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Linear response time-dependent density functional theory is used to study low-lying electronic continuum states of targets that can bind an extra electron. Exact formulas to extract scattering amplitudes from the susceptibility are derived…

Other Condensed Matter · Physics 2009-11-11 Adam Wasserman , Neepa T. Maitra , Kieron Burke

Time-dependent density functional theory (TDDFT) is a standard approach for calculating optical excitations of molecules and solids, while ensemble DFT (EDFT) is a promising alternative under development. We introduce ensemble TDDFT…

Chemical Physics · Physics 2026-05-22 Kimberly J. Daas , Steven Crisostomo , Kieron Burke

We develop a Hamiltonian theory for a time dispersive and dissipative (TDD) inhomogeneous medium, as described by a linear response equation respecting causality and power dissipation. The canonical Hamiltonian constructed here exactly…

Classical Physics · Physics 2009-04-24 A. Figotin , J. H. Schenker

Basic issues of the time-dependent density-functional theory are discussed, especially on the real-time calculation of the linear response functions. Some remarks on the derivation of the time-dependent Kohn-Sham equations and on the…

Nuclear Theory · Physics 2017-01-06 Takashi Nakatsukasa

We consider a second order linear evolution equation with a dissipative term multiplied by a time-dependent coefficient. Our aim is to design the coefficient in such a way that all solutions decay in time as fast as possible. We discover…

Analysis of PDEs · Mathematics 2015-06-24 Marina Ghisi , Massimo Gobbino , Alain Haraux

The adiabatic connection formalism, usually based on the first-order perturbation theory, has been generalized to an arbitrary order. The generalization stems from the observation that the formalism can be derived from a properly arranged…

Chemical Physics · Physics 2023-10-18 Andreas Savin , Jacek Karwowski

We continue our study of the linear response of a nonequilibrium system. This Part II concentrates on models of open and driven inertial dynamics but the structure and the interpretation of the result remain unchanged: the response can be…

Statistical Mechanics · Physics 2010-05-02 Marco Baiesi , Eliran Boksenbojm , Christian Maes , Bram Wynants

The paper deals with the problem of existence of a convergent "strong" normal form in the neighbourhood of an equilibrium, for a finite dimensional system of differential equations with analytic and time-dependent non-linear term. The…

Dynamical Systems · Mathematics 2016-09-27 Alessandro Fortunati , Stephen Wiggins

Basing on the theory of Feynman's influence functional and its hierarchical equations of motion, we develop a linear response theory for quantum open systems. Our theory provides an effective way to calculate dynamical observables of a…

Mesoscale and Nanoscale Physics · Physics 2011-08-31 J. H. Wei , YiJing Yan

We apply the adiabatic time-dependent density functional theory to magnetic ci the real-space, real-time computational method. The standard formulas for the MCD response and its A and B terms are derived from the observables in the…

Chemical Physics · Physics 2015-05-20 K. -M. Lee , K. Yabana , G. F. Bertsch

We present a diagrammatic formulation of a theory for the time dependence of density fluctuations in equilibrium systems of interacting Brownian particles. To facilitate derivation of the diagrammatic expansion we introduce a basis that…

Soft Condensed Matter · Physics 2009-11-13 Grzegorz Szamel

We present a rigorous formulation of the time-dependent density functional theory for interacting lattice electrons strongly coupled to cavity photons. We start with an example of one particle on a Hubbard dimer coupled to a single photonic…

Strongly Correlated Electrons · Physics 2015-06-22 Mehdi Farzanehpour , I. V. Tokatly

The particle-hole interaction problem is longstanding within time-dependent density functional theory (TDDFT) and leads to extreme errors in the prediction of K-edge X-ray absorption spectra (XAS). We derive a linear-response formalism that…

Chemical Physics · Physics 2022-10-18 Kevin Carter-Fenk , Leonardo A. Cunha , Juan E. Arias-Martinez , Martin Head-Gordon

We propose a description of nonequilibrium systems via a simple protocol that combines exchange-correlation potentials from density functional theory with self-energies of many-body perturbation theory. The approach, aimed to avoid double…

Strongly Correlated Electrons · Physics 2016-06-15 M. Hopjan , D. Karlsson , S. Ydman , C. Verdozzi , C. -O. Almbladh

We address and quantify the role of non-adiabaticity ("memory effects") in the exchange-correlation (xc) functional of time-dependent density functional theory (TDDFT) for describing non-linear dynamics of many-body systems. Time-dependent…

Other Condensed Matter · Physics 2015-06-18 Johanna I. Fuks , Mehdi Farzanehpour , Ilya V. Tokatly , Heiko Appel , Stefan Kurth , Angel Rubio

Besides the traditional circuit-based model of quantum computation, several quantum algorithms based on a continuous-time Hamiltonian evolution have recently been introduced, including for instance continuous-time quantum walk algorithms as…

Quantum Physics · Physics 2007-05-23 Jeremie Roland , Nicolas J. Cerf

By stating the adiabatic theorem of quantum mechanics in a clear and rigorous way, we establish a necessary condition and a sufficient condition for its validity, where the latter is obtained employing our recently developed adiabatic…

Quantum Physics · Physics 2012-06-19 Gustavo Rigolin , Gerardo Ortiz

Based on our earlier works [Phys. Rev. B 75, 195127 (2007) & J. Chem. Phys. 128, 234703 (2008)], we propose a formally exact and numerically convenient approach to simulate time-dependent quantum transport from first-principles. The…

Chemical Physics · Physics 2015-05-18 Xiao Zheng , GuanHua Chen , Yan Mo , SiuKong Koo , Heng Tian , ChiYung Yam , YiJing Yan

Understanding the linear response of any system is the first step towards analyzing its linear and nonlinear dynamics, stability properties, as well as its behavior in the presence of noise. In non-Hermitian Hamiltonian systems, calculating…

In their famous paper Kohn and Sham formulated a formally exact density-functional theory (DFT) for the ground-state energy and density of a system of $N$ interacting electrons, albeit limited at the time by certain troubling…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Miquel Huix-Rotllant , Mark E. Casida
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