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Electroactive polymer thin films undergo repeated reversible structural change during operation in electrochemical applications. While synchrotron X-ray scattering is powerful for the characterization of stand-alone and ex-situ organic thin…

The electronic structure of the $(2\sqrt{2}\times\sqrt{2})R45^{\circ}$ O/Cu(001) system has been calculated using locally self-consistent, real space multiple scattering technique based on first principles. Oxygen atoms are found to perturb…

Materials Science · Physics 2009-11-07 S. Stolbov , T. S. Rahman

Employing electrons for direct control of nanoscale reaction is highly desirable since it provides fabrication of nanostructures with different properties at atomic resolution and with flexibility of dimension and location. Here, applying…

Effective regulation of the morphology of transition metal spinel structures is crucial for creating efficient and stable bifunctional catalysts for electrocatalysis of water. In this work, micro-flower NiCo2O4 (F-NCO) assembled by…

Chemical Physics · Physics 2024-03-27 Yujie Wang , Yan Duan , Yuwen Chen , Man Zhang , Yuchen Wang , Bin Liu , Xiaodie Zhang , Yutong Zhang , Kai Yan

Electrolyte gating is widely used to induce large carrier density modulation on solid surfaces to explore various properties. Most of past works have attributed the charge modulation to electrostatic field effect. However, some recent…

Active sites and catalytic mechanism of nitrogen-doped graphene in oxygen reduction reaction (ORR) have been extensively studied but are still inconclusive, partly due to the lack of an experimental method that can detect the active sites.…

Mesoscale and Nanoscale Physics · Physics 2014-10-29 Tan Xing , Yao Zheng , Lu Hua Li , Bruce C. C. Cowie , Daniel Gunzelmann , Shi Zhang Qiao , Shaoming Huang , Ying Chen

Charge-transfer excitations are of paramount importance for understanding the electronic structure of copper-oxide based high-temperature superconductors. In this study, we investigate the response of a Bi$_2$Sr$_2$CaCu$_2$O$_{\mathrm{8}+…

The oriented attachment (OA) of nanoparticles is an important mechanism for the synthesis of the crystals of inorganic functional materials, and the formation of natural minerals. For years it has been generally acknowledged that OA is a…

Tandem catalysis involves two or more catalysts arranged in proximity within a single reaction vessel, with the aim of synergistically aligning the catalysts' reaction pathways to maximize overall system performance. This study presents a…

Electrochemical CO2 reduction (CO2R) offers a promising approach to decarbonize chemical manufacturing through production of carbon-neutral fuels. However, insufficient performance and instability of membrane electrode assembly (MEA)…

Correlating the microstructure of an energy conversion device to its performance is often a complex exercise, notably in solid oxide fuel cell (SOFC) research. SOFCs combine multiple materials and interfaces that evolve in time due to high…

Nanoporous Cu (NPC), synthesized by chemical dealloying of brass, holds significant potential for catalysis of electrochemical CO2 and CO reduction, owing to the optimal binding energy of Cu with *CO and *H intermediates, and the abundance…

Using electrodeposition, we have grown nanowires of ZnCoO with Cu codoping concentrations varying from 4-10 at.%, controlled only by the deposition potential. We demonstrate control over magnetic Co oxide nano-precipitate formation in the…

Materials Science · Physics 2014-12-30 S. Granville , E. Matei , I. Enculescu , M. Eugenia Toimil-Molares

In this study, we address the significant challenge of overcoming limitations in catalytic efficiency for the oxygen evolution reaction (OER). The current linear scaling relationships hinder the optimization of electrocatalytic performance.…

Materials Science · Physics 2023-06-06 Swetarekha Ram , Gwan Hyun Choi , Albert S. Lee , Seung-Cheol Lee , Satadeep Bhattacharjee

NiFe oxyhydroxide is one of the most promising oxygen evolution reaction (OER) catalysts for renewable hydrogen production, and deciphering the identity and reactivity of the oxygen intermediates on its surface is a key challenge but is…

Materials Science · Physics 2020-10-01 Yaming Hao , Yefei Li , Jianxiang Wu , Jinling Wang , Chenglin Jia , Tao Liu , Xuejing Yang , Zhipan Liu , Ming Gong

Understanding the atomic-scale interaction mechanism of CO$_2$ and H$_2$O on TiO$_2$ surface is crucial to establish a correlation between the catalytic efficiency with its exposed facet. Here, with the aid of a three-state model, nudged…

Materials Science · Physics 2020-08-07 Shashi B. Mishra , B. R. K. Nanda

Achieving operating conditions comparable to ``bulk'' electronic devices, such as thin film capacitors, during \textit{operando} electron microscopy remains challenging, particularly when devices are grown on non-conductive substrates.…

The current study illustrates the successful synthesis of Ce$_{1.0}$Mn$_{0.9}$Co$_{0.1}$ nanoparticles, characterized through XRD, EPR, magnetization curves, and TEM/HRTEM/EDX analyses. These nanoparticles were then loaded into the carbon…

Catalysis is indispensable to chemical processes and relevant to many aspects of modern life. Owing to the intriguing electronic structures and good ionic properties, multivalent transition metal oxides have attracted attention as key…

High temperature superconductors, especially YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO), are considered a key enabling technology towards a clean energy future. Hole doping in YBCO is a prerequisite for the emergence of its unchallenged…

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