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A simple approximation within the framework of the hybrid methods for the calculation of the electronic structure of solids is presented. By considering only the diagonal elements of the perturbation operator (Hartree-Fock exchange minus…

Materials Science · Physics 2012-01-31 Fabien Tran

Symplectic integrators are the established standard for long-term simulations of nearly-integrable Hamiltonian systems due to their preservation of geometric structures. However, they suffer from an inherent limitation: secular phase-shift…

Numerical Analysis · Mathematics 2026-02-19 Mingwei Fu , Bin Shi

Partial differential equations (PDEs) are fundamental across numerous scientific fields. As these problems scale to high dimensions, classical numerical schemes introduce severe computational bottlenecks, known as the curse of…

Quantum Physics · Physics 2026-04-29 Chih-Kang Huang , Giacomo Antonioli , Frédéric Barbaresco

We review our recently developed electronic structure calculation methods used for the dynamics of large-scale solids or liquids with an efficient algorithm for large scale simultaneous linear equations. The electronic structure calculation…

Materials Science · Physics 2011-02-02 T. Fujiwara , S. Yamamoto , T. Hoshi , S. Nishino , H. Teng , T. Sogabe , S. -L. Zhang , M. Ikeda , M. Nakashima , N. Watanabe

Numerical relativity has traditionally been pursued via finite differencing. Here we explore pseudospectral collocation (PSC) as an alternative to finite differencing, focusing particularly on the solution of the Hamiltonian constraint (an…

General Relativity and Quantum Cosmology · Physics 2009-10-31 Lawrence E. Kidder , Lee Samuel Finn

The Bethe-Salpeter equation (BSE) is currently the state of the art in the description of neutral electron excitations in both solids and large finite systems. It is capable of accurately treating charge-transfer excitations that present…

Quantum computation has the potential to revolutionize quantum chemistry through major speedups to computation times and exponential reduction of computational resources. Here, we combine the symmetry-adapted Jordan-Wigner encoding based on…

Chemical Physics · Physics 2025-08-21 Joseph Desroches , Sijia S. Dong

The computation of vibrational spectra of diatomic molecules through the exact diagonalization of algebraically determined matrixes based on powers of Morse coordinates is made substantially more efficient by choosing a properly adapted…

Chemical Physics · Physics 2016-09-28 Andrea Bordoni , Nicola Manini

Quantum Monte Carlo (QMC) is an advanced simulation methodology for studies of manybody quantum systems. In this review, we focus on the electronic structure QMC, i.e., methods relevant for systems described by the electron-ion…

Other Condensed Matter · Physics 2010-08-16 Michal Bajdich , Lubos Mitas

We present a new solver for coupled nonlinear elliptic partial differential equations (PDEs). The solver is based on pseudo-spectral collocation with domain decomposition and can handle one- to three-dimensional problems. It has three…

General Relativity and Quantum Cosmology · Physics 2009-11-07 Harald P. Pfeiffer , Lawrence E. Kidder , Mark A. Scheel , Saul A. Teukolsky

We propose a unique scheme to construct fully optimized atomic basis sets for density-functional calculations. The shapes of the radial functions are optimized by minimizing the {\it spillage} of the wave functions between the atomic…

Materials Science · Physics 2015-05-19 Mohan Chen , G-C Guo , Lixin He

Including the effect of the molecular environment in the numerical modeling of time-resolved electronic spectroscopy remains an important challenge in computational spectroscopy. In this contribution, we present a general approach for the…

Quantum Physics · Physics 2024-12-17 Federico Gallina , Matteo Bruschi , Roberto Cacciari , Barbara Fresch

Hamiltonian representations based on the sum-of-squares (SOS) hierarchy provide rigorous lower bounds on ground-state energies and facilitate the design of efficient classical and quantum simulation algorithms. This work presents a unified…

Quantum Physics · Physics 2026-02-06 Nicholas C. Rubin , Guang Hao Low , A. Eugene DePrince

The need for accurate calculations on atoms and diatomic molecules is motivated by the opportunities and challenges of such studies. The most commonly-used approach for all-electron electronic structure calculations in general - the linear…

Chemical Physics · Physics 2019-08-19 Susi Lehtola

We present a numerical technique for solving evolution equations, as the wave equation, in the description of rotating astrophysical compact objects in comoving coordinates, which avoids the problems associated with the light cylinder. The…

General Relativity and Quantum Cosmology · Physics 2008-11-26 Silvano Bonazzola , José-Luis Jaramillo , Jerome Novak

Quasi-one-dimensional quantum structures with spectra scaling faster than the square of the eigenmode number (superscaling) can generate intrinsic, off-resonant optical nonlinearities near the fundamental physical limits, independent of the…

Optics · Physics 2015-10-28 Rick Lytel , Sean M. Mossman , Mark G. Kuzyk

This paper introduces the sparsifying preconditioner for the pseudospectral approximation of highly indefinite systems on periodic structures, which include the frequency-domain response problems of the Helmholtz equation and the…

Numerical Analysis · Mathematics 2014-09-18 Lexing Ying

Increasing attention is being focussed on the use of symmetry-adapted functions to describe magnetic structures, structural distortions, and incommensurate crystallography. Though the calculation of such functions is well developed,…

Materials Science · Physics 2016-10-04 Zoso Davies , Andrew Wills

We propose a scheme for imaging periodic surfaces using a superlens. By employing an inverse scattering model and the transformed field expansion method, we derive an approximate reconstruction formula for the surface profile, assuming…

Numerical Analysis · Mathematics 2024-03-05 Peijun Li , Yuliang Wang

Correlated phenomena occur in quantum materials because of the delicate interplay between internal degrees of freedom, leading to multiple symmetry-broken quantum phases. Resolving the structure of these phases is a key challenge, often…