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Accurately learning the temporal behavior of dynamical systems requires models with well-chosen learning biases. Recent innovations embed the Hamiltonian and Lagrangian formalisms into neural networks and demonstrate a significant…

Machine Learning · Computer Science 2021-10-04 Shaan Desai , Marios Mattheakis , David Sondak , Pavlos Protopapas , Stephen Roberts

The density-constrained time-dependent Hartree-Fock (DC-TDHF) theory is a fully microscopic approach for calculating heavy-ion interaction potentials and fusion cross sections below and above the fusion barrier. We discuss recent…

Nuclear Theory · Physics 2014-02-07 A. S. Umar , V. E. Oberacker , R. Keser , J. A. Maruh , P. -G. Reinhard

Octupole vibrations are studied in some doubly magic nuclei using the time-dependent Hartree-Fock (TDHF) theory with a Skyrme energy density functional. Through the use of the linear response theory, the energies and transition amplitudes…

Nuclear Theory · Physics 2016-09-07 C. Simenel , J. Buete , K. Vo-Phuoc

We study a class of time-dependent (TD) non-Hermitian Hamiltonians $H(t)$ that can be transformed into a time-independent pseudo-Hermitian Hamiltonian $\mathcal{H}_{0}^{PH}$ using a suitable TD unitary transformation $F(t)$. The latter can…

Quantum Physics · Physics 2025-10-06 F. Kecita , B. Khantoul , A. Bounames

We apply in a schematic model a theory beyond mean-field, namely Stochastic Time-Dependent Hartree-Fock (STDHF), which includes dynamical electron-electron collisions on top of an incoherent ensemble of mean-field states by occasional…

Atomic and Molecular Clusters · Physics 2016-10-12 Lionel Lacombe , Paul-Gerhard Reinhard , Eric Suraud , Phuong Mai Dinh

Machine learning has emerged as a powerful tool for predicting molecular properties in chemical reaction networks with reduced computational cost. However, accurately predicting energies of transition state (TS) structures remains a…

Chemical Physics · Physics 2025-04-29 Stefan Gugler , Markus Reiher

Background: The study of deep-inelastic reactions of nuclei provide a vehicle to investigate nuclear transport phenomena for a full range of equilibration dynamics. These inquires provide us the ingredients to model such phenomena and help…

Nuclear Theory · Physics 2017-09-06 A. S. Umar , C. Simenel , W. Ye

The $\lambda \phi^4$ model in a finite volume is studied within a non-gaussian Hartree-Fock approximation (tdHF) both at equilibrium and out of equilibrium, with particular attention to the structure of the ground state and of certain…

High Energy Physics - Phenomenology · Physics 2009-10-31 C. Destri , E. Manfredini

A challenge in modeling time-dependent strong-field processes such as high-harmonic generation for many-body systems, is how to effectively represent the electronic continuum. We apply Rothe's method to the time-dependent Hartree-Fock…

Chemical Physics · Physics 2025-08-22 Simon Elias Schrader , Håkon Emil Kristiansen , Thomas Bondo Pedersen , Simen Kvaal

We present the first realization of Stochastic TDHF, a theory which goes beyond pure mean-field dynamics, embracing dissipation as well as fluctuations. Applications to heavy-ion collisions in the Fermi energy domain are given and analyzed…

Nuclear Theory · Physics 2009-10-30 E. Suraud , P. G. Reinhard

A recent interpretation of the caloric curve based on the expansion of the abraded spectator nucleus is re-analysed in the framework of the Time-Dependent Hartree-Fock (TDHF) evolution. It is shown that the TDHF dynamics is more complex…

Nuclear Theory · Physics 2016-09-08 D. Lacroix , Ph. Chomaz

Evolutionary algorithms for molecular design require computationally efficient yet accurate fitness functions. We systematically benchmark Hartree-Fock and density functional theory for predicting molecular first hyperpolarizability…

Chemical Physics · Physics 2026-04-24 Dominic Mashak , S. A. Alexander

Deep learning electronic structures from ab initio calculations holds great potential to revolutionize computational materials studies. While existing methods proved success in deep-learning density functional theory (DFT) Hamiltonian…

We present the time-dependent restricted-active-space self-consistent field (TD-RASSCF) theory as a new framework for the time-dependent many-electron problem. The theory generalizes the multiconfigurational time-dependent Hartree-Fock…

Atomic Physics · Physics 2014-05-22 Haruhide Miyagi , Lars Bojer Madsen

Multinucleon transfer processes in heavy-ion reactions at energies slightly above the Coulomb barrier are investigated in a fully microscopic framework of the time-dependent Hartree-Fock (TDHF) theory. Transfer probabilities are calculated…

Nuclear Theory · Physics 2016-05-25 Kazuyuki Sekizawa , Kazuhiro Yabana

Recently, sophisticated deep learning-based approaches have been developed for generating efficient initial guesses to accelerate the convergence of density functional theory (DFT) calculations. While the actual initial guesses are often…

Chemical Physics · Physics 2026-03-24 Zhe Liu , Yuyan Ni , Zhichen Pu , Qiming Sun , Siyuan Liu , Wen Yan

We introduce an individually fitted screened-exchange interaction for the time-dependent Hartree-Fock (TDHF) method and show that it resolves the missing binding energies in polymethine organic dye molecules compared to time-dependent…

Chemical Physics · Physics 2024-06-21 Nadine C. Bradbury , Barry Y. Li , Tucker Allen , Justin R. Caram , Daniel Neuhauser

In this contribution, we extend our framework for analyzing and visualizing correlated many-electron dynamics to non-variational, highly scalable electronic structure method. Specifically, an explicitly time-dependent electronic wave packet…

Chemical Physics · Physics 2017-04-27 Gunter Hermann , Vincent Pohl , Jean Christophe Tremblay

In the near future, material and drug design may be aided by quantum computer assisted simulations. These have the potential to target chemical systems intractable by the most powerful classical computers. However, the resources offered by…

Time-dependent Hartree-Fock (TDHF) theory has been a powerful tool in describing a variety of complex nuclear dynamics microscopically without empirical parameters. In this contribution, recent advances in nuclear dynamics studies with TDHF…

Nuclear Theory · Physics 2019-03-26 Kazuyuki Sekizawa