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The electronic and thermoelectric properties of molecular junctions formed from iron and ruthenium metal-acetylide were studied using complementary experimental techniques and quantum chemical simulations. We performed physical…

We report the thermal conductances of molecular junctions made of self-assembled monolayers of benzo-bis(imidazole) molecules, without side groups or functionalized with two phenylamine side groups. In the two cases, when the molecules are…

Mesoscale and Nanoscale Physics · Physics 2026-03-31 Sergio Gonzalez-Casal , Simon Pascal , Olivier Siri , Dominique Vuillaume

We study by scanning thermal microscopy the nanoscale thermal conductance of films (40 to 400 nm thick) of [1]benzothieno[3,2-b][1]benzothiophene (BTBT) and 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT-C8). We demonstrate that…

We report the formation of self-assembled monolayers of a molecular photoswitch (azobenzene-bithiophene derivative, AzBT) on cobalt via a thiol covalent bond. We study the electrical properties of the molecular junctions formed with the tip…

We have fabricated a variety of novel molecular tunnel junctions based on self-assembled-monolayers (SAM) of two-component solid-state mixtures of molecular wires (1,4 methane benzene-dithiol; Me-BDT with two thiol anchoring groups), and…

Materials Science · Physics 2009-11-11 Vladimir Burtman , Alexander S. Ndobe , Valy Z. Vardeny

Thermopower measurements of molecular junctions have recently gained interest as a characterization technique that supplements the more traditional conductance measurements. Here we investigate the electronic conductance and thermopower of…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Troels Markussen , Chengjun Jin , Kristian S. Thygesen

By using a first-principles approach, monolayer PbI$_2$ is found to have great potential in thermoelectric applications. The linear Boltzmann transport equation is applied to obtain the perturbation to the electron distribution by different…

Materials Science · Physics 2021-05-24 Bo Peng , Haodong Mei , Hao Zhang , Hezhu Shao , Ke Xu , Gang Ni , Qingyuan Jin , Costas M. Soukoulis , Heyuan Zhu

Here we present a theoretical study of the thermoelectric transport through {[}2,2{]}para\-cyclo\-phane-based single-molecule junctions. Combining electronic and vibrational structures, obtained from density functional theory (DFT), with…

Mesoscale and Nanoscale Physics · Physics 2017-04-07 Marius Bürkle , Thomas J. Hellmuth , Fabian Pauly , Yoshihiro Asai

C60 fullerene has been studied extensively, as it is considered to be a good candidate for building single-molecule junctions. Here, we theoretically demonstrate that the conductance of single-molecule junctions based on a newly discovered…

Mesoscale and Nanoscale Physics · Physics 2015-11-19 Chengbo Zhu , Xiaolin Wang

We report the first concurrent determination of conductance (G) and thermopower (S) of single-molecule junctions via direct measurement of electrical and thermoelectric currents using a scanning tunneling microscope-based break-junction…

Mesoscale and Nanoscale Physics · Physics 2012-01-10 J. R. Widawsky , P. Darancet , J. B. Neaton , L. Venkataraman

It is believed that nanostructuring is an effective way to achieve excellent thermoelectric performance. In the work, by combining the first-principles calculations and semiclassical Boltzmann transport theory, we investigate the…

Materials Science · Physics 2017-06-27 San-Dong Guo , Hui-Chao Li

We report a method using scanning tunnelling microscope single molecular break junction to simultaneously measure and correlate the single-molecule thermopower and electrical conductance. In contrast to previously reported approaches, it…

Mesoscale and Nanoscale Physics · Physics 2021-09-24 Joseph M. Hamill , Christopher Weaver , Tim Albrecht

Within the framework of nonequilibrium Green's functions, we investigate the thermoelectric transport in a single molecular junction with electron-phonon and electron-electron interactions. By transforming into a displaced phonon basis, we…

Mesoscale and Nanoscale Physics · Physics 2012-04-26 Jie Ren , Jian-Xin Zhu , James E. Gubernatis , Chen Wang , Baowen Li

The miniaturization of thermoelectric nanojunctions raises a fundamental question: do the thermoelectric quantities of the bridging materials in nanojunctions remain to display material properties or show junction properties? In order to…

Mesoscale and Nanoscale Physics · Physics 2009-04-09 Yu-Chang Chen , Yu-Shen Liu

The energy dependent thermoelectric response of a single molecule contains valuable information about its transmission function and its excited states. However, measuring it requires devices that can efficiently heat up one side of the…

Monolayer semiconductors of group-VA elements (As, Sb, Bi) with graphenelike buckled structure offer a potential to achieve nanoscale electronic, optoelectronic and thermoelectric devices. Motivated by recently-fabricated Sb monolayer, we…

Materials Science · Physics 2017-02-10 Dong-Chen Zhang , Ai-Xia Zhang , San-Dong Guo

Critical thermoelectric parameters including Seebeck coefficient, electrical conductivity, thermal conductivity and figure of merit ZT of one-dimensional coaxial Bi2Te3/Sb2Te3 nanocomposite were modeled by following the single carrier…

Materials Science · Physics 2011-01-31 Qilin Gu

We present an \emph{ab initio} study of the role of interference effects in the thermal conductance of single-molecule junctions. To be precise, using a first-principles transport method based on density functional theory, we analyze the…

Mesoscale and Nanoscale Physics · Physics 2017-12-27 J. C. Klöckner , J. C. Cuevas , F. Pauly

A first-principles approach is presented for the thermoelectricity in molecular junctions formed by a single molecule contact. The study investigates the Seebeck coefficient considering the source-drain electrodes with distinct temperatures…

Mesoscale and Nanoscale Physics · Physics 2009-05-07 Yu-Shen Liu , Yu-Chang Chen

We carry out a systematic study of the thermal conductivity of four single-layer transition metal dichalcogenides, MX$_2$ (M = Mo, W; X = S, Se) from first-principles by solving the Boltzmann Transport Equation (BTE). We compare three…

Materials Science · Physics 2019-03-29 Pol Torres , Francesc Xavier Alvarez , Xavier Cartoixà , Riccardo Rurali
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