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Chemical relaxation phenomena, including photochemistry and electron transfer processes, form a vigorous area of research in which nonadiabatic dynamics plays a fundamental role. Here, we show that for nonadiabatic dynamics with two…

Chemical Physics · Physics 2022-07-20 Yanze Wu , Xuezhi Bian , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

We consider complex dynamical systems showing metastable behavior but no local separation of fast and slow time scales. The article raises the question of whether such systems exhibit a low-dimensional manifold supporting its effective…

Dynamical Systems · Mathematics 2019-07-10 Andreas Bittracher , Péter Koltai , Stefan Klus , Ralf Banisch , Michael Dellnitz , Christof Schütte

Nonadiabatic transition dynamics lies at the core of many electron/hole transfer, photoactivated, and vacuum field-coupled processes. About a century after Ehrenfest proposed "Phasenraum" and the Ehrenfest theorem, we report a conceptually…

Quantum Physics · Physics 2024-04-09 Baihua Wu , Xin He , Jian Liu

Reliable trajectory-based nonadiabatic quantum dynamics methods at the atomic level are critical for understanding many important processes in real systems. The paper reports latest progress of nonadiabatic field (NaF), a conceptually novel…

Chemical Physics · Physics 2025-04-14 Baihua Wu , Bingqi Li , Xin He , Xiangsong Cheng , Jiajun Ren , Jian Liu

We investigate Taylor-Couette flow with realistic no-slip boundary conditions at all surfaces through direct numerical simulations (DNS) and theoretical analysis. Imposing physically consistent end-wall conditions at the top and bottom lids…

We study the detection of electrons undergoing coherent transfer via adiabatic passage (CTAP) in a triple quantum-dot system with a quantum point-contact sensing the change of the middle dot. In the ideal scenario, the protocol amounts to…

Mesoscale and Nanoscale Physics · Physics 2019-04-24 Oded Zilberberg , Alessandro Romito

The simplest model of three coupled Bose-Einstein Condensates (BEC) is investigated using a group theoretical method. The stationary solutions are determined using the SU(3) group under the mean field approximation. This semiclassical…

Quantum Physics · Physics 2009-11-06 K. Nemoto , C. A. Holmes , G. J. Milburn , W. J. Munro

We investigate crystal nucleation in supersaturated colloid suspensions using enhanced molecular dynamics simulations augmented with machine learning techniques. The simulations reveal that crystallization in the model colloidal system…

Soft Condensed Matter · Physics 2024-04-30 Vanessa J. Meraz , Ziyue Zou , Pratyush Tiwary

A general theoretical framework is derived for the recently developed multi-state trajectory (MST) approach from the time dependent Schr\"odinger equation, resulting in equations of motion for coupled nuclear-electronic dynamics equivalent…

Chemical Physics · Physics 2017-09-13 Guohua Tao

Motivated by observations of snap-through phenomena in buckled elastic strips subject to clamping and lateral end translations, we experimentally explore the multi-stability and bifurcations of thin bands of various widths and compare these…

Soft Condensed Matter · Physics 2018-05-15 Tian Yu , J. A. Hanna

Molecular dynamics with the stochastic process provides a convenient way to compute structural and thermodynamic properties of chemical, biological, and materials systems. It is demonstrated that the virtual dynamics case that we proposed…

Statistical Mechanics · Physics 2018-03-20 Dezhang Li , Zifei Chen , Zhijun Zhang , Jian Liu

The mapping approach addresses the mismatch between the continuous nuclear phase space and discrete electronic states by creating an extended, fully continuous phase space using a set of harmonic oscillators to encode the populations and…

Chemical Physics · Physics 2019-09-30 Maximilian A. C. Saller , Aaron Kelly , Jeremy O. Richardson

Lobe dynamics and escape from a potential well are general frameworks introduced to study phase space transport in chaotic dynamical systems. While the former approach studies how regions of phase space are transported by reducing the flow…

Dynamical Systems · Mathematics 2017-11-22 Shibabrat Naik , Francois Lekien , Shane D. Ross

Trajectory-based methods that propagate classical nuclei on multiple quantum electronic states are often used to simulate nonadiabatic processes in the condensed phase. A long-standing problem of these methods is their lack of detailed…

Chemical Physics · Physics 2023-02-22 Graziano Amati , Johan E. Runeson , Jeremy O. Richardson

Quantum computation promises to provide substantial speedups in many practical applications with a particularly exciting one being the simulation of quantum many-body systems. Adiabatic state preparation (ASP) is one way that quantum…

Quantum Physics · Physics 2022-01-05 Vladimir Kremenetski , Carlos Mejuto-Zaera , Stephen J. Cotton , Norm M. Tubman

We theoretically examine three-well interferometry in Bose-Einstein condensates using adiabatic passage. Specifically, we demonstrate that a fractional coherent transport adiabatic passage protocol enables stable spatial splitting in the…

Quantum Gases · Physics 2015-06-05 M. Rab , A. L. C. Hayward , J. H. Cole , A. D. Greentree , A. M. Martin

We consider probabilistic models for sequential observations which exhibit gradual transitions among a finite number of states. We are particularly motivated by applications such as human activity analysis where observed accelerometer time…

Machine Learning · Computer Science 2023-09-22 Kevin C. Cheng , Shuchin Aeron , Michael C. Hughes , Eric L. Miller

A growing number of generative statistical models do not permit the numerical evaluation of their likelihood functions. Approximate Bayesian computation (ABC) has become a popular approach to overcome this issue, in which one simulates…

Methodology · Statistics 2019-05-10 Espen Bernton , Pierre E. Jacob , Mathieu Gerber , Christian P. Robert

The computational bottleneck of molecular dynamics is the pairwise additive long-range interactions between particles. The random batch Ewald (RBE) method provides a highly efficient and superscalable solver for long-range interactions, but…

Chemical Physics · Physics 2023-12-29 Jiuyang Liang , Zhenli Xu , Yue Zhao

We derive the fundamental equations of an optimal control theory for systems containing both quantum electrons and classical ions. The system is modeled with Ehrenfest dynamics, a non-adiabatic variant of molecular dynamics. The general…

Chemical Physics · Physics 2015-06-16 Alberto Castro , E. K. U. Gross
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