Related papers: Cosmic-ray induced sputtering of interstellar form…
We present Spitzer IRS spectroscopy of CO2 ice bending mode spectra at 15.2 micrometer toward 19 young stellar objects with luminosity lower than 1 Lsun (3 with luminosity lower than 0.1 Lsun). Ice on dust grain surfaces can encode the…
UV-induced photodesorption of ice is a non-thermal evaporation process that can explain the presence of cold molecular gas in a range of interstellar regions. Information on the average UV photodesorption yield of astrophysically important…
$Context.$ The quantification of the terahertz (THz) and IR optical properties of astrophysical ice analogs, which have different molecular compositions, phases, and structural properties, is required to model both the continuum emission by…
We report on the effects of cosmic rays (CRs) on the abundance of CO in $\rm H_2$ clouds under conditions typical for star-forming galaxies in the Universe. We discover that this most important molecule for tracing H$_2$ gas is very…
Planet atmosphere and hydrosphere compositions are fundamentally set by accretion of volatiles, and therefore by the division of volatiles between gas and solids in planet-forming disks. For hyper-volatiles such as CO, this division is…
Aims: We wish to separate and quantify the CO luminosity and CO-H2 conversion factor applicable to diffuse but partially-molecular ISM when H2 and CO are present but C+ is the dominant form of gas-phase carbon. Methods: We discuss galactic…
CO$_2$ ice has a phase transition at 35 K when its structure changes from amorphous to crystalline. Using Reflection absorption Infrared Spectroscopy (RAIRS), \"Oberg et al. observed that the photodesorption yield of CO$_2$ ice deposited at…
Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2…
Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…
Ice desorption affects the evolution of the gas-phase chemistry during the protostellar stage, and also determines the chemical composition of comets forming in circumstellar disks. From observations, most volatile species are found in…
(Abridged) Mid- and far-infrared observations of the environment around embedded protostars reveal a plethora of high excitation molecular and atomic emission lines. In this work we present spectro-imaging observations of the HH211 system…
Context: Hydrogenation reactions are expected to be among the most important surface reactions on interstellar ices. However, solid state astrochemical laboratory data on reactions of H-atoms with common interstellar ice constituents are…
Aims: For the first time we investigate the role of the grain surface chemistry in the Horsehead Photo-dissociation region (PDR). Methods: We performed deep observations of several H2CO rotational lines toward the PDR and its associated…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Ionized carbon is the main gas-phase reservoir of carbon in the neutral diffuse interstellar medium and its 158 micron fine structure transition [CII] is the most important cooling line of the diffuse interstellar medium (ISM). We combine…
CO$_2$ is a major component of the icy mantles surrounding dust grains in planet and star formation regions. Understanding its photodesorption is crucial for explaining gas phase abundances in the coldest environments of the interstellar…
Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and by inducing photodesorption. So far, the focus of laboratory…
We present a dedicated experimental study of microscopic mechanisms controlling radiolysis and sputtering of astrophysical ices due to their bombardment by cosmic ray ions. Such ions are slowed down due to inelastic collisions with bound…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
Diffuse interstellar clouds show large abundances of H_3^+ which can be maintained only by a high ionization rate of H_2. Cosmic rays are the dominant ionization mechanism in this environment, so the large ionization rate implies a high…