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Molecular nanomagnets show clear signatures of coherent behavior and have a wide variety of effective low-energy spin Hamiltonians suitable for encoding qubits and implementing spin-based quantum information processing. At the nanoscale,…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Mircea Trif , Filippo Troiani , Dimitrije Stepanenko , Daniel Loss

Individual magnetic molecules are promising building blocks for quantum technologies because of their chemical tunability, nanoscale dimensions, and ability to self-assemble into ordered arrays. However, harnessing their properties in…

Electrical control of spins at the nanoscale offers significant architectural advantages in spintronics, because electric fields can be confined over shorter length scales than magnetic fields. Thus, recent demonstrations of electric-field…

Mesoscale and Nanoscale Physics · Physics 2021-10-15 Junjie Liu , Jakub Mrozek , Aman Ullah , Yan Duan , José J. Baldoví , Eugenio Coronado , Alejandro Gaita-Ariño , Arzhang Ardavan

Coherent control of individual molecular spins in nano-devices is a pivotal prerequisite for fulfilling the potential promised by molecular spintronics. By applying electric field pulses during time-resolved electron spin resonance…

We study the triangular antiferromagnet Cu$_3$ in external electric fields, using symmetry group arguments and a Hubbard model approach. We identify a spin-electric coupling caused by an interplay between spin exchange, spin-orbit…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Mircea Trif , Filippo Troiani , Dimitrije Stepanenko , Daniel Loss

We report the existence of a sizeable quantum tunnelling splitting between the two lowest electronic spin levels of mononuclear Ni complexes. The level anti-crossing, or magnetic clock transition, associated with this gap has been directly…

Molecular spin clusters are mesoscopic systems whose structural and physical features can be tailored at the synthetic level. Besides, their quantum behavior is directly accessible in laboratory and their magnetic properties can be…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 F. Troiani , V. Bellini , A. Candini , G. Lorusso , M. Affronte

The design and control of atomic-scale spin structures constitute major challenges for spin-based quantum technology platforms, including quantum dots, color centers, and molecular spins. Here, we showcase a strategy for designing the…

Precise control of spin states and spin-spin interactions in atomic-scale magnetic structures is crucial for spin-based quantum technologies. A promising architecture is molecular spin systems, which offer chemical tunability and…

Frustrated triangular molecular magnets are a very important class of magnetic molecules since the absence of inversion symmetry allows an external electric field to couple directly with the spin chirality that characterizes their ground…

Mesoscale and Nanoscale Physics · Physics 2023-06-14 J. F. Nossa , M. F. Islam , Mark R. Pederson , C. M. Canali

Novel understanding of the recent nanomagnet tailoring experiments and the possibility to further unveil the mechanisms by which the magnetic interactions arise in an atom by atom fashion covers importance as the demand for spin qubit and…

We experimentally demonstrate an approach to scale up quantum devices by harnessing spin defects in the environment of a quantum probe. We follow this approach to identify, locate, and control two electron-nuclear spin defects in the…

Quantum Physics · Physics 2020-03-04 Alexandre Cooper , Won Kyu Calvin Sun , Jean-Christophe Jaskula , Paola Cappellaro

The chiral $Fe_3O(NC_5H_5)_3(O_2CC_6H_5)_6$ molecular cation, with C$_3$ symmetry, is composed of three six-fold coordinated spin-carrying Fe$^{3+}$ cations that form a perfect equilateral triangle. Experimental reports demonstrating the…

Materials Science · Physics 2019-11-06 Alexander I Johnson , M. Fhokrul Islam , Carlo M. Canali , Mark R Pederson

Electric fields represent an ideal means for controlling spins at the nanoscale and, more specifically, for manipulating protected degrees of freedom in multispin systems. Here we perform low-temperature magnetic far-IR spectroscopy on a…

Mesoscale and Nanoscale Physics · Physics 2025-02-03 Florian le Mardelé , Ivan Mohelský , Jan Wyzula , Milan Orlita , Philippe Turek , Filippo Troiani , Athanassios K. Boudalis

Tunable synthetic spin-orbit coupling (s-SOC) is one of the key challenges in various quantum systems, such as ultracold atomic gases, topological superconductors, and semiconductor quantum dots. Here we experimentally demonstrate…

We develop energy efficient, continuous microwave schemes to couple electron and nuclear spins, using phase or amplitude modulation to bridge their frequency difference. These controls have promising applications in biological systems,…

Quantum Physics · Physics 2019-01-14 J. Casanova , E. Torrontegui , M. B. Plenio , J. J. García-Ripoll , E. Solano

We consider electrical transport through molecules with Heisenberg-coupled spins arranged in a ring structure in the presence of an easy-axis anisotropy. The molecules are coupled to two metallic leads and a gate. In the charged state of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jörg Lehmann , Daniel Loss

The ability to design quantum systems that decouple from environmental noise sources is highly desirable for development of quantum technologies with optimal coherence. The chemical tunability of electronic states in magnetic molecules…

Single magnetic molecules may be the smallest functional magnets. An electric-field controllable spin state of magnetic molecules is of fundamental importance for applications while its realization remains challenging. To date the observed…

Materials Science · Physics 2022-12-16 Yan Lu , Yunlong Wang , Linghan Zhu , Li Yang , Li Wang

We have fabricated hybrid magnetic complexes from V atoms and tetracyanoethylene (TCNE) ligands via atomic manipulation with a cryogenic scanning tunneling microscope. Using tunneling spectroscopy we observe spin-polarized molecular…

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