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Systems of spins engineered with tunable density and reduced dimensionality enable a number of advancements in quantum sensing and simulation. Defects in diamond, such as nitrogen-vacancy (NV) centers and substitutional nitrogen (P1…

First-principles calculations reported here illuminate the effects of the interfacial properties of $\alpha$-Al$_{2}$O$_{3}$ and graphene, with emphasis on the structural and electronic properties. Various contact interfaces and different…

Diamond is a solid-state platform to develop quantum technologies, but it has been a long-standing problem that the current understanding of quantum states in diamond is mostly limited to single-electron pictures. Here, we combine the full…

Chemical Physics · Physics 2023-07-19 Yilin Chen , Tonghuan Jiang , Haoxiang Chen , Erxun Han , Ali Alavi , Kuang Yu , En-Ge Wang , Ji Chen

Using spin-density functional theory we investigated various possible structures of the hematite (0001) surface. Depending on the ambient oxygen partial pressure, two geometries are found to be particularly stable under thermal equilibrium:…

Materials Science · Physics 2009-10-31 X. -G. Wang , W. Weiss , Sh. K. Shaikhutdinov , M. Ritter , M. Petersen , F. Wagner , R. Schloegl , M. Scheffler

Spin squeezed states provide a seminal example of how the structure of quantum mechanical correlations can be controlled to produce metrologically useful entanglement. Such squeezed states have been demonstrated in a wide variety of…

We report the results of an x-ray scattering study that reveals oxidation kinetics and formation of a previously unreported crystalline phase of SnO at the liquid-vapour interface of Sn. Our experiments reveal that the pure liquid Sn…

To understand the crystal structure of n-diamond, a hydrogen-doped (H-doped) diamond model has been investigated using first principles calculations. In particular, hydrogen concentration dependent elastic constants and lattice parameters…

Materials Science · Physics 2015-05-27 Bin Wen , Roderick Melnik , Shan Yao , Tingju Li

A novel carbon allotrope, hexagonal C12, is proposed from crystal chemistry and quantum density functional theory DFT calculations of ground state and physical properties. The structure exhibits corner sharing distorted tetrahedra with the…

Materials Science · Physics 2023-06-16 Samir F. Matar

Understanding and controlling fluorescent nanodiamonds (FNDs) with optically read qubits is a key focus of research, as they show high potential for detecting electric and magnetic fields, temperature, and other physico-chemical quantities…

Solar water splitting has attracted much attention as a clean and renewable route to produce hydrogen fuel. Since the oxygen evolution half-reaction (OER) requires high overpotentials, much research has focused on finding catalyst materials…

Materials Science · Physics 2019-06-03 Maria Bouri , Ulrich Aschauer

We investigate nuclear spin hyperpolarization from nitrogen vacancy centers in isotopically enriched diamonds with $^{13}$C concentrations up to 100%. $^{13}$C enrichment leads to hyperfine structure of the nitrogen vacancy electron spin…

In diamond, nitrogen defects like the substitutional nitrogen defect (Ns) or the nitrogen-vacancy-hydrogen complex (NVH) outnumber the nitrogen vacancy (NV) defect by at least one order of magnitude creating a dense spin bath. While neutral…

The growth of thin amorphous hydrogenated carbon films (a-C:H) on diamond (111) surface from the bombardment of CH2 radicals is studied using molecular dynamics simulations. The structural analysis shows that the local structure (e.g., the…

Materials Science · Physics 2014-11-27 Chuan-guo Zhang , Yong Yang , Ting Hao , Ming Zhang

Polycrystalline boron-doped diamond (BDD) is widely used as a working electrode material in electrochemistry, and its properties, such as its stability, make it an appealing support material for nanostructures for electrocatalytic…

Materials Science · Physics 2023-06-13 Shayantan Chaudhuri , Andrew J. Logsdail , Reinhard J. Maurer

Ultra-small, low-strain, artificially produced diamonds with an internal, active color center have substantial potential for quantum information processing and biomedical applications. Thus, it is of great importance to be able to…

The eventual presence of the diamond carbon allotrope in space is discussed in numerous theoretical and experimental studies. The review summarizes the principal mechanisms of nanodiamond formation and experimental results of spectroscopic…

Earth and Planetary Astrophysics · Physics 2024-07-30 A. A. Shiryaev

The discovery of novel carbon allotropes with tailored thermal and mechanical properties is critical for advanced thermal management. However, exploring the vast configurational space of carbon using \textit{ab initio} calculations remains…

Materials Science · Physics 2026-03-11 Yuzhou Hao , Yujie Liu , Xuejie Li , Turab Lookman , Xiangdong Ding , Jun Sun , Zhibin Gao

We present density-functional theory calculations of Ru 3d and O 1s surface core-level shifts (SCLSs) at an oxygen-rich Ru(0001) surface, namely for the O(1x1)/Ru(0001) chemisorption phase and for two surface terminations of fully oxidized…

Materials Science · Physics 2009-11-07 Karsten Reuter , Matthias Scheffler

The magnetic properties of the alkaline earth oxocuprate BaCu3O4 are investigated. We show that the characteristic Cu3O4 layers of this material can be described with diamond chains of antiferromagnetically coupled Cu 1/2 spins with only a…

Strongly Correlated Electrons · Physics 2012-04-18 Carl-Willem Rischau , Brigitte Leridon , Dorothée Colson , Anne Forget , Philippe Monod

Probing electrical and magnetic properties in aqueous environments remains a frontier challenge in nanoscale sensing. Our inability to do so with quantitative accuracy imposes severe limitations, for example, on our understanding of the…