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Sum-frequency generation (SFG) is a powerful second-order nonlinear spectroscopic technique that provides detailed insights into molecular structures and absolute orientations at surfaces and interfaces. However, conventional SFG based on…

Vibrational sum- and difference-frequency generation (SFG and DFG) spectroscopy probes the nonlinear response of interfaces at mid-infrared (MIR) wavelengths while detecting upconverted signals in the visible. Recent work has moved from…

We introduce sum-frequency generation (SFG) as an effective physical two-photon detector for high power two-mode squeezed coherent states with arbitrary frequency separation, as produced by parametric oscillators well above the threshold.…

Optics · Physics 2013-10-30 Faina Shikerman , Avi Pe'er

Sum-frequency generation (SFG) is a second-order nonlinear process widely used for characterizing surfaces and interfaces with monolayer sensitivity. Recently, optical field enhancement in plasmonic nanocavities has enabled SFG with…

Vibrational sum frequency generation (SFG) is a nonlinear spectroscopic technique widely used to study the molecular structure and dynamics of surface systems. However, the spatial resolution achieved by far-field observations is…

Plasmonic nanostructures that support surface plasmon (SP) resonance potentially provide a route for the development of nanoengineered nonlinear optical devices. In this work, second-order nonlinear light scattering, specifically…

Computational Physics · Physics 2016-12-20 Xiaoyan Y. Z. Xiong , Li Jun Jiang , Wei E. I. Sha , Yat Hei Lo , Weng Cho Chew

Second-harmonic generation (SHG) is a direct measure of the strength of second-order nonlinear optical effects, which also include frequency mixing and parametric oscillations. Natural and artificial materials with broken…

Vibrational sum frequency generation (SFG) spectroscopy is a powerful technique for investigating molecular structures, orientations, and dynamics at surfaces. However, its spatial resolution is fundamentally restricted to the micrometer…

We experimentally demonstrate shaping of the two-photon wavefunction of entangled photon-pairs, utilizing coherent pulse-shaping techniques. By performing spectral-phase manipulations we tailor the two-photon wavefunction exactly like a…

Quantum Physics · Physics 2011-12-06 Avi pe'er , Barak Dayan , Asher A. Friesem , Yaron Silberberg

Sum frequency generation (SFG) has multiple applications, from optical sources to imaging, where efficient conversion requires either long interaction distances or large field concentrations in a quadratic nonlinear material. Metasurfaces…

Optics · Physics 2024-08-22 Neuton Li , Jihua Zhang , Dragomir N. Neshev , Andrey A. Sukhorukov

We propose non-phase-matched sum frequency generation (SFG) as a method for characterizing broadband multimode light. We demonstrate its advantages using high-gain parametric down conversion (PDC) as an example. By generating the sum…

Quantum Physics · Physics 2019-05-22 Denis A. Kopylov , Kirill Yu. Spasibko , Tatiana V. Murzina , Maria V. Chekhova

We experimentally demonstrate sum-frequency generation (SFG) with entangled photon-pairs, generating as many as 40,000 SFG photons per second, visible even to the naked eye. The nonclassical nature of the interaction is exhibited by a…

Quantum Physics · Physics 2007-05-23 Barak Dayan , Avi pe'er , Asher A. Friesem , Yaron Silberberg

Sum-frequency generation (SFG) spectroscopy provides a versatile method for the investigation of non-centrosymmetric media and interfaces. Here, using tunable picosecond infrared (IR) pulses from a free-electron laser, the nonlinear optical…

Materials Science · Physics 2023-08-01 Riko Kiessling , Martin Wolf , Alexander Paarmann

Moving the detection wavelength in vibrational sum-frequency generation (VSFG) spectroscopy to the near-infrared (> 700 nm) can potentially enable the study of molecular interfaces absorbing in the visible and give access to buried…

Optics · Physics 2024-05-10 Zsuzsanna Heiner , Valentin Petrov , Mark Mero

The formation of diatomic molecules with rotational and vibrational coherence is demonstrated experimentally in free-to-bound two-photon femtosecond photoassociation of hot atoms. In a thermal gas at a temperature of 1000 K, pairs of…

We propose and experimentally demonstrate a scheme allowing to reach noncollinear phase-matching of high harmonic generation in solids, which may potentially lead to an enhancement of the generation efficiency. The principle is based on…

Optics · Physics 2026-02-24 Pavel Peterka , František Trojánek , Petr Malý , Martin Kozák

We propose a computational framework to extract non-linear response functions from real-time simulations in the presence of more than one external field. We apply this approach to the calculation of sum frequency generation (SFG) and…

Materials Science · Physics 2025-11-19 Mike N. Pionteck , Myrta Grüning , Simone Sanna , Claudio Attaccalite

Much work over the last 25 years has demonstrated that the interface-specific, alloptical technique, vibrational sum frequency generation (v-SFG) spectroscopy, is often uniquely capable of characterizing the structure and dynamics of…

Optics · Physics 2018-11-14 Martin Thämer , R. Kramer Campen , Martin Wolf

Experimental insight into the elementary processes underlying charge transfer across interfaces has blossomed with the wide-spread availability of ultra-high vacuum set-ups that allow the preparation and characterization of solid surfaces…

Chemical Physics · Physics 2024-02-27 Zhipeng Huang , Tobias Roos , Yujin Tong , R. Kramer Campen

The optimal properties for single photons may vary drastically between different quantum technologies. Along with central frequency conversion, control over photonic temporal waveforms will be paramount to the effective coupling of…

Quantum Physics · Physics 2015-03-10 John M. Donohue , Michael D. Mazurek , Kevin J. Resch
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