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We present a theoretical analysis of heat transport through a single-molecule junction with two possible transport channels for electrons where interactions between electrons on the molecule and phonons in the nuclear environment is strong…

Mesoscale and Nanoscale Physics · Physics 2023-07-13 Natalya A. Zimbovskaya

Understanding current-induced bond rupture in single-molecule junctions is both of fundamental interest and a prerequisite for the design of molecular junctions, which are stable at higher bias voltages. In this work, we use a fully quantum…

Mesoscale and Nanoscale Physics · Physics 2021-06-30 Yaling Ke , André Erpenbeck , Uri Peskin , Michael Thoss

Routinely, experiments on tunneling molecular junctions report values of conductances ($G_{RT}$) and currents ($I_{RT}$) measured at room temperature. On the other side, theoretical approaches based on simplified models provide analytic…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Ioan Baldea

The appealing feature of molecular electronics is the possibility of exploiting functionality built within a single molecule. This functionality can be employed, for example, for sensing or switching purposes. Thus, ideally, the associated…

Current-induced bond rupture is a fundamental process in nanoelectronic architectures such as molecular junctions and in scanning tunneling microscopy measurements of molecules at surfaces. The understanding of the underlying mechanisms is…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Yaling Ke , Jan Dvořák , Martin Čížek , Raffaele Borrelli , Michael Thoss

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

By using a propagation scheme for current matrices and an auxiliary mode expansion method, we investigate the transient dynamics of a single molecular junction coupled with a vibrational mode. Our approach is based on the Anderson-Holstein…

Mesoscale and Nanoscale Physics · Physics 2016-02-17 Guo-Hui Ding , Bo Xiong , Bing Dong

This mini review focuses on conductance measurements through molecular junctions containing few tens of molecules, which are fabricated along two approaches: (i) conducting atomic force microscope contacting a self-assembled monolayers on…

Applied Physics · Physics 2019-11-12 Dominique Vuillaume

We propose an objective and robust method to extract the electrical conductance of single molecules connected to metal electrodes from a set of measured conductance data. Our method roots in the physics of tunneling and is tested on…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Teresa González , Songmei Wu , Roman Huber , Sense J. van der Molen , Christian Schönenberger , Michel Calame

The transport properties of a conduction junction model characterized by two mutually coupled channels that strongly differ in their couplings to the leads are investigated. Models of this type describe molecular redox junctions (where a…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Alexander J. White , Agostino Migliore , Michael Galperin , Abraham Nitzan

Experimental studies on single-molecule junctions are typically in need of a simple theoretical approach that can reproduce or be fitted to experimentally measured transport data. In this context, the single-level variant of the Landauer…

Chemical Physics · Physics 2021-02-10 Jakub K. Sowa , Rudolph A. Marcus

We study the statistical properties of currents in two particular systems of capacitively coupled parallel transport channels. In the first system, each transport channel contains a single quantum dot in contact with two electron…

Mesoscale and Nanoscale Physics · Physics 2013-10-03 Gregory Bulnes Cuetara

Electronic conductance through a single molecule is sensitive towards its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by…

Mesoscale and Nanoscale Physics · Physics 2023-08-11 Koushik R. Das , Sudipta Dutta

While heating of a current carrying Ohmic conductors is an obvious consequence of the diffusive nature of the conduction in such systems, current induced cooling has been recently reported in some molecular conduction junctions. In this…

Mesoscale and Nanoscale Physics · Physics 2009-09-25 Michael Galperin , Keiji Saito , Alexander V. Balatsky , Abraham Nitzan

We studied the noise spectra of molecule-free and molecule-containing mechanically controllable break junctions. Both types of junctions revealed typical 1/ f noise characteristics at different distances between the contacts with square…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 V. A. Sydoruk , D. Xiang , S. A. Vitusevich , M. V. Petrychuk , A. Vladyka , Y. Zhang , A. Offenhäusser , V. A. Kochelap , A. E. Belyaev , D. Mayer

We present an original method to estimate the conductivity of a single molecule anchored to nanometric-sized metallic electrodes, using a Mechanically Controlled Break Junction (MCBJ) operated at room temperature in liquid. We record the…

Mesoscale and Nanoscale Physics · Physics 2018-03-16 M. Gil , T. Malinowski , M. Iazykov , H. Klein

One of the ultimate goals of molecular electronics is to create technologies that will complement - and eventually supersede - Si-based microelectronics technologies. To reach this goal, electronic properties that mimic at least some of the…

Mesoscale and Nanoscale Physics · Physics 2015-06-26 Bingqian Xu , Yonatan Dubi

The rate-equation approach is used to describe sequential tunneling through a molecular junction in the Coulomb blockade regime. Such device is composed of molecular quantum dot (with discrete energy levels) coupled with two metallic…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Kamil Walczak

The coupling of the charge carriers passing through a molecule bridging two bulky conductors with local vibrational modes of the molecule, gives rise to distinct features in the electronic transport properties on one hand, and to…

Mesoscale and Nanoscale Physics · Physics 2017-02-01 A. Ueda , Y. Utsumi , Y. Tokura , O. Entin-Wohlman , A. Aharony

Quantum transport in mesoscopic conductors is essentially governed by the laws of quantum mechanics. One of the major open questions of quantum mechanics is what happens if non-commuting observables are measured simultaneously. Since…

Mesoscale and Nanoscale Physics · Physics 2010-03-15 Adam Bednorz , Wolfgang Belzig