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In recent years, ultrafast pump-probe spectroscopy has provided insightful information about nonequilibrium dynamics of excitations in materials. In a typical experiment of time-resolved x-ray absorption spectroscopy, the systems are…

Strongly Correlated Electrons · Physics 2019-05-29 Chen-Yen Lai , Jian-Xin Zhu

An accurate treatment of electronic spectra in large systems with a technique such as time dependent density functional theory (TDDFT) is computationally challenging. Due to the Nyquist sampling theorem, direct real time simulations must be…

Materials Science · Physics 2024-01-17 Matthias Kick , Ezra Alexander , Anton Beiersdorfer , Troy Van Voorhis

Transition metals with their densely confined and strongly coupled valence electrons are key constituents of many materials with unconventional properties, such as high-Tc superconductors, Mott insulators and transition-metal…

Atomic Physics · Physics 2020-01-08 M. Volkov , S. A. Sato , F. Schlaepfer , L. Kasmi , N. Hartmann , M. Lucchini , L. Gallmann , A. Rubio , U. Keller

In the limit of low adatom concentration, we obtain exact analytic expressions for the local and total density of states (LDOS, TDOS) for a tight-binding model of adatoms on graphene. The model is not limited to nearest-neighbor hopping but…

Mesoscale and Nanoscale Physics · Physics 2014-03-21 Nicholas A. Pike , David Stroud

Phase and time delays of atomic above-threshold ionization were recently experimentally explored in an $\omega -2\omega$ setting [Zipp et al, Optica 1, 361 (2014)]. The phases of wavepackets ejected from argon by a strong $2\omega$ pulse…

Atomic Physics · Physics 2022-11-23 Diego G. Arbó , Sebastián D. López , Joachim Burgdörfer

In many mechanical, electrical, and general physical systems evolving over time or space, spectral analysis methods as Fast Fourier Transform (FFT), Short Term Fourier Transform (STFT), Power Spectrum Density (PSD) plays a very important…

Signal Processing · Electrical Eng. & Systems 2023-06-21 Andreas Tuor , Nico Canzani , Tobias Rüggeberg , Stefan Gorenflo , Gerd Simons , Bruno Bättig , Daniel Iseli

Probing vibronic coherence in molecules has been a central topic in ultrafast science, as it is an essential prerequisite to monitoring electronic motion. While experiments have demonstrated that attosecond transient absorption spectroscopy…

Atomic Physics · Physics 2023-08-02 C. H. Yuen , C. D. Lin

Ultrafast, time-resolved spectroscopies enable the direct observation of non-equilibrium processes in condensed-phase systems and have revealed key insights into energy transport, hydrogen-bond dynamics, and vibrational coupling. While ab…

Chemical Physics · Physics 2025-09-01 Kit Joll , Philipp Schienbein

Modern bandgap engineered electronic devices are typically made of multi-semiconductor multi-layer heterostructures that pose a major challenge to silicon-era characterization methods. As a result, contemporary bandgap engineering relies…

Applied Physics · Physics 2018-01-18 Yury Turkulets , Ilan Shalish

Time-dependent density functional theory (TDDFT) is a standard approach for calculating optical excitations of molecules and solids, while ensemble DFT (EDFT) is a promising alternative under development. We introduce ensemble TDDFT…

Chemical Physics · Physics 2026-05-22 Kimberly J. Daas , Steven Crisostomo , Kieron Burke

In this manuscript we present a theoretical framework and its numerical implementation to simulate the out-of-equilibrium electron dynamics induced by the interaction of ultrashort laser pulses in condensed-matter systems. Our approach is…

The atomistic resolution recently achieved by ultrafast spectroscopies demands corresponding theoretical advances. Real-time time-dependent density-functional theory (RT-TDDFT) with Ehrenfest dynamics offers an optimal trade-off between…

Materials Science · Physics 2022-10-19 Jannis Krumland , Matheus Jacobs , Caterina Cocchi

We investigate theoretically charge migration following prompt double ionization of a polyatomic molecule (C$_2$H$_4$BrI) and find that for double ionization, correlation-driven charge migration appears to be particularly prominent, i.e.,…

Chemical Physics · Physics 2016-05-24 Maximilian Hollstein , Robin Santra , Daniela Pfannkuche

Time-resolved photoemission spectroscopy provides a unique and direct way to explore the real-time nonequilibrium dynamics of electrons and holes. The formal theory of the spectral function evolution requires inclusion of electronic…

Materials Science · Physics 2025-05-09 Thomas Blommel , Enrico Perfetto , Gianluca Stefanucci , Vojtěch Vlček

Accurate and efficient simulation of excited state properties is an important and much aspired cornerstone in the study of adsorbate dynamics on metal surfaces. To this end, the recently proposed linear expansion \Delta Self-Consistent…

Materials Science · Physics 2013-07-23 Reinhard J. Maurer , Karsten Reuter

This chapter provides a basic introduction to excited-state extensions of density functional theory (DFT), including time-dependent (TD-)DFT in both its linear-response and its explicitly time-dependent formulations. As applied to the…

Chemical Physics · Physics 2023-05-02 John M. Herbert

This paper studies the performance of time-dependent density-functional theory (TDDFT) for calculating the dielectric function of semiconductors and insulators at finite momentum transfer, comparing against the standard Bethe-Salpeter…

Materials Science · Physics 2025-03-03 Didarul Alam , Jiuyu Sun , Carsten A. Ullrich

We present a new method to accelerate real time-time dependent density functional theory (rt-TDDFT) calculations with hybrid exchange-correlation functionals. For large basis set, the computational bottleneck for large scale calculations is…

Computational Physics · Physics 2019-07-24 Weile Jia , Lin Lin

Exploiting high-energy electron beams colliding into high-intensity laser pulses brings an opportunity to reach high values of the dimensionless rest-frame acceleration $\chi$ and thereby invoke processes described by strong-field quantum…

Plasma Physics · Physics 2023-03-02 Christoffer Olofsson , Arkady Gonoskov

Dynamical Mean-Field Theory (DMFT) has opened new perspectives for the investigation of strongly correlated electron systems and greatly improved our understanding of correlation effects in models and materials. In contrast to…

Strongly Correlated Electrons · Physics 2020-07-16 Dieter Vollhardt
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