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Density functional theory (DFT) has become the most popular approach to electronic structure across disciplines, especially in material and chemical sciences. Last year, at least 30,000 papers used DFT to make useful predictions or give…

Chemical Physics · Physics 2017-01-05 Justin C. Smith , Francisca Sagredo , Kieron Burke

We introduce a quasiclassical Green function approach describing the unitary yet irreversible dynamics of quantum systems effectively acting as their own environment. Combining a variety of concepts of quantum many-body theory, notably the…

Mesoscale and Nanoscale Physics · Physics 2025-09-09 Alexander Altland , Kun Woo Kim , Tobias Micklitz

The entropy produced when a system undergoes an infinitesimal quench is directly linked to the work parameter susceptibility, making it sensitive to the existence of a quantum critical point. Its singular behavior at $T=0$, however,…

Quantum Physics · Physics 2022-07-13 Adalberto D. Varizi , Raphael C. Drumond , Gabriel T. Landi

This work continues the investigation in two recent papers on the quantum thermodynamics of spacetimes, 1) placing what was studied in [1] for thermal quantum fields in the context of early universe cosmology, and 2) extending the…

High Energy Physics - Theory · Physics 2024-11-26 Jen-Tsung Hsiang , Yu-Cun Xie , Bei-Lok Hu

Lack of knowledge about the detailed many-particle motion on the microscopic scale is a key issue in any theoretical description of a macroscopic experiment. For systems at or close to thermal equilibrium, statistical mechanics provides a…

Statistical Mechanics · Physics 2016-03-03 Peter Reimann

The role of quantum entanglement in thermodynamical systems remains elusive. Does entanglement result in thermodynamic advantages or does it impose fundamental limitations? Here, we unambiguously quantify the amount of heat and work in a…

Quantum Physics · Physics 2026-03-23 Joan Alba , Laura Ares , Jan Sperling , Julien Pinske

The aim of this book chapter is to indicate how quantum phenomena are affecting the operation of microscopic thermal machines, such as engines and refrigerators. As converting heat to work is one of the fundamental concerns in…

Quantum Physics · Physics 2019-05-01 Amikam Levy , David Gelbwaser-Klimovsky

Warm dense matter is a highly energetic phase characterized by strong correlations, thermal effects, and quantum effects of electrons. Thermal density functional theory is commonly used in simulations of this challenging phase, driving the…

Strongly Correlated Electrons · Physics 2025-09-10 Brittany P. Harding , Francisca Sagredo , Vincent Martinetto , Aurora Pribram-Jones

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines,…

Quantum Physics · Physics 2016-11-23 R. Gallego , J. Eisert , H. Wilming

We consider quantum nonlinear many-body systems with dissipation described within the Caldeira-Leggett model, i.e., by a nonlocal action in the path integral for the density matrix. Approximate classical-like formulas for thermodynamic…

Statistical Mechanics · Physics 2009-10-31 A. Cuccoli , A. Fubini , V. Tognetti , R. Vaia

Thermodynamics of quantum systems and quantum thermal machines are rapidly developing fields, which have already delivered several promising results, as well as raised many intriguing questions. Many-body quantum machines present new…

Quantum Physics · Physics 2021-09-22 Victor Mukherjee , Uma Divakaran

The many-body space fractional quantum system is studied using the density matrix method. We give the new results of the Thomas-Fermi model, and obtain the quantum pressure of the free electron gas. We also show the validity of the…

Mathematical Physics · Physics 2011-06-27 Jianping Dong

We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed…

Quantum Physics · Physics 2015-01-20 F. Plastina , A. Alecce , T. J. G. Apollaro , G. Falcone , G. Francica , F. Galve , N. Lo Gullo , R. Zambrini

Quantum thermodynamics aims to explore quantum features to enhance energy conversion beyond classical limits. While significant progress has been made, the understanding of caloric potentials in quantum systems remains incomplete. In this…

Quantum Physics · Physics 2025-02-27 Clebson Cruz , J. S. Amaral , Mario Reis

Using a central limit theorem for arrays of interacting quantum systems, we give analytical expressions for the density of states and the partition function at finite temperature of such a system, which are valid in the limit of infinite…

Statistical Mechanics · Physics 2009-11-10 Michael Hartmann , Guenter Mahler , Ortwin Hess

The Hohenberg-Kohn theorem and the Kohn-Sham equations, which are at the basis of the Density Functional Theory, are reformulated in terms of a particular many-body density, which is translational invariant and therefore is relevant for…

Nuclear Theory · Physics 2021-09-29 A. Kievsky , G. Orlandini , M. Gattobigio

How to rigorously define thermodynamic quantities such as heat, work, and internal energy in open quantum systems driven far from equilibrium remains a significant open question in quantum thermodynamics. Heat is a quantity whose…

Mesoscale and Nanoscale Physics · Physics 2023-07-18 Parth Kumar , Charles A. Stafford

Universal exact conditions guided the construction of most ground-state density functional approximations in use today. We derive the relation between the entropy and Mermin free energy density functionals for thermal density functional…

Chemical Physics · Physics 2016-05-25 Kieron Burke , Justin C. Smith , Paul E. Grabowski , Aurora Pribram-Jones

Energy functionals serve as the basis for different models and methods in quantum and classical many-particle physics. Arguably, one of the most successful and widely used approaches in material science at both ambient and extreme…

Plasma Physics · Physics 2024-10-22 Z. Moldabekov , J. Vorberger , T. Dornheim

Simulation of warm dense matter requires computational methods that capture both quantum and classical behavior efficiently under high-temperature, high-density conditions. Currently, density functional theory molecular dynamics is used to…

Chemical Physics · Physics 2015-10-21 Attila Cangi , Aurora Pribram-Jones
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