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Nonlinear spectroscopy and microscopy techniques are ubiquitous in a wide range of applications across physics and biology. However, these usually rely on high-powered pulsed laser systems. A promising alternative is to exploit entangled…

Entangled two-photon absorption (ETPA) could form the basis of nonlinear quantum spectroscopy at very low photon fluxes, since, at sufficiently low photon fluxes, ETPA scales linearly with the photon flux. When different pairs start to…

Quantum Physics · Physics 2023-12-04 Frank Schlawin

When a low flux of time-frequency-entangled photon pairs (EPP) illuminates a two-photon transition, the rate of two-photon absorption (TPA) can be enhanced considerably by the quantum nature of photon number correlations and frequency…

Two-photon absorption (TPA) and other nonlinear interactions of molecules with time-frequency-entangled photon pairs (EPP) has been predicted to display a variety of fascinating effects. Therefore, their potential use in practical…

Quantum Physics · Physics 2021-09-15 Michael G. Raymer , Tiemo Landes , Andrew H. Marcus

Over the last 50 years entangled photon pairs have received attention for use in lowering the flux in two-photon absorption imaging and spectroscopy. Despite this, evidence for entangled two-photon absorption (ETPA) effects remain highly…

Recent investigations suggest that the use of non-classical states of light, such as entangled photon pairs, may open new and exciting avenues in experimental two-photon absorption spectroscopy. Despite several experimental studies of…

We introduce a method for determining the sensitivity of any given Entangled Two-Photon Absorption (ETPA) measurement. By modeling all signal and noise contributions to the measurement, we derive a single numerical value that describes the…

Quantum Physics · Physics 2025-12-23 René Pollmann , Franz Roeder , Christine Silberhorn , Benjamin Brecht

It has been proposed that entangled two-photon absorption (E2PA) can be observed with up to 10 orders of magnitude lower photon flux than its classical counterpart. However, there is a significant controversy regarding the magnitude of this…

The phenomenon of Entangled Two-Photon Absorption (ETPA) presents a persistent controversy in the literature, evidenced by a wide disparity in the reported values for the $\sigma_E$ cross-sections. Much of this discrepancy is attributed to…

Quantum Physics · Physics 2025-12-02 Pablo Yepiz-Graciano , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

Entangled two-photon absorption spectroscopy (TPA) has been widely recognized as a powerful tool for revealing relevant information about the structure of complex molecular systems. However, to date, the experimental implementation of this…

Quantum Physics · Physics 2019-07-10 Roberto de J. León-Montiel , Jiří Svozilík , Juan P. Torres , Alfred B. U'Ren

Entangled two-photon absorption (eTPA) has been recognized as a potentially powerful tool for the implementation of ultra-sensitive spectroscopy. Unfortunately, there exists a general agreement in the quantum optics community that…

Quantum Physics · Physics 2025-01-31 Áulide Martínez-Tapia , Roberto de J. León-Montiel

Recently, different experimental methods to investigate the entangled two-photon absorption (ETPA) process in a variety of materials have been reported. The present work reports on a different approach on which the ETPA process is detected…

Quantum Physics · Physics 2022-02-15 Freiman Triana-Arango , Gabriel Ramos-Ortiz , Roberto Ramírez-Alarcón

We introduce a toluene-filled fiber platform for two-photon absorption measurements. By confining both the light and molecular sample inside the 5 $\mu$m hollow core of the fiber, we increase the distance over which the nonlinear…

While two-photon absorption (TPA) and other forms of nonlinear interactions of molecules with isolated time-frequency-entangled photon pairs (EPP) have been predicted to display a variety of fascinating effects, their potential use in…

Entangled photons are a crucial resource for quantum communication and linear optical quantum computation. Unfortunately, the applicability of many photon-based schemes is limited due to the stochastic character of the photon sources.…

Quantum Physics · Physics 2012-02-07 Stefanie Barz , Gunther Cronenberg , Anton Zeilinger , Philip Walther

In virtual-state spectroscopy, information about the energy-level structure of an arbitrary sample is retrieved by Fourier transforming sets of measured two-photon absorption probabilities of entangled photon pairs where the degree of…

Quantum Physics · Physics 2021-08-04 Lutz Mertenskötter , Kurt Busch , Roberto de J. León-Montiel

Excitation with entangled photon pairs may lead to an increase in the efficiency of two-photon absorption at low photon flux. The corresponding process, entangled two-photon absorption (E2PA), has been investigated in numerous theoretical…

It is well known that energy-time entanglement can enhance two photon absorption (TPA) by simultaneously optimizing the two photon resonance and the coincidence rate of photons at the absorber. However, the precise relation between…

Quantum Physics · Physics 2021-08-31 Baihong Li , Holger F. Hofmann

Entangled two-photon spectroscopy is expected to provide advantages compared with classical protocols. It is achieved by coherently controlling the spectral properties of energy-entangled photons. We present here an experimental setup that…

Quantum Physics · Physics 2021-08-25 Stefan Lerch , André Stefanov

We use a non-perturbative theoretical approach to the parametric down-conversion (PDC) process, which generates entangled-photon field for an arbitrarily strong pump-pulse. This approach can be used to evaluate multi-point field correlation…

Chemical Physics · Physics 2025-10-22 Deependra Jadoun , Upendra Harbola , Vladimir Y. Chernyak , Shaul Mukamel
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