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Using a configuration-interaction variational method, we accurately compute the reduced, single-electron von Neumann entropy for several low-energy, singlet and triplet eigenstates of helium atom. We estimate the amount of electron-electron…

Quantum Physics · Physics 2013-05-03 Giuliano Benenti , Stefano Siccardi , Giuliano Strini

In order to quantify entanglement between two parts of a quantum system, one of the most used estimator is the Von Neumann entropy. Unfortunately, computing this quantity for large interacting quantum spin systems remains an open issue.…

Strongly Correlated Electrons · Physics 2011-05-26 S. Capponi , F. Alet , M. Mambrini

Here a finite-Lieb-lattice quantum computing circuit consisting of spin-1/2 quantum bits (qubits) and triplet couplers is designed. Important gradient - quantum entanglement - is analysed. This type of design could be realised in a vast…

Strongly Correlated Electrons · Physics 2026-04-16 Wei Wu

A recent development in quantum chemistry has established the quantum mutual information between orbitals as a major descriptor of electronic structure. This has already facilitated remarkable improvements of numerical methods and may lead…

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

Measuring entanglement entropy in interacting, multipartite systems remains a significant experimental challenge. We address this challenge by developing a protocol to measure von Neumann entropy (VNE) and mutual information in quantum…

Mesoscale and Nanoscale Physics · Physics 2025-08-05 Zhenhua Zhu , Gu Zhang , Dong E. Liu

We consider the quantum entanglement of the electronic and vibrational degrees of freedom in molecules with a tendency towards double welled potentials using model coupled harmonic diabatic potential-energy surfaces. The von Neumann entropy…

Quantum Physics · Physics 2012-02-24 Laura K. McKemmish , Ross H. McKenzie , Noel S. Hush , Jeffrey R. Reimers

Electronic quantum entanglement between the central chain and the two electrodes in an infinite one-dimensional two-probe device system is studied. The entanglement entropy is calculated employing the nonequilibrium Green's function method…

Mesoscale and Nanoscale Physics · Physics 2016-03-02 Yao-Sheng Li , Wen-Long You , Xue-Feng Wang

This thesis offers novel strategies for the measurement of quantum correlations present in controllable quantum systems, as well as for a full-fledged implementation of the models of light-matter interaction through which these correlations…

Quantum Physics · Physics 2016-11-30 Julen S. Pedernales

We define correlational (von Neumann) entropy for an individual quantum state of a system whose time-independent hamiltonian contains random parameters and is treated as a member of a statistical ensemble. This entropy is representation…

chao-dyn · Physics 2013-01-16 Valentin V. Sokolov , B. Alex Brown , Vladimir Zelevinsky

We present the first hardware implementation of electrostatic interaction energies using a trapped-ion quantum computer. As test system for our computation, we focus on the reduction of $\mathrm{NO}$ to $\mathrm{N}_2\mathrm{O}$ catalyzed by…

We present a method to measure the von Neumann entanglement entropy of ground states of quantum many-body systems which does not require access to the system wave function. The technique is based on a direct thermodynamic study of…

Strongly Correlated Electrons · Physics 2020-02-19 T. Mendes-Santos , G. Giudici , R. Fazio , M. Dalmonte

We calculate correlation functions of exactly-solvable one-dimensional flat-band models by utilizing the "molecular-orbital" representation. The models considered in this paper have a gapped ground state with flat-band being fully occupied,…

Strongly Correlated Electrons · Physics 2022-03-23 Tomonari Mizoguchi , Yoshihito Kuno , Yasuhiro Hatsugai

We consider the low-energy excitations of one-dimensional spin-orbital models which consist of spin waves, orbital waves, and joint spin-orbital excitations. Among the latter we identify strongly entangled spin-orbital bound states which…

Strongly Correlated Electrons · Physics 2012-09-11 Wen-Long You , Andrzej M. Oleś , Peter Horsch

Entanglement is considered a fundamental ingredient for quantum technologies and condensed matter systems are among the good candidates for quantum devices. For bipartite pure states the von Neumann entropy is a proper measure of…

Quantum Physics · Physics 2023-03-15 T. Pauletti , M. Garcia , G. A. Canella , V. V. França

We explore quantum correlations, in particular, quantum entanglement, among vibrational phonon modes as well as between electronic and vibrational degrees of freedom in molecular systems, described by Jahn-Teller mechanism. Specifically, to…

Quantum Physics · Physics 2022-02-23 Ali Pedram , Onur Pusuluk , Özgür E. Müstecaplıoğlu

The characterization of many-body correlations provides a powerful tool for analyzing correlated quantum materials. However, experimental extraction of quantum entanglement in correlated electronic systems remains an open problem in…

Strongly Correlated Electrons · Physics 2023-04-21 Faluke Aikebaier , Teemu Ojanen , Jose L. Lado

Understanding and quantifying entanglement entropy is crucial to characterize the quantum behaviors that drive phenomena in a variety of systems. Rare-earth spin complexes, with their unique magnetic properties, provide fertile ground for…

Other Condensed Matter · Physics 2025-05-12 David W. Facemyer , Sergio E. Ulloa

The aim of this work is to introduce the entanglement entropy of real and virtual excitations of fermion and photon fields. By rewriting the generating functional of quantum electrodynamics theory as an inner product between quantum…

High Energy Physics - Theory · Physics 2018-05-23 Juan Sebastian Ardenghi

Quantifying correlation and complexity in quantum many-body states is central to advancing theoretical and computational chemistry, physics, and quantum information science. This work introduces a novel framework, mutual correlation, based…

Chemical Physics · Physics 2025-06-10 Francesco A. Evangelista