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From a symmetry perspective, ferroaxial order belongs to the same symmetry as time-reversal-even pseudovectors. Experimentally, ${\rm K_2Zr(PO_4)_2}$ is known to undergo a displacive-type phase transition from a non-ferroaxial to a…

Materials Science · Physics 2025-12-22 Yu Xie , Rikuto Oiwa , Satoru Hayami

Orbital angular momentum and torque transfer play central roles in a wide range of magnetic textures and devices including skyrmions and spin-torque electronics(1-4). Analogous topological structures are now also being explored in…

Although ferroelectric materials are characterised by their parallel arrangement of electric dipoles, in the right boundary conditions these dipoles can reorganize themselves into vortices, antivortices and other non-trivial topological…

A ferroic alignment of a time-reversal-even axial vector, which is called the ferroaxial ordered state, is identified by the spontaneous rotational distortion of the lattice structure to break the vertical mirror symmetry. We theoretically…

Strongly Correlated Electrons · Physics 2024-12-03 Akane Inda , Satoru Hayami

A ferroaxial ordering, which appears without mirror symmetry parallel to an electric axial moment, is described by a ferroic alignment of the electric toroidal (ET) dipole rather than the conventional electric and magnetic dipoles. Although…

Strongly Correlated Electrons · Physics 2023-11-23 Akimitsu Kirikoshi , Satoru Hayami

We present a first principles study of the ferrochiral phase transition in chiral BaTiOCu$_4$(PO$_4$)$_4$, which has been shown using X-ray diffraction to proceed via the antiferroaxial rotation of antipolar structural units. We analyze the…

Materials Science · Physics 2026-05-05 Alex Hallett , Nicola A. Spaldin

We investigate electric polarizations emergent perpendicular to an applied thermal gradient in insulating systems. The thermally-induced electric polarization, known as thermopolarization, has been studied conventionally in the case that an…

Strongly Correlated Electrons · Physics 2022-06-29 Joji Nasu , Satoru Hayami

A toroidal dipole moment appears independent of the electric and magnetic dipole moment in the multipole expansion of electrodynamics. It arises naturally from vortex-like arrangements of spins. Observing and controlling spontaneous…

Ferroelectric materials embedded with dielectric inclusions offer a unique platform for exploring novel topological polar textures. Using first-principles-based atomistic simulations, we investigate the polarization behavior of a BaTiO$_3$…

Materials Science · Physics 2026-03-12 R. Machado , F. Di Rino , M. Sepliarsky , M. G. Stachiotti

In the early 2000s, low dimensional systems were predicted to have topologically nontrivial polar structures, such as vortices or skyrmions, depending on mechanical or electrical boundary conditions. A few variants of these structures have…

The ordering of magnetic or electric dipoles leading to real-space topological structures is at the forefront of materials research as their quantum mechanical nature often lends itself to emergent properties. Atomic lattice vibrations…

Interaction between dipoles often emerges intriguing physical phenomena, such as exchange bias in the magnetic heterostructures and magnetoelectric effect in multiferroics, which lead to advances in multifunctional heterostructures.…

This letter addresses basic questions concerning ferroelectric order in positionally disordered dipolar materials. Three models distinguished by dipole vectors which have one, two or three components are studied by computer simulation.…

Condensed Matter · Physics 2009-10-28 G. Ayton , M. J. P. Gingras , G. N. Patey

Metal-organic frameworks comprehend a wide class of hybrid organic-inorganic materials with general structure A$_m$BX$_n$, with $A$ and $X$ being organic molecules and B a metal cation. This often results in enhanced structural flexibility…

Materials Science · Physics 2022-04-21 Francesco Foggetti , Alessandro Stroppa , Sergey Artyukhin

In this short article, we overview a concept of electronic toroidal multipoles, and their ordering with associated physical properties in non-magnetic and magnetic materials. The toroidal multipoles are introduced as microscopic electronic…

Materials Science · Physics 2024-09-12 Hiroaki Kusunose , Satoru Hayami

In this paper we present an analysis of the magnetic toroidal moment and its relation to the various structural modes in R3c-distorted perovskites with magnetic cations on either the perovskite A or B site. We evaluate the toroidal moment…

Materials Science · Physics 2015-05-13 Claude Ederer

Ferroelectricity in BaTiO3 was observed nearly eighty years ago, but the mechanism underlying its ferroelectric-paraelectric phase transition remains elusive. The order-disorder transition has been recognized as playing a critical role,…

Materials Science · Physics 2025-10-02 Yang Zhang , Xiaoming Shi , Suk Hyun Sung , Cong Li , Houbing Huang , Pu Yu , Ismail El Baggari

We report from first-principles-based atomistic simulations that ferroelectricity can be sustained in PbTiO3 nanoparticles of only a few lattice constants in size as a result of a toroidal ordering. We found that size-induced topological…

Materials Science · Physics 2015-05-27 M. G. Stachiotti , M. Sepliarsky

The recent observation of a ferroelectric-like structural transition in metallic LiOsO$_3$ has generated a flurry of interest in the properties of polar metals. Such materials are thought to be rare because free electrons screen out the…

Materials Science · Physics 2016-02-29 Nicole A. Benedek , Turan Birol

The first switchable electric polarization in metals was recently discovered in bilayer and trilayer WTe2. Strangely, despite the tininess of the ordered polarization, the ferroelectricity survives up to 350 K, rendering the mechanism of…

Materials Science · Physics 2025-07-25 Fangyuan Gu , Ruoshi Jiang , Wei Ku
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