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Related papers: Oxygen redox in battery cathodes: A brief overview

200 papers

Understanding microscopic properties of LiNiO$_2$, a Li-ion battery cathode material with extraordinarily high reversible capacity, has remained a challenge for decades. Based on extensive electronic structure calculations, which reveal a…

Materials Science · Physics 2021-04-20 Kateryna Foyevtsova , Ilya Elfimov , Joerg Rottler , George A. Sawatzky

This work explores controllability and the control effort required for lithium-ion batteries. Battery packs have become a critical technology in both personal and professional applications as a means to store large amounts of energy.…

Systems and Control · Electrical Eng. & Systems 2026-04-14 Preston T. Abadie , Donald J. Docimo

Electrochemical impedance spectra for battery electrodes are usually interpreted using models that assume isotropic active particles, having uniform current density and symmetric diffusivities. While this can be reasonable for amorphous or…

Chemical Physics · Physics 2013-09-24 J. Song , M. Z. Bazant

Magnesium-ion batteries hold promise as future energy storage solution, yet current Mg cathodes are challenged by low voltage and specific capacity. Herein, we present an AI-driven workflow for discovering high-performance Mg cathode…

Materials Science · Physics 2025-06-11 Wenjie Chen , Zichang Lin , Xinxin Zhang , Hao Zhou , Yuegang Zhang

To discover novel materials with high performance, there have been many attempts to adopt Bayesian optimization (BO) to materials science, owing to its efficiency in navigating complex and high-dimensional design spaces. However, the…

Materials Science · Physics 2025-05-12 Sanghyeon Park , Yoonsu Shim , Junpyo Hur , Dongmin Jeon , Jong Min Yuk , Chan-Woo Lee

The kinetic battery model is a popular model of the dynamic behavior of a conventional battery, useful to predict or optimize the time until battery depletion. The model however lacks certain obvious aspects of batteries in-the-wild,…

Systems and Control · Computer Science 2016-08-07 Holger Hermanns , Jan Krčál , Gilles Nies

This work presents a comprehensive study on the aging behavior of 18650-type lithium-ion batteries, focusing on the uneven intercalation of lithium ions during fast charging processes. It introduces a novel approach using color visual…

Materials Science · Physics 2025-04-17 Yihan Shi , Qingrui Pan , Jitao Li , Xiaoze Shi , Youchang Wang , Peng Xiao

The current rechargeable battery technologies have a failure in their performance at high pressure and temperature. In this article, we have brought theoretical insights on using boron nitride flakes as a protecting layer for a lithium-ion…

Applied Physics · Physics 2021-02-15 Narjes Kheirabadi , Azizollah Shafiekhani

Crack growth in lithium-ion battery electrodes is typically detrimental and undesirable. However, recent experiments suggest that stabilized fracture of cathode active materials in liquid electrolytes can increase electrochemically active…

As an alternative approach to ionic data transmission with hydrogel as substrate, this work explores the possible applications of liquid electrolyte filling cavity of a stretchable, flexible elastomeric tubing, which is the primary…

Systems and Control · Electrical Eng. & Systems 2023-07-06 Khoi Ly , Chong-Chan Kim , Robert Shepherd

All-solid-state Li-ion batteries promise safer electrochemical energy storage with larger volumetric and gravimetric energy densities. A major concern is the limited electrochemical stability of solid electrolytes and related detrimental…

We present a physics-based model that accurately predicts the performance of Medtronic's implantable medical device battery lithium/carbon monofluoride (CF$_x$) - silver vanadium oxide (SVO) under both low-rate background monitoring and…

Electrolytes mediate interactions between the cathode and anode and determine performance characteristics of batteries. Mixtures of multiple solvents are often used in electrolytes to achieve desired properties, such as viscosity,…

Chemical Physics · Physics 2024-10-22 Celia Kelly , Emil Annevelink , Adarsh Dave , Venkatasubramanian Viswanathan

Recent debates on the oxygen redox behaviors in battery electrodes have triggered a pressing demand for the reliable detection and understanding of non-divalent oxygen states beyond conventional absorption spectroscopy. Here, enabled by…

The development of high-energy density solid-state batteries is critical for the achievement of carbon neutrality goals and the advancement of clean energy. Still, the fundamental understanding of lithium transport mechanisms and…

Designing lithium-ion batteries for long service life remains a challenge, as most cells are optimized for beginning-of-life metrics such as energy density, often overlooking how design and operating conditions shape degradation. This work…

Si-anodes have long been candidates thanks to an expected ten-fold increase in capacity compared to graphite. However, details of the mechanisms governing their degradation remain elusive, hindering science-guided development of long-lived…

The morphologies of crystalline lithium peroxide (Li2O2) discharge products in Li-O2 batteries have been shown to exhibit a dependency on subtle variations within the battery cell-operating environment including exposure to ambient air,…

Materials Science · Physics 2016-06-22 Hariharan Katharajan , Kumar Virwani , A. David Erpelding , Jeannette M. Garcia

The recent geopolitical crisis resulted in a gas price surge. Although lithium-ion batteries represent the best available rechargeable battery technology, a significant energy and power density gap exists between LIBs and petrol/gasoline.…

Computational Engineering, Finance, and Science · Computer Science 2023-09-06 Dibakar Datta

A general technique to investigate charge storage characteristics of conducting polymer films has been developed. A redox reaction is conducted on a polymer film on a rotating disk electrode under potentiostatic condition so that the rate…

Chemical Physics · Physics 2013-11-19 Asfiya Q. Contractor , Vinay A. Juvekar