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When the atomic layers in a non-centrosymmetric van der Waals structure slide against each other, the interfacial charge transfer results in a reversal of the structures spontaneous polarization. This phenomenon is known as sliding…

Bilayers of two-dimensional van der Waals materials that lack an inversion centre can show a novel form of ferroelectricity, where certain stacking arrangements of the two layers lead to an interlayer polarization. Under an external…

Superconductivity · Physics 2024-06-27 Gaurav Chaudhary , Ivar Martin

Sliding ferroelectricity is a unique type of polarity recently observed in a properly stacked van der Waals bilayer. However, electric-field control of sliding ferroelectricity is hard and could induce large coercive electric fields and…

Materials Science · Physics 2024-03-13 Jian Wang , Xu Li , Xingyue Ma , Lan Chen , Jun-Ming Liu , Chun-Gang Duan , Jorge Íñiguez-González , Di Wu , Yurong Yang

Stacking nonpolar, monolayer materials has emerged as an effective strategy to harvest ferroelectricity in two-dimensional (2D) van de Waals (vdW) materials. At a particular stacking sequence, interlayer charge transfer allows for the…

Materials Science · Physics 2024-11-12 Lingyuan Gao , Laurent Bellaiche

In recent years, sliding ferroelectricity has emerged as a topic of significant interest due to its possible application in non-volatile, reconfigurable storage devices. This phenomenon is unique to two-dimensional van der Waals materials,…

Light-induced sliding ferroelectricity in two-dimensional van der Waals materials enables polarization control via relative layer motion. However, polarization switching occurs on the time scale of shear modes (tens of ps) and requires very…

Materials Science · Physics 2026-05-26 Xiangzhou Zhu , Stefano Mocatti , Matteo Calandra

Sliding ferroelectricity is a phenomenon that arises from the insurgence of spontaneous electronic polarization perpendicular to the layers of two-dimensional (2D) systems upon the relative sliding of the atomic layer constituents. Because…

Materials Science · Physics 2026-04-21 Matteo D'Alessio , Daniele Varsano , Elisa Molinari , Massimo Rontani

Two-dimensional materials with ferroelectric properties break the size effect of conventional ferroelectric materials and unlock unprecedented potentials of ferroelectric-related application at small length scales. In this work, using…

Materials Science · Physics 2022-03-25 Bo Xu , Junkai Deng , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu

According to the recent studies on sliding/moire ferroelectricity, most 2D van der Waals nonferroelectric monolayers can become ferroelectric via multilayer stacking. In this paper we propose that similar strategy can be used to induce…

Materials Science · Physics 2025-07-24 Yuxuan Sheng , Junwei Liu , Jia Zhang , Menghao Wu

Sliding ferroelectricity may emerge in many van der Waals bilayers/multilayers and the low switching barriers render ultrafast data writing with low energy cost. We note that such barriers are still much higher compared with structural…

Materials Science · Physics 2025-07-24 Zihao Yang , Menghao Wu

We propose ferroelectric layer sliding as a new approach to realize and manipulate topological quantum states in two-dimensional (2D) bilayer magnetic van der Waals materials. We show that stacking monolayer ferromagnetic topological states…

Materials Science · Physics 2025-08-13 Ning-Jing Yang , Jian-Min Zhang , Xiao-Ping Li , Zeying Zhang , Zhi-Ming Yu , Zhigao Huang , Yugui Yao

The so-called interlayer-sliding ferroelectricity was recently proposed as an unconventional route to pursuit electric polarity in van der Waals multi-layers, which was already experimentally confirmed in WTe$_2$ bilayer even though it is…

Materials Science · Physics 2021-08-17 Ning Ding , Jun Chen , Churen Gui , Haipeng You , Xiaoyan Yao , Shuai Dong

Van der Waals "sliding" ferroelectric bilayers, whose electric polarization is locked to the interlayer alignment, show promise for future non-volatile memory and other nanoelectronic devices. These applications require a fuller…

Statistical Mechanics · Physics 2025-09-19 Benjamin Remez , Moshe Goldstein

Sliding ferroelectricity in bilayer van der Waals materials exhibits ultrafast switching speed and fatigue resistance during the polarization switching, offering an avenue for the design of memories and neuromorphic devices. The unique…

Materials Science · Physics 2025-02-21 Yubai Shi , Yuxiang Gao , Ri He , Hua Wang , Binwen Zhang , Zhicheng Zhong

The combination of metallicity and ferroelectricity breaks traditional boundaries, paving new avenues for innovative electronic materials and devices. This breakthrough is particularly notable, as metallicity and ferroelectricity have…

Materials Science · Physics 2024-04-09 Jiagang Zhang , Ting Zhang

In conventional ferroelectric materials, polarization is an intrinsic property limited by bulk crystallographic structure and symmetry. Recently, it has been demonstrated that polar order can also be accessed using inherently non-polar van…

Most non-ferroelectric two-dimensional materials can be endowed with so-called sliding ferroelectricity via non-equivalent homo-bilayer stacking, which is not applicable to mono-element systems like pure graphene bilayer with inversion…

Mesoscale and Nanoscale Physics · Physics 2023-08-31 Liu Yang , Shiping Ding , Jinhua Gao , Menghao Wu

Interlayer stacking order has recently emerged as a unique degree of freedom to control crystal symmetry and physical properties in two-dimensional van der Waals (vdW) materials and heterostructures. By tuning the layer stacking pattern,…

Although most two-dimensional (2D) materials are non-ferroelectric with highly symmetric lattices, symmetry breaking may take place in their bilayers upon certain stacking order, giving rise to so-called sliding ferroelectricity where the…

Mesoscale and Nanoscale Physics · Physics 2023-04-10 Liu Yang , Menghao Wu

We address the sliding thermodynamics of van der Waals-bonded bilayers by the continuum elasticity theory. We attribute the robustness of the ferroelectricity recently observed in h-BN and WTe2 bilayers to large monolayer in-plane…

Mesoscale and Nanoscale Physics · Physics 2023-05-10 Ping Tang , Gerrit E. W. Bauer
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