Related papers: Entropy augmentation through subadditive excess: i…
We consider several low--dimensional chaotic maps started in far-from-equilibrium initial conditions and we study the process of relaxation to equilibrium. In the case of conservative maps the Boltzmann-Gibbs entropy S(t) increases linearly…
The ``Gibbs Paradox'' refers to several related questions concerning entropy in thermodynamics and statistical mechanics: whether it is an extensive quantity or not, how it changes when identical particles are mixed, and the proper way to…
Dissipative quantum systems are frequently described within the framework of the so-called "system-plus-reservoir" approach. In this work we assign their description to the Maximum Entropy Formalism and compare the resulting thermodynamic…
This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both…
This study critically analyses the information-theoretic, axiomatic and combinatorial philosophical bases of the entropy and cross-entropy concepts. The combinatorial basis is shown to be the most fundamental (most primitive) of these three…
Due to the second principle of thermodynamics, the time dependence of entropy for all kinds of systems under all kinds of physical circumstances always thrives interest. The logistic map $x_{t+1}=1-a x_t^2 \in [-1,1]\;(a\in [0,2])$ is…
We ask the question whether entropy accumulates, in the sense that the operationally relevant total uncertainty about an $n$-partite system $A = (A_1, \ldots A_n)$ corresponds to the sum of the entropies of its parts $A_i$. The Asymptotic…
Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
It has recurrently been proposed that the Boltzmann textbook definition of entropy $S(E)=k\ln \Omega (E)$ in terms of the number of microstates $\Omega (E)$ with energy $E$ should be replaced by the expression $S_G(E)=k\ln \sum_{E^\prime…
Under certain conditions, the rate of increase of the statistical entropy of a simple, fully chaotic, conservative system is known to be given by a single number, characteristic of this system, the Kolmogorov-Sinai entropy rate. This…
If the N bosons that compose an ideal Bose-Einstein gas with energy E and volume V are each assumed to have the average energy of the system E/N, the entropy is easily expressed in terms of the number of bosons N and the number of…
This is a study of the information evolution of complex systems by geometrical consideration. We look at chaotic systems evolving in fractal phase space. The entropy change in time due to the fractal geometry is assimilated to the…
We develop an axiomatic reconstruction of thermodynamics based entirely on two primitive components: a description of what aspects of a system are observed and a reference measure that encodes the underlying descriptive convention. These…
Maximum-entropy ensembles are key primitives in statistical mechanics from which thermodynamic properties can be derived. Over the decades, several approaches have been put forward in order to justify from minimal assumptions the use of…
For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…
The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy.…
A first principles analysis of an open system thermodynamical Carnot cycle is provided, and the results are compared to those proposed by Gibbs for open systems. The Kelvin-Clausius statement concerning heat transfer for reversible cycles…
The Boltzmann entropy $S^{(B)}$ is true in the case of equal probability of all microstates of a system. In the opposite case it should be averaged over all microstates that gives rise to the Boltzmann--Shannon entropy (BSE). Maximum…
We examine information theory using the steady-state Boltzmann equation. In a nonequilibrium steady-state system under steady heat conduction, the thermodynamic quantities from information theory are calculated and compared with those from…