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We have analyzed the morphology of ferroelectric domains in very thin films of multiferroic BiFeO3. Unlike the more common stripe domains observed in thicker films BiFeO3 or in other ferroics, the domains tend not to be straight, but…

Materials Science · Physics 2009-11-13 G. Catalan , H. Bea , S. Fusil , M. Bibes , P. Paruch , A. Barthelemy , J. F. Scott

We demonstrate a direct correlation between the domain structure of multiferroic BiFeO3 thin films and exchange bias of Co0.9Fe0.1/BiFeO3 heterostructures. Two distinct types of interactions, an enhancement of the coercive field (exchange…

The anisotropic optical properties of multiferroic BiFeO$_3$ thin films have been determined with Mueller matrix ellipsometry at room-temperature. The full dielectric tensors of tetragonal-like and rhombohedral-like BiFeO$_3$ phases…

Materials Science · Physics 2015-08-26 Daniel Schmidt , Lu You , Xiao Chi , Junling Wang , Andrivo Rusydi

Hidden spin polarization (HSP) emerges in centrosymmetric crystals where visible spin splittings in the real space can be observed because of the lack of inversion symmetry in each local sector. Starting from tight-binding models, we…

Materials Science · Physics 2020-11-18 Shan Guan , Jun-Wei Luo

The integration of ferroelectric and topological materials offers a promising avenue for advancing the development of quantum material devices. In this work, we explore the strong coupling between topological states and ferroelectricity in…

Materials Science · Physics 2025-12-17 Jiaheng Li , Quansheng Wu , Hongming Weng

The domain configuration of 50 nm thick La0.7SrMnO3 films has been directly investigated using scanning electron microscopy with polarization analysis (SEMPA), with magnetic contrast obtained without the requirement for prior surface…

Materials Science · Physics 2015-06-15 Robert M. Reeve , Christian Mix , Markus König , Michael Foerster , Gerhard Jakob , Mathias Kläui

The kinetics and thermodynamics of first order transitions is universally controlled by defects that act as nucleation sites and pinning centers. Here we demonstrate that defect-domain interactions during polarization reversal processes in…

Materials Science · Physics 2009-11-13 S. V. Kalinin , S. Jesse , B. J. Rodriguez , Y. H. Chu , R. Ramesh , E. A. Eliseev , A. N. Morozovska

Tuning the lattice degree of freedom in nanoscale functional crystals is critical to exploit the emerging functionalities such as piezoelectricity, shape-memory effect, or piezomagnetism, which are attributed to the intrinsic lattice-polar…

Here we demonstrate that MnTe epitaxial films with zinc-blend structure and MnTe/ZnTe multilayers should show ferroelectric polarization in antiferromagnetically (AFM) ordered state and thus belong to multiferroics. Spontaneous…

Materials Science · Physics 2008-11-14 Helen V. Gomonay , Ievgeniia G. Korniienko

We have directly imaged reversible electrical switching of the cycloidal rotation direction (magnetic polarity) in a (111)-BiFeO3 epitaxial-film device at room temperature by non-resonant x-ray magnetic scattering. Consistent with previous…

Strongly Correlated Electrons · Physics 2017-07-06 N. Waterfield Price , R. D. Johnson , W. Saenrang , A. Bombardi , F. P. Chmiel , C. B. Eom , P. G. Radaelli

First-principles density functional calculations show that the $\textrm{SrRuO}_{3}/\textrm{PbTiO}_{3}/\textrm{SrRuO}_{3}$ multiferroic junction with asymmetric (RuO$_{2}$/PbO and TiO$_{2}$/SrO) interfaces has a large ferroelectric…

Materials Science · Physics 2013-12-20 Francesco Ricci , Alessio Filippetti , Vincenzo Fiorentini

Epitaxial strain has emerged as a powerful tool to tune magnetic and ferroelectric properties in functional materials such as in multiferroic perovskite oxides. Here, we use first-principles calculations to explore the evolution of magnetic…

Materials Science · Physics 2023-11-23 Sebastian Meyer , Bin Xu , Laurent Bellaiche , Bertrand Dupé

Multiferroic BiFeO3 epitaxial films with thickness ranging from 40 nm to 960 nm were grown by pulsed laser deposition on SrTiO3 (001) substrates with SrRuO3 bottom electrodes. X-ray characterization shows that the structure evolves from…

Materials Science · Physics 2009-11-13 Dae Ho Kim , Ho Nyung Lee , Michael D. Biegalski , Hans M. Christen

Pb(Fe$_{0.5}$Nb$_{0.5}$)O$_3$ (PFN), one of the few relaxor multiferroic systems, has a $G$-type antiferromagnetic transition at $T_N$ = 143 K and a ferroelectric transition at $T_C$ = 385 K. By using high-resolution neutron-diffraction…

Using Landau-Ginzburg-Devonshire approach, we predict the intrinsic instability of the ferroelectric-ferroelastic domain walls in the multiferroic BiFeO3 emerging from the interplay between the gradient terms of the antiferrodistortive and…

Materials Science · Physics 2019-01-03 Eugene A. Eliseev , Anna N. Morozovska , Christopher T. Nelson , Sergei V. Kalinin

Two-dimensional multiferroics promise low-power, multifunctional devices, yet the intrinsic coexistence and mutual control of three coupled ferroic orders in a single layer remains elusive. Here, we identify pentagonal monolayer FeO$_2$ as…

Materials Science · Physics 2025-11-26 Deping Guo , Jiaqi Dai , Renhong Wang , Cong Wang , Wei Ji

Using the results of x-ray and neutron diffraction experiments, we show that the ferroelectric polarization, in ~22 nm particles of BiFeO3, exhibits a jump by ~30% around the magnetic transition point T_N (~635 K) and a suppression by ~7%…

Materials Science · Physics 2011-08-18 S. Goswami , Dipten Bhattacharya , P. Choudhury , B. Ouladdiaf , T. Chatterji

Despite multiple efforts, there exist many unsolved fundamental problems related with detection and analysis of internal polarization structure and related phase transitions in ferroelectric domain walls. Their solution can be very…

The ground-state polarization of PbTiO3 thin films is studied using a microscopic effective Hamiltonian with parameters obtained from first-principles calculations. Under short-circuit electrical boundary conditions, (001) films with…

Materials Science · Physics 2009-10-31 Ph. Ghosez , K. M. Rabe

We investigate the microstructural evolution in a ferroelectric to antiferroelectric phase transition at the morphotropic phase boundary in the Bi(1-x)SmxFeO3 system. Continuous Sm3+ substitution on the A-site induces short-range…