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In this paper we establish a new efficient method for simulating polymer-solvent systems which combines a lattice Boltzmann approach for the fluid with a continuum molecular dynamics (MD) model for the polymer chain. The two parts are…

Soft Condensed Matter · Physics 2009-10-31 Patrick Ahlrichs , Burkhard Duenweg

Active matter is driven out of equilibrium by a local influx of energy. While classical active matter has been extensively studied, the extension of active matter concepts to quantum systems has been explored far less. In this work we…

In recent years it was shown both theoretically and experimentally that in certain systems exhibiting anomalous diffusion the time and ensemble average mean squared displacement are remarkably different. The ensemble average diffusivity is…

Statistical Mechanics · Physics 2017-12-20 Philipp Meyer , Eli Barkai , Holger Kantz

It is proposed that the rate of relaxation in a liquid is better described by the geometric mean of the van Hove distribution function, rather than the standard arithmetic mean used to obtain the mean squared displacement. The difference…

Soft Condensed Matter · Physics 2016-02-10 Shibu Saw , Peter Harrowell

We analyze a (1+1)-dimension directed random walk model of a polymer dipped in a medium constituted by two immiscible solvents separated by a flat interface. The polymer chain is heterogeneous in the sense that a single monomer may…

Probability · Mathematics 2007-05-23 Erwin Bolthausen , Giambattista Giacomin

We report a numerical study of the diffusiophoresis of short polymers using non-equilibrium molecular dynamics simulations. More precisely, we consider polymer chains in a fluid containing a solute which has a concentration gradient, and…

Soft Condensed Matter · Physics 2020-05-20 Simón Ramírez-Hinestrosa , Hiroaki Yoshida , Lydéric Bocquet , Daan Frenkel

We propose the quantitative mean-field theory of mechanical unfolding of a globule formed by long flexible homopolymer chain collapsed in poor solvent and subjected to an extensional force We show that with an increase in the applied force…

Soft Condensed Matter · Physics 2012-05-15 Alexey A. Polotsky , Elizaveta E. Smolyakova , Oleg V. Borisov , Tatiana M. Birshtein

We present a kinetic model of crystal growth of polymers of finite molecular weight. Experiments help to classify polymer crystallization broadly into two kinetic regimes. One is observed in melts or in high molar mass polymer solutions and…

Soft Condensed Matter · Physics 2009-11-11 Arindam Kundagrami , M. Muthukumar

We study the quantum dynamics of a suddenly released beam of particles using a background independent (polymer) quantization scheme. We show that, in the first order of approximation, the low-energy polymer distribution converges to the…

Quantum Physics · Physics 2015-06-22 A. Martín-Ruiz

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

Soft Condensed Matter · Physics 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

A new method based on quasi-independent parallel simulations approach, replica-averaging, has been developed to study the influence of flow on mechanical force-mediated polymer processes such as denaturation and breaking of bonds. This…

Chemical Physics · Physics 2024-06-19 Sagar Kania , Anh H. Nguyen , Alparslan Oztekin , Edmund Webb

A Gibbs-like approach for simultaneous multi-scale correlation functions in random, time-dependent, multiplicative processes for the turbulent energy cascade is investigated. We study the optimal log-normal Gibbs-like distribution able to…

Chaotic Dynamics · Physics 2007-06-13 Roberto Benzi , Luca Biferale , Mauro Sbragaglia

Consider a statistical model with an epistemic restriction such that, unlike in classical mechanics, the allowed distribution of positions is fundamentally restricted by the form of an underlying momentum field. Assume an agent (observer)…

Quantum Physics · Physics 2020-05-15 Agung Budiyono

Coupled length and time scales determine the dynamic behavior of polymers and underlie their unique viscoelastic properties. To resolve the long-time dynamics it is imperative to determine which time and length scales must be correctly…

Soft Condensed Matter · Physics 2016-02-16 K. Michael Salerno , Anupriya Agrawal , Dvora Perahia , Gary S. Grest

The statistics of polymers advected by a turbulent flow are investigated. To limit the polymer lengths above to coil-stretch transition, a FENE-P type relaxation law is used. The turbulence is modeled by a random strain, delta-correlated in…

Chaotic Dynamics · Physics 2009-11-07 Jean-Luc Thiffeault

We consider the simplest representative of the class of multiply branched polymer macromolecules, known as a pom-pom structure. The molecule consists of a backbone linear chain terminated by two branching points with functionalities…

Soft Condensed Matter · Physics 2020-12-02 Khristine Haydukivska , Ostap Kalyuzhnyi , Viktoria Blavatska , Jaroslav Ilnytskyi

Many physical systems share the property of scale invariance. Most of them show ordinary power-law scaling, where quantities can be expressed as a leading power law times a scaling function which depends on scaling-invariant ratios of the…

Statistical Mechanics · Physics 2009-11-07 Lionel Sittler , Haye Hinrichsen

Aims. The process of pitch-angle isotropization is important for many applications ranging from diffusive shock acceleration to large-scale cosmic-ray transport. Here, the basic analytical description is revisited on the basis of recent…

High Energy Astrophysical Phenomena · Physics 2015-06-17 R. C. Tautz

Polymers consisting of more than one type of monomer, known as copolymers, are vital to both living and synthetic systems. Copolymerisation has been studied theoretically in a number of contexts, often by considering a Markov process in…

We present results from a systematic numerical study of decaying turbulence in a dilute polymer solution by using a shell-model version of the FENE-P equations. Our study leads to an appealing definition of drag reduction for the case of…

Statistical Mechanics · Physics 2009-11-10 Chirag Kalelkar , Rama Govindarajan , Rahul Pandit