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We review recent ab initio molecular dynamics studies of electrode/electrolyte interfaces in lithium ion batteries. Our goals are to introduce experimentalists to simulation techniques applicable to models which are arguably most faithful…

Materials Science · Physics 2013-04-23 Kevin Leung

All-solid-state batteries (ASSBs) offer a promising route to safer batteries with superior energy density compared to conventional Li-ion batteries (LIBs). However, the design of the composite cathode and optimization of the underlying…

The participation of oxygen or other anionic species in redox activities in cathode materials for lithium and sodium-ion battery systems is known to play a role in governing the useful capacity of these batteries. Directly probing anionic…

Materials Science · Physics 2024-08-20 M. Hussein N. Assadi , Dorian A. H. Hanaor

We compile data and machine learned models of solid Li-ion electrolyte performance to assess the state of materials discovery efforts and build new insights for future efforts. Candidate electrolyte materials must satisfy several…

Materials Science · Physics 2019-04-22 Austin D. Sendek , Gowoon Cheon , Mauro Pasta , Evan J. Reed

This manuscript explores recent advancements in solid-state sodium-based battery technology, particularly focusing on electrochemical performance and the challenges associated with developing efficient solid electrolytes. The replacement of…

Lithium-ion batteries dominate battery research and industry due to their long research history and high energy density. However, increasing demand and limited lithium resources have raised lithium prices and battery costs, motivating…

Materials Science · Physics 2025-12-17 Caolin Ua Tuiscint , Jonathan N Coleman

A comprehensive understanding of the electrode-electrolyte interface in energy conversion systems remains challenging due to the complex and multifaceted nature of interfacial processes. This complexity hinders the development of more…

Chemical Physics · Physics 2024-10-23 Ben Wang , Tomohiro Fukushima , Hiro Minamimoto , Andrey Lyalin , Kei Murakoshi , Tetsuya Taketsugu

We present a thermodynamic analysis of the driving forces for intercalation and conversion reactions in battery cathodes across a range of possible working ion, transition metal, and anion chemistries. Using this body of results, we analyze…

Materials Science · Physics 2018-04-19 Daniel C. Hannah , Gopalakrishnan Sai Gautam , Pieremanuele Canepa , Gerbrand Ceder

Here we report fabrication of flexible and stretchable battery composed of strain free LiFePO4 cathode, Li4Ti5O10 anode and a solid poly ethylene oxide (PEO) electrolyte as a separator layer. The battery is developed in a view of smart…

Materials Science · Physics 2015-03-13 Yang Liu , Maksim Skorobogatiy

We introduce an adhesion parameter that enables rapid screening for materials interfaces with high adhesion. This parameter is obtained by density functional theory calculations of individual single-material slabs rather than slabs…

In this work, we introduce a novel workflow that couples robotics to machine-learning for efficient optimization of a non-aqueous battery electrolyte. A custom-built automated experiment named "Clio" is coupled to Dragonfly - a Bayesian…

Machine Learning · Computer Science 2022-10-12 Adarsh Dave , Jared Mitchell , Sven Burke , Hongyi Lin , Jay Whitacre , Venkatasubramanian Viswanathan

Electric Vehicle (EV) penetration and renewable energies enables synergies between energy supply, vehicle users, and the mobility sector. However, also new issues arise for car manufacturers: During charging and discharging of EV batteries…

Other Computer Science · Computer Science 2019-10-17 Karl Schwenk , Tim Harr , René Großmann , Riccardo Remo Appino , Veit Hagenmeyer , Ralf Mikut

Rechargeable lithium-ion (Li-ion) batteries are a ubiquitous element of modern technology. In the last decades, the production and design of such batteries and their adjacent embedded charging and safety protocols, denoted by Battery…

Systems and Control · Electrical Eng. & Systems 2025-09-09 Rudi Coppola , Hovsep Touloujian , Pierfrancesco Ombrini , Manuel Mazo

A model of a lithium-ion battery containing a cosolvent electrolyte is developed and implemented within the open-source PyBaMM platform. Lithium-ion electrolytes are essential to battery operation and normally contain at least two solvents…

Dynamic models of the battery performance are an essential tool throughout the development process of automotive drive trains. The present study introduces a method making a large data set suitable for modeling the electrical impedance.…

Machine Learning · Computer Science 2020-12-08 Philipp Gesner , Christian Gletter , Florian Landenberger , Frank Kirschbaum , Lutz Morawietz , Bernard Bäker

Selecting materials for hybrid cathodes for batteries, which combine intercalation and conversion materials, has gained interest due to their unique synergistic properties, which are not achievable by homogeneous materials. Here, we present…

Materials Science · Physics 2024-10-28 Ahmed H. Biby , Benjamin S. Rich , Charles B. Musgrave

In this paper, we introduce a density-based topology optimization framework to design porous electrodes for maximum energy storage. We simulate the full cell with a model that incorporates electronic potential, ionic potential, and…

Polymer electrolytes (PEs) are promising candidates for use in next-generation high-voltage batteries, as they possess advantageous elastic and electrochemical properties. However, PEs still suffer from low ionic conductivity and need to be…

We present a coupled continuum formulation for the electrostatic, chemical, thermal, mechanical and fluid physics in battery materials. Our treatment is at the particle scale, at which the active particles held together by carbon-binders,…

Computational Physics · Physics 2018-07-26 Zhenlin Wang , Krishna Garikipati

Fast-charging of lithium-ion batteries is essential for electric vehicle adoption, but aggressive charging can accelerate its degradation and create safety risks. This study investigates a control framework that coordinates charging current…

Systems and Control · Electrical Eng. & Systems 2026-05-26 Frederic Fabry , Alessio Lodge , Robinson Medina , Feye Hoekstra , Steven Wilkins , Madalin Frunzete