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We discuss modulation phasons as a possible source of unusual elastic behavior of five-layer modulated (10\,M) martensite of the Ni-Mn-Ga shape memory alloy. This material exhibits anomalous macroscopic shear compliance along specific…

Materials Science · Physics 2026-05-01 Petr Sedlák , Tomáš Grabec , Hanuš Seiner

Structural modulation is a key ingredient behind the extraordinary (magneto)elastic response of Ni-Mn-Ga martensite, yet its link to fine twinned microstructure and twin-boundary supermobility remains unresolved. Here we analyse martensitic…

We investigate relative stability, structural properties and electronic structure of various modulated martensites of the magnetic shape memory alloy Mn$_{2}$NiGa by means of density functional theory. We observe that the instability in the…

Materials Science · Physics 2017-08-23 Ashis Kundu , Markus E. Gruner , Mario Siewert , Alfred Hucht , Peter Entel , Subhradip Ghosh

The impact of shear deformation in $(1\,0\,1)[1\,0\,\bar{1}]$ system of non-modulated (NM) martensite in Ni$_2$MnGa ferromagnetic shape memory alloy is investigated by means of ab initio atomistic simulations. The shear system is associated…

Materials Science · Physics 2024-11-11 Martin Heczko , Petr Šesták , Hanuš Seiner , Martin Zelený

Recently, several research groups have reported on the observation of super-large more than 5% magneto-strain effect in some non-stoichiometric Ni-Mn-Ga alloys close to 5.78% value expected from the tetragonality aspect ratio of the…

Materials Science · Physics 2009-10-31 A. A. Likhachev , K. Ullakko

Modulated martensites play an important role in magnetic shape memory alloys, because all functional properties are closely connected to the twin microstructure and the phase boundary. The nature of the modulated martensites is still…

Materials Science · Physics 2017-04-19 Robert Niemann , Sebastian Fähler

Understanding the crystal structure of magnetic shape memory alloys is crucial for insights into their unique properties, such as the high mobility of twin boundaries and magnetic field functionality. The complex neutron diffraction…

Materials Science · Physics 2024-06-25 P. Veřtát , M. Klicpera , O. Fabelo , O. Heczko , L. Straka

The local atomic structure of Ni-Mn-Ga alloys was explored using Mn and Ga K-edge extended X-ray fine structure (EXAFS) measurement. The changes occuring in the L1$_0$ sub-cell of the martensitic unit cell and the bond lengths obtained from…

Materials Science · Physics 2007-05-23 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

Modulated phases occur in numerous functional materials like giant ferroelectrics and magnetic shape memory alloys. To understand the origin of these phases, we review and generalize the concept of adaptive martensite. As a starting point,…

Materials Science · Physics 2015-05-13 S. Kaufmann , U. K. Roessler , O. Heczko , M. Wuttig , J. Buschbeck , L. Schultz , S. Fahler

Heusler alloys exhibiting magnetic and martensitic transitions enable applications like magnetocaloric refrigeration and actuation based on the magnetic shape memory effect. Their outstanding functional properties depend on low hysteresis…

Diffusionless phase transitions are at the core of the multifunctionality of (magnetic) shape memory alloys, ferroelectrics and multiferroics. Giant strain effects under external fields are obtained in low symmetric modulated martensitic…

Twin boundaries play an essential role in the use of magnetic shape memory alloy Ni-Mn-Ga as active material. Only if twin boundaries can be moved by an external magnetic field, high strain values of up to 10 % can be obtained. Therefore,…

In the present work, the aspects of magnetic and structural properties of Ni-Mn-Ga alloys are described in the framework of fist-principles approach and mapped into ternary composition diagrams. The stable atomic arrangement and magnetic…

Materials Science · Physics 2020-03-23 Yu. Sokolovskaya , O. Miroshkina , V. Sokolovskiy , M. Zagrebin , V. Buchelnikov , A. Zayak

Magnetic, transport, and x-ray diffraction measurements of ferromagnetic shape memory alloy Ni$_{2.16}$Mn$_{0.84}$Ga revealed that this alloy undergoes an intermartensitic transition upon cooling, whereas no such a transition is observed…

Materials Science · Physics 2009-11-10 V. V. Khovailo , K. Oikawa , C. Wedel , T. Takagi , T. Abe , K. Sugiyama

This article presents a brief overview of our recent work on the nature of long period modulation in the premartensite and martensite phases of Ni2MnGa ferromagnetic shape memory alloy using high resolution synchrotron x-ray powder…

Materials Science · Physics 2015-06-16 Sanjay Singh , S. R. Barman , D. Pandey

In search for the origins of the extraordinary low twinning stress of Ni-Mn-Ga magnetic shape memory alloys we studied the thermally induced changes of structure in Ni$_{50}$Mn$_{25+x}$Ga$_{25-x}$ ($x$=2.7--3.9) single crystal samples and…

The modulated structure of the martensite phase of Ni2MnGa is revisited using high resolution synchrotron x-ray powder diffraction (SXRPD) measurements, which reveals higher order satellite reflections up to the 3rd order and phason…

Materials Science · Physics 2014-08-04 Sanjay Singh , V. Petricek , Parasmani Rajput , Adrian H. Hill , E. Suard , S. R. Barman , Dhananjai Pandey

Influence of disorder, antisite defects, martensite transition and compositional variation on the magnetic properties and electronic structure of Mn$_2$NiGa and Mn$_{1+x}$Ni$_{2-x}$Ga magnetic shape memory alloys have been studied by using…

Materials Science · Physics 2015-06-17 Sunil Wilfred D'Souza , Tufan Roy , Sudipta Roy Barman , Aparna Chakrabarti

The magnetic correlations in the austenite phase and the consequent martensitic transition in inverse magnetocaloric alloys, Ni$_{2}$Mn$_{1+x}$Sn$_{1-x}$, have been a matter of debate for decades. We conclusively establish using {\it ab…

Strongly Correlated Electrons · Physics 2018-11-13 Vijay Singh , Ambroise van Roekeghem , S. K. Panda , S. Majumdar , Natalio Mingo , I Dasgupta

Magnetic shape memory alloys exhibit a hierarchically twinned microstructure, which has been well examined in epitaxial Ni-Mn-Ga films. Here we analyze consequences of this twin within twins microstructure on the magnetic domain pattern.…

Materials Science · Physics 2015-06-12 Anett Diestel , Volker Neu , Anja Backen , Ludwig Schultz , Sebastian Fähler
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