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Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The…

Solar and Stellar Astrophysics · Physics 2018-05-02 N. F. W. Ligterink , C. Walsh , R. G. Bhuin , S. Vissapragada , J. Terwisscha van Scheltinga , H. Linnartz

The fate of metals ejected by young OB associations into the Interstellar Medium (ISM) is investigated numerically. In particular, we study the enrichment of the cold gas phase, which is the material that forms molecular clouds. Following…

Astrophysics of Galaxies · Physics 2011-11-09 Evangelia Ntormousi , Andreas Burkert

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is…

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

The formation of methanol (CH3OH) on icy grain mantles during the star formation cycle is mainly associated with the CO freeze-out stage. Yet there are reasons to believe that CH3OH also can form at an earlier period of interstellar ice…

Astrophysics of Galaxies · Physics 2018-05-02 D. Qasim , K. -J. Chuang , G. Fedoseev , S. Ioppolo , A. C. A. Boogert , H. Linnartz

Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in…

Astrophysics of Galaxies · Physics 2026-01-14 K. -Y. Huang , E. Méndez-Robayo , S. Viti , Mario -A. Higuera -G

Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…

Astrophysics · Physics 2007-05-23 A. C. A. Boogert , P. Ehrenfreund

Dimethyl ether is one of the most abundant interstellar complex organic molecules. Yet its formation route remains elusive. In this work, we have performed electronic structure and kinetics calculations to derive the rate coefficients for…

[Abridged] Ethylene oxide and its isomer acetaldehyde are important complex organic molecules because of their potential role in the formation of amino acids. Despite the fact that acetaldehyde is ubiquitous in the interstellar medium,…

Solar and Stellar Astrophysics · Physics 2014-05-08 A. Occhiogrosso , A. Vasyunin , E. Herbst , S. Viti , M. D. Ward , S. D. Price , W. A. Brown

In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…

Astrophysics of Galaxies · Physics 2022-09-07 Alec Paulive , Joshua T. Carder , Eric Herbst

Methanol, one of the simplest complex organic molecules in the Interstellar Medium (ISM), has been shown to be present and extended in cold environments such as starless cores. We aim at studying methanol emission across several starless…

Astrophysics of Galaxies · Physics 2021-12-22 S. Spezzano , A. Fuente , P. Caselli , A. Vasyunin , D. Navarro-Almaida , M. Rodríguez-Baras , A. Punanova , C. Vastel , V. Wakelam

Acetaldehyde is one of the most common and abundant gaseous interstellar complex organic molecules, found in cold and hot regions of the molecular interstellar medium. Its presence in the gas-phase depends on the chemical formation and…

Astrophysics of Galaxies · Physics 2022-09-21 S. Ferrero , F. Grieco , A-S. Ibrahim Mohamed , F. Dulieu , A. Rimola , C. Ceccarelli , C. Nervi , M. Minissale , P. Ugliengo

We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…

Astrophysics of Galaxies · Physics 2023-04-27 Y. Nakai , W. M. C. Sameera , K. Furuya , H. Hidaka , A. Ishibashi , N. Watanabe

The neutral interstellar medium (ISM) inside the Local Bubble (LB) has been known to have properties typical of the warm neutral medium (WNM). However, several recent neutral hydrogen (HI) absorption experiments show evidence for the…

Astrophysics · Physics 2009-06-23 Snezana Stanimirovic

The superheating that usually occurs when a solid is melted by volumetric heating can produce irregular solid-liquid interfaces. Such interfaces can be visualised in ice, where they are sometimes known as Tyndall stars. This paper describes…

Fluid Dynamics · Physics 2015-08-19 Andrew A. Lacey , Matthew G. Hennessy , Peter Harvey , Richard F. Katz

The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of…

Astrophysics of Galaxies · Physics 2017-02-22 V. M. Rivilla , M. T. Beltrán , J. Martín-Pintado , F. Fontani , P. Caselli , R. Cesaroni

The recent discovery of methyl formate and dimethyl ether in the gas phase of cold cores with temperatures as cold as 10 K challenges our previous astrochemical models concerning the formation of complex organic molecules. The strong…

Solar and Stellar Astrophysics · Physics 2016-03-23 Qiang Chang , Eric Herbst

The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…

Solar and Stellar Astrophysics · Physics 2015-12-02 A. Faure , M. Faure , P. Theulé , E. Quirico , B. Schmitt

Measuring the temperature and abundance patterns of clouds in the interstellar medium (ISM) provides an observational basis for models of the physical conditions within the clouds, which play an important role in studies of star and planet…

Astrophysics of Galaxies · Physics 2019-06-26 Nicholas Kruczek , Kevin France , Keri Hoadley , Brian Fleming , Nicholas Nell

In this work, we have carried out a two-dimensional (2D) simulation of thermal instability (TI) in interstellar matter (ISM), considering it to be a weakly ionised inviscid plasma with radiation loss. We carry out the simulation using our…

Plasma Physics · Physics 2026-02-04 Hitendra Sarkar , Madhurjya P. Bora