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Methanol and formaldehyde are two simple organic molecules that are ubiquitously detected in the interstellar medium. An origin in the solid phase and a subsequent nonthermal desorption into the gas phase is often invoked to explain their…

Astrophysics of Galaxies · Physics 2016-04-20 R. Martín-Doménech , G. M. Muñoz Caro , G. A. Cruz-Díaz

It has been implicitly assumed that ices on grains in molecular clouds and proto planetary disks are formed by homogeneous layers regardless of their composition or crystallinity. To verify this assumption, we observed the H2O deposition…

We present a novel framework to self-consistently model the effects of radiation fields, dust physics and molecular chemistry (H$_2$) in the interstellar medium (ISM) of galaxies. The model combines a state-of-the-art radiation…

Despite the organic molecule inventory detected in Orion KL, acetaldehyde (CH3CHO) -- one of the most ubiquitous interstellar aldehydes -- has not been firmly identified with mm-wave interferometry. We analyze extensive ALMA archival…

The existence of substellar cold H2 globules in planetary nebulae and the mere existence of comets suggest that the physics of cold interstellar gas might be much richer than usually envisioned. We study the case of a cold gaseous medium in…

Astrophysics of Galaxies · Physics 2016-08-08 Andreas Füglistaler , Daniel Pfenniger

The majority of hydrogen in the interstellar medium (ISM) is in atomic form. The transition from atoms to molecules and, in particular, the formation of the H$_2$ molecule, is a key step in cosmic structure formation en route to stars.…

Astrophysics of Galaxies · Physics 2018-10-31 Pei Zuo , Di Li , J. E. G. Peek , Qiang Chang , Xia Zhang , Nicholas chapman , Paul F. Goldsmith , Zhi-Yu Zhang

We present 3-5 micron VLT-ISAAC spectroscopy searching for evidence of methanol ices in edge-on disks of young embedded stars. Examples include the disks of L1489 IRS in Taurus and CRBR 2422.8-3423 in Ophiuchus, the last of which has the…

Astrophysics · Physics 2007-05-23 K. Pontoppidan , E. Dartois , W. -F. Thi , E. F. van Dishoeck

Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…

Astrophysics of Galaxies · Physics 2023-07-26 A. Clément , A. Taillard , V. Wakelam , P. Gratier , J. -C. Loison , E. Dartois , F. Dulieu , J. A. Noble , M. Chabot

Despite its potential reactivity due to ring strain, ethylene oxide (c-C2H4O) is a complex molecule that seems to be stable under the physical conditions of an interstellar dense core; indeed it has been detected towards several high-mass…

Astrophysics of Galaxies · Physics 2015-06-11 A. Occhiogrosso , S. Viti , M. D. Ward , S. D. Price

Despite low elemental abundance of atomic deuterium in interstellar medium (ISM), observational evidences suggest that several species in gas-phase and in ices could be heavily fractionated. We explore various aspects of deuterium…

Astrophysics of Galaxies · Physics 2019-02-05 Ankan Das , Liton Majumdar , Sandip K. Chakrabarti , Dipen Sahu

Orion KL is one of the prime templates of astrochemical and prebiotic chemical studies. We wish to explore more organic molecules with increasing complexity in this region. In particular, we have searched for one of the most complex organic…

Solar and Stellar Astrophysics · Physics 2019-02-13 Yaping Peng , V. M. Rivilla , Li Zhang , J. X. Ge , Bing Zhou

We report detection of moderate to high-mass star formation in an infrared dark cloud (G11.11-0.12) where we discovered class II methanol and water maser emissions at 6.7 GHz and 22.2 GHz, respectively. We also observed the object in…

Astrophysics · Physics 2009-11-13 Thushara Pillai , Friedrich Wyrowski , Karl M. Menten , Endrik Kr"ugel

The study of the formation of molecular hydrogen on low temperature surfaces is of interest both because it allows to explore elementary steps in the heterogeneous catalysis of a simple molecule and because of the applications in…

Chemical Physics · Physics 2008-11-21 G. Vidali , V. Pirronello , L. Li , J. Roser , G. Manico , R. Mehl , A. Lederhendler , H. B. Perets , J. R. Brucato , O. Biham

Ice naturally forms in the disordered or ``amorphous'' state when accreted from vapor at temperatures and pressures found in the interstellar medium and in the frigid, low density outer regions of the Sun's protoplanetary disk. It is…

Earth and Planetary Astrophysics · Physics 2022-09-14 Dina Prialnik , David Jewitt

Context. The chemical evolution of formamide (HCONH2), a molecule of astrobiological interest that has been tentatively identified in interstellar ices and in cometary coma, has been studied in laboratory under simulated astrophysical…

Astrophysics · Physics 2009-11-11 John R. Brucato , Giuseppa A. Baratta , Giovanni Strazzulla

Whether ice in cold cosmic environments is physically separated from the silicate dust or mixed with individual silicate moieties is not known. However, different grain models give very different compositions and temperatures of grains. The…

Astrophysics of Galaxies · Physics 2020-08-26 Alexey Potapov , Jeroen Bouwman , Cornelia Jäger , Thomas Henning

Aims: The large abundances of CH$^+$ in the diffuse interstellar medium (ISM) are a long standing issue of our understanding of the thermodynamical and chemical states of the gas. We investigate, here, the formation of CH+ in turbulent and…

Astrophysics of Galaxies · Physics 2023-01-18 Benjamin Godard , Guillaume Pineau Des Forêts , Patrick Hennebelle , Elena Bellomi , Valeska Valdivia

Carbon disulfide (CS$_2$) is one of the sulfur-bearing species expected to be present in the interstellar medium (ISM). In this study, we investigated the surface reactions of solid CS$_2$ with hydrogen (H) atoms on amorphous solid water…

In recent astrochemical studies it has become crucial to study all the complete conformational panorama of the molecule, some of which are potentially detectable in the interstellar medium (ISM). In this context, the isomeric ratio can be…

Astrophysics of Galaxies · Physics 2025-06-04 Miguel Sanz-Novo , Germán Molpeceres , Víctor M. Rivilla , Izaskun Jiménez-Serra

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…

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