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An ab initio Hartree-Fock approach aimed at directly obtaining the localized orthogonal orbitals (Wannier functions) of a crystalline insulator is described in detail. The method is used to perform all-electron calculations on the ground…

Condensed Matter · Physics 2009-10-30 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

The momentum-space derivatives of Bloch wavefunctions are essential for studying quantum geometry and the equilibrium and response properties of solids. In practical first-principles calculations, these derivatives are obtained via Wannier…

Materials Science · Physics 2026-04-27 Jae-Mo Lihm , Minsu Ghim , Seung-Ju Hong , Cheol-Hwan Park

We present a general method of constructing maximally localized Wannier functions. It consists of three steps: (1) picking a localized trial wave function, (2) performing a full band projection, and (3) orthonormalizing with the Lowdin…

Other Condensed Matter · Physics 2017-01-11 Junbo Zhu , Zhu Chen , Biao Wu

Maximally localized Wannier functions (MLWFs) are widely used to construct first-principles tight-binding models that accurately reproduce the electronic structure of materials. Recently, robust and automated approaches to generate these…

Computational Physics · Physics 2023-11-02 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari

A recently proposed approach for performing electronic-structure calculations on crystalline insulators in terms of localized orthogonal orbitals is applied to the oxides of lithium and sodium, Li2O and Na2O. Cohesive energies, lattice…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

Wannier functions have become a powerful tool in the electronic structure calculations of extended systems. The generalized Pipek-Mezey Wannier functions exhibit appealing characteristics (e.g., reaching an optimal localization and the…

Materials Science · Physics 2022-04-04 Guorong Weng , Mariya Romanova , Arsineh Apelian , Hanbin Song , Vojtěch Vlček

We propose a numerical method using the discrete variable representation (DVR) for constructing real-valued Wannier functions localized in a unit cell for both symmetric and asymmetric periodic potentials. We apply these results to finding…

Quantum Gases · Physics 2016-09-14 Saurabh Paul , Eite Tiesinga

Wannier90 is an open-source computer program for calculating maximally-localised Wannier functions (MLWFs) from a set of Bloch states. It is interfaced to many widely used electronic-structure codes thanks to its independence from the basis…

Position scaling-eigenfunctions are generated by transforming compactly supported orthonormal scaling functions and utilized for faster alternatives to maximally localized Wannier functions (MLWFs). The position scaling-eigenfunctions are…

Mesoscale and Nanoscale Physics · Physics 2023-12-18 Yuji Hamai , Katsunori Wakabayashi

Maximally-localized Wannier functions (MLWFs) are a powerful and broadly used tool to characterize the electronic structure of materials, from chemical bonding to dielectric response to topological properties. Most generally, one can…

Computational Physics · Physics 2023-11-07 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari

We present a semi-automated method for obtaining an initial estimate of Wannier functions, designed to facilitate the construction of Wannier functions for describing low-energy effective models of solids, particularly those relevant to…

Strongly Correlated Electrons · Physics 2025-12-24 Tatsuki Oikawa , Kota Ido , Takahiro Misawa , Takashi Koretsune , Kazuyoshi Yoshimi

The exponential localization of Wannier functions in two or three dimensions is proven for all insulators that display time-reversal symmetry, settling a long-standing conjecture. Our proof relies on the equivalence between the existence of…

We report a theoretical scheme that enables the calculation of maximally localized Wannier functions in the formalism of projector-augmented-waves (PAW) which also includes the ultrasoft-pseudopotential (USPP) approach. We give a…

Soft Condensed Matter · Physics 2007-05-23 Andrea Ferretti , Arrigo Calzolari , Benedetta Bonferroni , Rosa Di Felice

We present a study of the construction and spatial properties of localized Wannier orbitals in large supercells of insulating solids using plane waves as the underlying basis. The Pipek-Mezey (PM) functional in combination with intrinsic…

Chemical Physics · Physics 2025-10-22 Benjamin Wöckinger , Alexander Rumpf , Tobias Schäfer

We use the maximally-localized Wannier function method to study bonding properties in amorphous silicon. This study represents, to our knowledge, the first application of the Wannier-function analysis to a disordered system. Our results…

Materials Science · Physics 2009-10-31 Pier Luigi Silvestrelli , Nicola Marzari , David Vanderbilt , Michele Parrinello

We report the numerical and experimental study of elastic Wannier-Stark Ladders and Bloch Oscillations in a tunable one-dimensional granular chain consisting of cylindrical particles. The Wannier-Stark Ladders are obtained by tuning the…

Mesoscale and Nanoscale Physics · Physics 2018-03-20 Xiaotian Shi , Rajesh Chaunsali , Ying Wu , Jinkyu Yang

We consider the applicability of phase space Wannier functions" to electronic structure calculations. These generalized Wannier functions are analogous to localized plane waves and constitute a complete, orthonormal set which is…

Other Condensed Matter · Physics 2010-07-22 D. J. Sullivan , J. J. Rehr , J. W. Wilkins , K. G. Wilson

Time-dependent Wannier functions were initially proposed as a means for calculating the polarization current in crystals driven by external fields. In this work, we present a simple gauge where Wannier states are defined based on the…

Materials Science · Physics 2024-10-29 Cristian M. Le , Hannes Hübener , Ofer Neufeld , Angel Rubio

We consider collocated wireless sensor networks, where each node has a Boolean measurement and the goal is to compute a given Boolean function of these measurements. We first consider the worst case setting and study optimal block…

Information Theory · Computer Science 2011-05-09 Hemant Kowshik , P. R. Kumar

In this paper we present an approach aimed at performing many-body calculations of Born-effective charges of crystalline insulators, by including the electron-correlation effects. The scheme is implemented entirely in the real space, using…

Materials Science · Physics 2010-01-14 Priya Sony , Alok Shukla