , Marc Blétry

The complex atomic scale structure of high entropy alloys presents new opportunities to expand the deformation theories of mechanical metallurgy. In this regard, solute-defect interactions have emerged as critical piece in elucidating the…

Materials Science · Physics 2025-09-18 Novin Rasooli , Wei Chen , Matthew Daly

Atomic-scale calculations indicate that both stress effects and chemical binding contribute to the redistribution of solute in the presence of vacancy clusters in magnesium alloys. As the size of the vacancy cluster increases, chemical…

Materials Science · Physics 2021-12-08 Peng Yi , Taisuke Sasaki , Suhas Eswarappa Prameela , Timothy P. Weihs , Michael L. Falk