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The chemical evolution in star forming regions is driven by the interplay between gas and ice mantles. Identifying the ice compositions at the early stage of star formation thus provides constraints on the chemical processes inaccessible…

Astrophysics of Galaxies · Physics 2026-02-06 Andrew M. Turner , Yao-Lun Yang , Rachel Gross , Nami Sakai , Ralf I. Kaiser

Within the framework of The Heterogeneous dust Evolution Model at the IaS (THEMIS) this work investigates in detail the surface processes and chemistry relating to core/mantle interstellar and cometary grain structures and its influence on…

Astrophysics of Galaxies · Physics 2021-11-09 A. P. Jones

In the past decade, there has been a significant shift in astrochemistry with a renewed focus on the role of non-thermal processes on the molecular interstellar medium, in particular energetic particles (such as cosmic ray particles and…

Astrophysics of Galaxies · Physics 2026-01-12 Brandt A. L. Gaches , Serena Viti

Computational chemistry plays a relevant role in many astrochemical research fields, either by complementing experimental measurements or by deriving parameters difficult to be reproduced by laboratories. While the role of computational…

Astrophysics of Galaxies · Physics 2024-09-12 Francesca Tonolo , Silvia Alessandrini

Cosmic dust grains are one of the fundamental ingredients of the interstellar medium (ISM). In spite of their small contribution to the total mass budget, dust grains play a significant role in the physical and chemical evolution of…

Astrophysics of Galaxies · Physics 2022-02-09 Angelos Nersesian , Maarten Baes , Suzanne C. Madden

The presence of carbon-chain molecules in the interstellar medium (ISM) has been known since the early 1970s and $>130$ such species have been identified to date, making up $\sim 43$% of the total of detected ISM molecules. They are…

Astrophysics of Galaxies · Physics 2024-04-15 Kotomi Taniguchi , Prasanta Gorai , Jonathan C. Tan

The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…

Solar and Stellar Astrophysics · Physics 2009-11-13 R. J. van Weeren , C. Brinch , M. R. Hogerheijde

We use a suite of hydrodynamics simulations of the interstellar medium (ISM) within a galactic disk, which include radiative transfer, a non-equilibrium model of molecular hydrogen, and a realistic model for star formation and feedback, to…

Astrophysics of Galaxies · Physics 2024-05-07 Ava Polzin , Andrey V. Kravtsov , Vadim A. Semenov , Nickolay Y. Gnedin

Our main purpose is to estimate the effect of assuming uniform density on the line-of-sight in PDR chemistry models, compared to a more realistic distribution for which total gas densities may well vary by several orders of magnitude. A…

Astrophysics of Galaxies · Physics 2016-11-11 François Levrier , Franck Le Petit , Patrick Hennebelle , Pierre Lesaffre , Maryvonne Gerin , Edith Falgarone

A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…

Astrophysics of Galaxies · Physics 2022-02-23 Robin T. Garrod , Mihwa Jin , Kayla A. Matis , Dylan Jones , Eric R. Willis , Eric Herbst

Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…

Astrophysics · Physics 2009-11-13 Robin T. Garrod , Susanna L. Widicus Weaver , Eric Herbst

We make use of our 'minimal' cold interstellar medium (ISM) emission line model that predicts the molecular and atomic line emission per unit dense, star-forming gas mass (Geach & Papadopoulos 2012; Paper I) to examine the utility of key…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-05 Padelis P. Papadopoulos , James E. Geach

Non-linear behavior in interstellar chemical models has been recognized for 25 years now. Different mechanisms account for the possibility of multiple fixed-points at steady state, characterized by the ionization degree of the gas. Chemical…

Astrophysics of Galaxies · Physics 2020-11-11 Evelyne Roueff , Jacques Le Bourlot

Physical and chemical properties of the interstellar medium (ISM) at sub-galactic ($\sim$kpc) scales play an indispensable role in controlling the ability of gas to form stars. As part of the SMAUG (Simulating Multiscale Astrophysics to…

This work is the continuation of a series attempting to characterize the local warm ionized medium through both static and time dependent simulations. We build upon our three dimensional, observationally-derived simulation of the local…

Astrophysics of Galaxies · Physics 2025-06-24 Lewis McCallum , Kenneth Wood , Robert Benjamin , Dhanesh Krishnarao , Anna F. McLeod

Dust plays a key role in the evolution of the ISM and its correct modelling in numerical simulations is therefore fundamental. We present a new and self-consistent model that treats grain thermal coupling with the gas, radiation balance,…

Astrophysics of Galaxies · Physics 2017-01-25 T. Grassi , S. Bovino , T. Haugboelle , D. R. G. Schleicher

The modelling of molecular excitation and dissociation processes relevant to astrochemistry requires the validation of theories by comparison with data generated from laboratory experimentation. The newly commissioned Ice Chamber for…

We introduce TIGRESS, a novel framework for multi-physics numerical simulations of the star-forming interstellar medium (ISM) implemented in the Athena MHD code. The algorithms of TIGRESS are designed to spatially and temporally resolve key…

Astrophysics of Galaxies · Physics 2017-09-20 Chang-Goo Kim , Eve C. Ostriker

Molecular gas is the key ingredient of the star formation cycle, and tracing its dependencies on other galaxy properties is essential for understanding galaxy evolution. In this work, we explore the relation between the different phases of…

Astrophysics of Galaxies · Physics 2025-07-23 Francesco Salvestrini , Simone Bianchi , Edvige Corbelli

Here we present our current updates of the gas-phase chemical reaction rates and molecular lines in the spectral synthesis code CLOUDY, and its implications in spectroscopic modelling of various astrophysical environments. We include energy…

Astrophysics of Galaxies · Physics 2022-08-03 Gargi Shaw , G. J. Ferland , M. Chatzikos
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