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We present a theoretical framework to investigate quantum thermodynamic processes under non-Markovian system-bath interactions on the basis of the hierarchical equations of motion (HEOM) approach, which is convenient to carry out…

Quantum Physics · Physics 2019-05-01 Akihito Kato , Yoshitaka Tanimura

We investigate the efficiency of a quantum Carnot engine based on open quantum dynamics theory. The model includes time-dependent external fields for the subsystems controlling the isothermal and isentropic processes and for the…

Statistical Mechanics · Physics 2022-08-24 Shoki Koyanagi , Yoshitaka Tanimura

For a system strongly coupled to a heat bath, the quantum coherence of the system and the heat bath plays an important role in the system dynamics. This is particularly true in the case of non-Markovian noise. We rigorously investigate the…

Statistical Mechanics · Physics 2015-02-16 Yoshitaka Tanimura

The laws of thermodynamics put limits to the efficiencies of thermal machines. Analogues of these laws are now established for quantum engines weakly and passively coupled to the environment providing a framework to find improvements to…

Quantum Physics · Physics 2015-10-23 Felipe Barra

The hierarchical equations of motion technique has found widespread success as a tool to generate the numerically exact dynamics of non-Markovian open quantum systems. However, its application to low temperature environments remains a…

Chemical Physics · Physics 2013-10-15 Jeremy M. Moix , Jianshu Cao

We derive an extended version of the hierarchical equations of motion (HEOM) to compute output physical properties of a bosonic environment, which is allowed to be initially prepared at an earlier time in a non-Gaussian input state and then…

Quantum Physics · Physics 2025-08-15 Mauro Cirio , Pengfei Liang , Neill Lambert

A recently developed approach to the thermodynamics of open quantum systems, on the basis of the principle of minimal dissipation, is applied to the spin-boson model. Employing a numerically exact quantum dynamical treatment based on the…

Quantum Physics · Physics 2024-08-30 Salvatore Gatto , Alessandra Colla , Heinz-Peter Breuer , Michael Thoss

We unite two of the most widely used approaches for strongly damped, non-Markovian open quantum dynamics, the Hierarchical Equations of Motion (HEOM) and the pseudomode method by proving two statements: First, every physical bath…

Quantum Physics · Physics 2026-04-09 Kai Müller , Walter T. Strunz

The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime,…

Statistical Mechanics · Physics 2016-06-29 Kay Brandner , Udo Seifert

In this review the debated rapport between thermodynamics and quantum mechanics is addressed in the framework of the theory of periodically-driven/controlled quantum-thermodynamic machines. The basic model studied here is that of a…

Quantum Physics · Physics 2015-09-15 D. Gelbwaser-Klimovsky , Wolfgang Niedenzu , Gershon Kurizki

An open quantum system refers to a system that is further coupled to a bath system consisting of surrounding radiation fields, atoms, molecules, or proteins. The bath system is typically modeled by an infinite number of harmonic…

Chemical Physics · Physics 2020-07-10 Yoshitaka Tanimura

The hierarchical equations of motion (HEOM) provide a numerically exact approach for simulating the dynamics of open quantum systems coupled to a harmonic bath. However, its applicability has traditionally been limited to specific spectral…

Quantum Physics · Physics 2023-08-07 Meng Xu , Joachim Ankerhold

We derive the formula of energy flux for the hierarchical equations of motion (HEOM) method with the help of stochastic decoupling technique. The resulting expression is a combination of the terms in the first two layers of the hierarchy.…

Statistical Mechanics · Physics 2019-04-30 Yun Zhou , Tie-Jun Xiao , Jun Cao , Yun-An Yan

Optimal control theory is implemented with fully converged hierarchical equations of motion (HEOM) describing the time evolution of an open system density matrix strongly coupled to the bath in a spin-boson model. The populations of the…

Quantum computing offers promising new avenues for tackling the long-standing challenge of simulating the quantum dynamics of complex chemical systems, particularly open quantum systems coupled to external baths. However, simulating such…

Quantum Physics · Physics 2025-02-20 Xiaohan Dan , Eitan Geva , Victor S. Batista

The focus is on understanding the quantum thermodynamics of strongly coupled non-Markovian quantum systems. To this end, a non-trivial, non-Markovian model of a central spin surrounded by a spin bath is taken up, and its exact evolution is…

Quantum Physics · Physics 2025-08-28 Devvrat Tiwari , Baibhab Bose , Subhashish Banerjee

This work is a pedagogical survey about the hierarchical equations of motion and their implementation with the tensor-train format. These equations are a great standard in non-perturbative non-Markovian open quantum systems. They are exact…

Quantum Physics · Physics 2023-08-09 Etienne Mangaud , Amine Jaouadi , Alex Chin , Michèle Desouter-Lecomte

From the thermodynamic equilibrium properties of a two-level system with variable energy-level gap $\Delta$, and a careful distinction between the Gibbs relation $dE = T dS + (E/\Delta) d\Delta$ and the energy balance equation $dE = \delta…

Quantum Physics · Physics 2014-01-22 Gian Paolo Beretta

We present a scheme to evaluate thermodynamic variables for a system coupled to a heat bath under a time-dependent external force using the quasi-static Helmholtz energy from the numerically "exact" hierarchical equations of motion (HEOM).…

Statistical Mechanics · Physics 2020-12-18 Souichi Sakamoto , Yoshitaka Tanimura

The hierarchical equations of motion (HEOM) provide a numerically exact approach for computing the reduced dynamics of a quantum system linearly coupled to a bath. We have found that HEOM contains temperature-dependent instabilities that…

Chemical Physics · Physics 2019-05-13 Ian S. Dunn , Roel Tempelaar , David R. Reichman
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