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Single molecule rotational correlation functions are analyzed for several reorientation geometries. Even for the simplest model of isotropic rotational diffusion our findings predict non-exponential correlation functions to be observed by…

Other Condensed Matter · Physics 2016-08-16 G. Hinze , G. Diezemann , Th. Basché

Two-dimensional molecular crystals have been beyond the reach of systematic investigation because of the lack or instability of their well-defined forms. Here, we demonstrate drastically enhanced photostability and Davydov splitting in…

Materials Science · Physics 2021-08-13 Seonghyun Koo , Ina Park , Kenji Watanabe , Takashi Taniguchi , Ji Hoon Shim , Sunmin Ryu

Hexagonal boron nitride is a van der Waals material that hosts visible-wavelength quantum emitters at room temperature. However, experimental identification of the quantum emitters' electronic structure is lacking, and key details of their…

Electric dipole radiation can be controlled by coherent optical feedback, as has previously been studied by modulating the photonic environment for point dipoles placed both in optical cavities and near metal mirrors. In experiments…

Mesoscale and Nanoscale Physics · Physics 2020-02-05 Christopher Rogers , Dodd Gray , Nathan Bogdanowicz , Takashi Taniguchi , Kenji Watanabe , Hideo Mabuchi

Determining the local symmetry of luminescent centers in crystals is critical for understanding and controlling their optical transitions, yet current methods are limited by stringent experimental requirements and ambiguous symmetry…

We explore the possibility of forming a oriented polar molecule directly from a pair of colliding atoms. The process comprises the photoassociation and vibrational stabilization along with the molecular orientation. These processes are…

Quantum Physics · Physics 2026-01-14 Murilo D. Forlevesi , Edson Denis Leonel , Emanuel F. de Lima

Electron spins coupled with optical transitions in solids stand out as a promising platform for developing spin-based quantum technologies. Recently, hexagonal boron nitride (hBN) - a layered Van der Waals (vdW) crystal, has emerged as a…

Excitons, quasi particles composed of an electron and a hole, play an important role in optical responses in low-dimensional nanostructures. In this work, we have investigated exciton diffusion in a monolayer MoSe2 encapsulated between…

Mesoscale and Nanoscale Physics · Physics 2020-09-30 T. Hotta , S. Higuchi , A. Ueda , K. Shinokita , Y. Miyauchi , K. Matsuda , K. Ueno , T. Taniguchi , K. Watanabe , R. Kitaura

Label-free single-molecule detection is essential for studying biomolecules in their native state, yet having materials with intrinsic molecular specificity to identify a broad range of molecules without complex functionalization remains…

Mesoscale and Nanoscale Physics · Physics 2024-09-30 Miao Zhang , Cristina Izquierdo Lozano , Stijn van Veen , Lorenzo Albertazzi

Scalable integration of bright emitters in quantum photonic structures is an important step in the broader quest to generate and manipulate single photons via compact solid-state devices. Unfortunately, implementations relying on material…

This report summarizes progress made in understanding properties such as zero-phonon-line energies, emission and absorption polarizations, electron-phonon couplings, strain tuning and hyperfine coupling of single photon emitters in…

Materials Science · Physics 2020-04-22 A. Sajid , Michael J. Ford , Jeffrey R. Reimers

The negatively charged boron vacancy (VB-) in hexagonal boron nitride (hBN) has been extensively investigated as it offers a novel playground for two-dimensional quantum sensing, with ultimate proximity to target samples. However, its…

We investigate the optical properties of Dibenzoterrylene (DBT) molecules in a spin-coated crystalline film of anthracence. By performing single molecule studies, we show that the dipole moments of the DBT molecules are oriented parallel to…

Quantum Physics · Physics 2015-05-18 C. Toninelli , K. Early , J. Bremi , A. Renn , S. Goetzinger , V. Sandoghdar

Defects in hexagonal boron nitride (hBN), a two-dimensional van der Waals material, have raised wide range interest for its potential in various quantum applications. Due to hBN's 2D nature, spin center in hBN can be engineered in close…

Mesoscale and Nanoscale Physics · Physics 2024-04-26 Lingnan Shen , Di Xiao , Ting Cao

We demonstrate the fabrication of individual nanopores in hexagonal boron nitride (hBN) with atomically precise control of the pore size. Previous methods of pore production in other 2D materials create pores of irregular geometry with…

Materials Science · Physics 2017-02-07 S. Matt Gilbert , Gabriel Dunn , Thang Pham , Brian Shevitski , Edgar Dimitrov , Shaul Aloni , Alex Zettl

Half-cycle laser pulse is applied on an absorbed molecule to investigate its alignment and orientation behavior. Crossover from field-free to hindered rotation motion is observed by varying the angel of hindrance of potential well. At small…

Atomic Physics · Physics 2007-05-23 Y. Y. Liao , Y. N. Chen , D. S. Chuu

Understanding the dynamics of molecules adsorbed to surfaces or confined to small volumes is a matter of increasing scientific and technological importance. Here, we demonstrate a pulse protocol using individual paramagnetic nitrogen…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 T. Staudacher , N. Raatz , S. Pezzagna , J. Meijer , F. Reinhard , C. A. Meriles , J. Wrachtrup

We demonstrate an all-optical method for magnetic sensing of individual molecules in ambient conditions at room temperature. Our approach is based on shallow nitrogen-vacancy (NV) centers near the surface of a diamond crystal, which we use…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 A. O. Sushkov , N. Chisholm , I. Lovchinsky , M. Kubo , P. K. Lo , S. D. Bennett , D. Hunger , A. Akimov , R. L. Walsworth , H. Park , M. D. Lukin

Single fluorescent molecules embedded in the bulk of host crystals have proven to be excellent probes of the dynamics in their nano environment, thanks to their narrow (about 0.1 {\mu}eV) optical linewidth of the 0-0 zero-phonon line (0-0…

Chemical Physics · Physics 2023-06-09 Robert Smit , Arash Tebyani , Jil Hameury , Sense Jan van der Molen , Michel Orrit

Fluorescent nanoparticles are widely utilized in a large range of nanoscale imaging and sensing applications. While ultra-small nanoparticles (size <10 nm) are highly desirable, at this size range their photostability can be compromised due…