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We examine the minimization of information entropy for measures on the phase space of bounded domains, subject to constraints that are averages of grand canonical distributions. We describe the set of all such constraints and show that it…

Mathematical Physics · Physics 2019-10-02 Stamatis Dostoglou , Alexander Hughes , Jianfei Xue

The article reveals the error that in classical thermodynamics leads to the Gibbs paradox. The essence of the error lies in the fact that the entropy of an ideal gas is attributed to additive quantities, but it is not correct. The value of…

History and Philosophy of Physics · Physics 2023-07-12 Volodymyr Ihnatovych

In this paper, we investigate and compare two well-developed definitions of entropy relevant for describing the dynamics of isolated quantum systems: bipartite entanglement entropy and observational entropy. In a model system of interacting…

Quantum Physics · Physics 2020-06-01 Dana Faiez , Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

In this study, we present a reformulation of classical equilibrium thermodynamics by replacing the obscure and ambiguous concept of entropy with the clear and intuitive concept of information stored in a thermodynamic system. Specifically,…

Statistical Mechanics · Physics 2025-01-15 Faical Barzi , Kaoutar Fethi

This article consists of a very short introduction to classical and quantum information theory. Basic properties of the classical Shannon entropy and the quantum von Neumann entropy are described, along with related concepts such as…

High Energy Physics - Theory · Physics 2020-04-20 Edward Witten

We consider the problem of finite sample corrections for entropy estimation. New estimates of the Shannon entropy are proposed and their systematic error (the bias) is computed analytically. We find that our results cover correction…

Statistical Mechanics · Physics 2009-11-10 Thomas Schürmann

A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…

Statistical Mechanics · Physics 2015-05-28 Michele Campisi

Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…

Physics Education · Physics 2015-06-26 Clinton D. Stoner

Entropy is a fundamental concept from Thermodynamics and it can be used to study models on context of Creation Cold Dark Matter (CCDM). From conditions on the first ($\dot{S}\geq0$)\footnote{Throughout the present work we will use dots to…

General Relativity and Quantum Cosmology · Physics 2020-12-02 R. Valentim , J. F. Jesus

The Renyi entropy is a generalization of the usual concept of entropy which depends on a parameter q. In fact, Renyi entropy is closely related to free energy. Suppose we start with a system in thermal equilibrium and then suddenly divide…

Quantum Physics · Physics 2022-05-18 John C. Baez

We overview the notion of entropy in thermodynamics. We start from the smooth case using differential forms on the manifold, which is the natural language for thermodynamics. Then the axiomatic definition of entropy as ordering on a set…

Mathematical Physics · Physics 2019-11-12 Radosław A. Kycia

Entanglement entropy is one of the most prominent measures in quantum physics. We show that it has an interesting ergotropic interpretation in terms of unitarily extracted work. It determines how much energy one can extract from a source of…

Quantum Physics · Physics 2023-06-16 Dominik Šafránek

In order to undestand how the complex concept of entropy emerged,we propose a trip towards the past reviewing the works of Clausius, Boltzmann, Gibbs and Planck. In particular, since the Gibbs's work is not very well known, we present a…

History and Philosophy of Physics · Physics 2015-06-11 L. Benguigui

Entropic Dynamics is a framework in which dynamical laws are derived as an application of entropic methods of inference. No underlying action principle is postulated. Instead, the dynamics is driven by entropy subject to the constraints…

Quantum Physics · Physics 2015-09-11 Ariel Caticha

Entropy generation in a chemical reaction is analyzed without using the general formalism of non-equilibrium thermodynamics at a level adequate for advanced undergraduates. In a first approach to the problem, the phenomenological kinetic…

General Physics · Physics 2015-06-11 E. N. Miranda

The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy.…

Statistical Mechanics · Physics 2008-11-26 Jörn Dunkel , Peter Talkner , Peter Hänggi

Microcanonical equations for several thermodynamic properties of a system, suitable for molecular dynamics simulations, are derived from the nonextensive Tsallis entropy functional. Two possible definitions of temperature, the usual one and…

Statistical Mechanics · Physics 2011-03-21 J. Carrete , L. M. Varela , L. J. Gallego

Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…

General Physics · Physics 2007-05-23 Bin Zhou

Entropy is one of the key thermodynamic variables reflecting changes in the state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this…

Statistical Mechanics · Physics 2026-04-15 Haim Diamant , Gil Ariel

It is well known that equilibrium in a thermodynamic system results from a competition or balance between lowering the energy and increasing the entropy, or at least the product of the temperature and entropy. This is remarkably similar to…

Statistical Mechanics · Physics 2009-09-30 Douglas Henderson
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