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We present a constructive solution to the N-representability problem---a full characterization of the conditions for constraining the two-electron reduced density matrix (2-RDM) to represent an N-electron density matrix. Previously known…

Quantum Physics · Physics 2012-07-04 David A. Mazziotti

The standard (``fine-grained'') interpretation of quantum density functional theory, in which densities are specified with infinitely-fine spatial resolution, is mathematically unruly. Here, a coarse-grained version of DFT, featuring…

Mathematical Physics · Physics 2015-05-13 Paul E. Lammert

Many-body quantum-mechanical stationary states that have real valued wavefunctions are shown to satisfy a classical conservation of energy equation with a kinetic energy function. The terms in the equation depend on the probability…

Atomic Physics · Physics 2021-07-23 James P. Finley

The formalism developed in the first paper of the series [arXiv:0901.1060] is applied to two thermodynamic systems: (i) of three global observables (the energy, the total electron number and the spin number), (ii) of one global observable…

Chemical Physics · Physics 2013-10-28 Robert Balawender , Andrzej Holas

The problem of stability of saturated and non-saturated ferromagnetism in the Hubbard model is considered in terms of the one-particle Green's functions. Approximations by Edwards and Hertz and some versions of the self-consistent…

Strongly Correlated Electrons · Physics 2009-11-07 V. Yu. Irkhin , A. V. Zarubin

As is well-known, for plasmas of high density and modest temperature, the classical kinetic theory needs to be extended. Such extensions can be based on the Schr\"odinger Hamiltonian, applying a Wigner transform of the density matrix, in…

Plasma Physics · Physics 2021-11-02 Gert Brodin , Jens Zamanian

We use density-matrix renormalization group, applied to a one-dimensional model of continuum Hamiltonians, to accurately solve chains of hydrogen atoms of various separations and numbers of atoms. We train and test a machine-learned…

Strongly Correlated Electrons · Physics 2016-12-28 Li Li , Thomas E. Baker , Steven R. White , Kieron Burke

The Seebeck coefficient plays a fundamental role in identifying the efficiency of a thermoelectric device. Its theoretical evaluation for atomistic models is routinely based on Density Functional Theory calculations combined with the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Kaike Yang , Enrico Perfetto , Stefan Kurth , Gianluca Stefanucci , Roberto D'Agosta

We provide a brief overview of approaches for calculating the density of states of quantum systems and random matrix Hamiltonians using the tools of free probability theory. For a given Hamiltonian of a quantum system or a generic random…

Quantum Physics · Physics 2025-12-04 Keun-Young Kim , Kuntal Pal

This chapter presents the development of a density functional theory (DFT)-based method for accurate, reliable treatment of various resonances in atoms. Many of these are known to be notorious for their strong correlation, proximity to more…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy

We prove rigorously that the exact N-electron Hohenberg-Kohn density functional converges in the strongly interacting limit to the strictly correlated electrons (SCE) functional, and that the absolute value squared of the associated…

Mathematical Physics · Physics 2018-04-04 Codina Cotar , Gero Friesecke , Claudia Klüppelberg

We revisit the one-dimensional attractive Hubbard model by using the Bethe-ansatz based density-functional theory and density-matrix renormalization method. The ground-state properties of this model are discussed in details for different…

Density Functional Theory's Kohn-Sham (KS) potential emerges as the minimizing effective potential in an unconstrained variational scheme that does not involve fixing the unknown single-electron density. The physical content behind the…

Other Condensed Matter · Physics 2007-05-23 N. I. Gidopoulos

We use the exact strong-interaction limit of the Hohenberg-Kohn energy density functional to approximate the exchange-correlation energy of the restricted Kohn-Sham scheme. Our approximation corresponds to a highly non-local density…

Strongly Correlated Electrons · Physics 2012-12-12 Francesc Malet , Paola Gori-Giorgi

Starting from a general $N$-band Hamiltonian with weak spatial and temporal variations, we derive a low energy effective theory for transport within one or several overlapping bands. To this end, we use the Wigner representation that allows…

Mesoscale and Nanoscale Physics · Physics 2013-08-09 Christian Wickles , Wolfgang Belzig

We present an \textit{ab initio} theory for superconductors, based on a unique mapping between the statistical density operator at equilibrium, on the one hand, and the corresponding one-body reduced density matrix $\gamma$ and the…

Superconductivity · Physics 2019-06-06 Jonathan Schmidt , Carlos L. Benavides-Riveros , Miguel A. L. Marques

By mapping the Hamiltonians of the two-mode and 2-photon Rabi models to differential operators in suitable Hilbert spaces of entire functions, we prove that the two models possess entire and normalizable wavefunctions in the…

Quantum Physics · Physics 2017-04-19 Yao-Zhong Zhang

The constrained-search formulation of Levy and Lieb, which formally defines the exact Hohenberg-Kohn functional for any N-representable electron density, is here shown to be equivalent to the minimization of the correlation functional with…

Quantum Physics · Physics 2015-05-13 L. Delle Site

Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

We consider the pairing Hamiltonian and systematically construct its density functional in the strong-coupling limit and in the limit of large particle number. In the former limit, the functional is an expansion into central moments of…

Nuclear Theory · Physics 2008-11-26 T. Papenbrock , Anirban Bhattacharyya