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Van der Waals (vdW) interactions are essential for describing molecules and materials, from drug design and catalysis to battery applications. These omnipresent interactions must also be accurately included in machine-learned force fields.…

Chemical Physics · Physics 2026-02-26 Evgeny Moerman , Adil Kabylda , Almaz Khabibrakhmanov , Alexandre Tkatchenko

Accurate treatment of the long-range electron correlation energy, including van der Waals (vdW) or dispersion interactions, is essential for describing the structure, dynamics, and function of a wide variety of systems. Among the most…

Computational Physics · Physics 2016-05-19 Martin A. Blood-Forsythe , Thomas Markovich , Robert A. DiStasio , Roberto Car , Alán Aspuru-Guzik

An accurate determination of the electron correlation energy is essential for describing the structure, stability, and function in a wide variety of systems, ranging from gas-phase molecular assemblies to condensed matter and…

Chemical Physics · Physics 2014-03-05 Alberto Ambrosetti , Anthony M. Reilly , Robert A. DiStasio , Alexandre Tkatchenko

Many-body dispersion (MBD) is a powerful framework to treat van der Waals (vdW) dispersion interactions in density-functional theory and related atomistic modeling methods. Several independent implementations of MBD with varying degree of…

We present a comprehensive methodology to enable addition of van der Waals (vdW) corrections to machine learning (ML) atomistic force fields. Using a Gaussian approximation potential (GAP) [Bart\'ok et al., Phys. Rev. Lett. 104, 136403…

The many-body dispersion (MBD) framework is a successful approach for modeling the long-range electronic correlation energy and optical response of systems with thousands of atoms. Inspired by field theory, here we develop a…

Chemical Physics · Physics 2023-04-26 Matteo Gori , Philip Kurian , Alexandre Tkatchenko

Noncovalent van der Waals (vdW) interactions are responsible for a wide range of phenomena in matter. Popular density-functional methods that treat vdW interactions use disparate physical models for these intricate forces, and as a result…

Materials Science · Physics 2020-04-15 Jan Hermann , Alexandre Tkatchenko

We present a structured force reformulation of the many-body dispersion (MBD) model that enables a physically consistent decomposition of forces into pairwise components. By introducing a many-body correlation matrix that scales…

Computational Physics · Physics 2026-04-14 Zhaoxiang Shen , Raúl I. Sosa , Stéphane P. A. Bordas , Alexandre Tkatchenko , Jakub Lengiewicz

Accurate prediction of many-body dispersion (MBD) interactions is essential for understanding the van der Waals forces that govern the behavior of many complex molecular systems. However, the high computational cost of MBD calculations…

Machine Learning · Computer Science 2026-04-01 Zhaoxiang Shen , Raúl I. Sosa , Jakub Lengiewicz , Alexandre Tkatchenko , Stéphane P. A. Bordas

A correct description of electronic exchange and correlation effects for molecules in contact with extended (metal) surfaces is a challenging task for first-principles modeling. In this work we demonstrate the importance of collective van…

Materials Science · Physics 2016-09-05 Reinhard J. Maurer , Victor G. Ruiz , Alexandre Tkatchenko

Recent work has shown that a fully many-body treatment of noncovalent interactions, such as that given by the method of many-body dispersion (MBD), is vital to accurately modeling the structure and energetics of many molecular systems with…

An efficient numerical method is developed using the matrix product formalism for computing the properties at finite energy densities in one-dimensional (1D) many-body localized (MBL) systems. Arguing that any efficient (possibly quantum)…

Disordered Systems and Neural Networks · Physics 2015-08-20 Yichen Huang

Electronic nearsightedness is one of the fundamental principles governing the behavior of condensed matter and supporting its description in terms of local entities such as chemical bonds. Locality also underlies the tremendous success of…

Computational Physics · Physics 2020-09-01 Andrea Grisafi , Jigyasa Nigam , Michele Ceriotti

The Many-Body Expansion (MBE) is a useful tool to simulate condensed phase chemical systems, often avoiding the steep computational cost of usual electronic structure methods. However, it often requires higher than 2-body terms to achieve…

Chemical Physics · Physics 2019-11-21 Srimukh Prasad Veccham , Joonho Lee , Martin Head-Gordon

Recent advances in machine-learned interatomic potentials largely benefit from the atomistic representation and locally invariant many-body descriptors. It was however recently argued that including three- (or even four-) body features is…

Chemical Physics · Physics 2021-10-14 Yaolong Zhang , Junfan Xia , Bin Jiang

We are interested in how quantum data can allow for practical solutions to otherwise difficult computational problems. A notoriously difficult phenomenon from quantum many-body physics is the emergence of many-body localization (MBL). So…

Disordered Systems and Neural Networks · Physics 2022-02-21 Alexander Gresch , Lennart Bittel , Martin Kliesch

We examine how effective-model-space (EMS) calculations of nuclear many-body systems rearrange and converge multi-particle entanglement. The generalized Lipkin-Meshkov-Glick (LMG) model is used to motivate and provide insight for future…

Nuclear Theory · Physics 2024-01-02 S. Momme Hengstenberg , Caroline E. P. Robin , Martin J. Savage

Spherically-symmetric atom-centered descriptors of atomic environments have been widely used for constructing potential or free energy surfaces of atomistic and colloidal systems and to characterize local structures using machine learning…

Soft Condensed Matter · Physics 2022-07-27 Gerardo Campos-Villalobos , Giuliana Giunta , Susana Marín-Aguilar , Marjolein Dijkstra

Many-body localization (MBL) features are studied here for a large spin chain model with long range interactions. The model corresponds to cold atoms placed inside a cavity and driven by an external laser field with long range interactions…

Disordered Systems and Neural Networks · Physics 2022-02-28 Titas Chanda , Jakub Zakrzewski

Introducing low-energy effective Hamiltonians is usual to grasp most correlations in quantum many-body problems. For instance, such effective Hamiltonians can be treated at the mean-field level to reproduce some physical properties of…

Quantum Gases · Physics 2025-01-09 Raphaël Photopoulos , Antoine Boulet
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