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It is a common view in philosophy of physics that thermodynamics is a non-fundamental theory. This is motivated in particular by the fact that thermodynamics is considered to be a paradigmatic example for a theory that can be reduced to…

History and Philosophy of Physics · Physics 2022-04-12 Michael te Vrugt , Paul Needham , Georg J. Schmitz

Optimality principles in nonequilibrium transport networks are linked to a thermodynamic formalism based on generalized transport potentials endowed with Legendre duality and related contact structure. This allows quantifying the distance…

Statistical Mechanics · Physics 2025-06-23 Amilcare Porporato , Shashank Kumar Anand , Salvatore Calabrese , Luca Ridolfi , Lamberto Rondoni

We discuss here the use of generalized forms of entropy, taken as information measures, to characterize phase transitions and critical behavior in thermodynamic systems. Our study is based on geometric considerations pertaining to the space…

Statistical Mechanics · Physics 2009-04-14 M. Portesi , F. Pennini , A. Plastino

The explanation of the apparent universality of thermodynamics points toward the extension of the usual conceptual background of the second law. Arguments are collected that a basic guiding idea of stability of thermodynamic equilibrium…

Classical Physics · Physics 2014-07-23 P. Ván

We show that thermodynamics can be formulated naturally from the intrinsic geometry of phase space alone-without postulating an ensemble, which instead emerges from the geometric structure itself. Within this formulation, phase transitions…

Statistical Mechanics · Physics 2025-12-03 Loris Di Cairano

Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 170 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We have constructed a nonextensive thermodynamic formalism consisting of two sets of parallel Legendre transformation structures in previous papers. One is the physical set and the other is the Lagrange set. In this paper we study the…

Statistical Mechanics · Physics 2018-04-24 Zheng Yahui , Du Jiulin , Liang Faku

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Quantum Physics · Physics 2019-11-21 Gian Paolo Beretta , Enzo Zanchini

In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…

Statistical Mechanics · Physics 2025-01-22 Markus Hofer , Jan Korbel , Rudolf Hanel , Stefan Thurner

Motivated by the notion that the mathematics of gravity can be reproduced from a statistical requirement of maximal entropy, we study the consequence of introducing an entropic source term in the Einstein-Hilbert action. For a spatially…

General Relativity and Quantum Cosmology · Physics 2024-03-20 Soumya Chakrabarti

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

In economics, construction of perfect models in a way that would be comparable to the standards customary in physical sciences is generally not feasible. In particular, the observed value for an economic equilibrium may deviate…

Probability · Mathematics 2026-01-05 Esa Nummelin , Elja Arjas

In geometrothermodynamics (GTD), to study the geometric properties of the equilibrium space three thermodynamic metrics have been proposed so far. These metrics are obtained by using the condition of Legendre invariance and can be computed…

Mathematical Physics · Physics 2019-08-16 Viridiana Pineda , Hernando Quevedo , Maria N. Quevedo , Alberto Sanchez , Edgar Valdes

We present an argument which purports to show that the use of the standard Legendre transform in non-additive Statistical Mechanics is not appropriate. For concreteness, we use as paradigm, the case of systems which are conjecturally…

Statistical Mechanics · Physics 2017-08-02 Nikolaos Kalogeropoulos

In traditional thermodynamical and statistical-mechanical approaches one has (some) detailed knowledge of the principles governing the microdynamics of a system. However in many instances we may not have a Hamiltonian or good information…

Statistical Mechanics · Physics 2007-05-23 David Ford

We consider the main physical notions and phenomena described by the author in his mathematical theory of thermodynamics. The new mathematical model yields the equation of state for a wide class of classical gases consisting of non-polar…

General Physics · Physics 2018-09-07 V. P. Maslov

A single mechanism, endemic to the standard model of physics, is proposed to explain wavefunction collapse, classical motion, dissipation, equilibration, and the transition from pure quantum mechanics through open system decoherence to the…

General Physics · Physics 2024-09-23 J. H. Brownell

Thermodynamic length is a metric distance between equilibrium thermodynamic states that asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. By means of thermodynamic length, we first…

Statistical Mechanics · Physics 2022-01-27 Carlo Cafaro , Orlando Luongo , Stefano Mancini , Hernando Quevedo

The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…

Statistical Mechanics · Physics 2020-07-01 S. N. Saadatmand , Tim Gould , E. G. Cavalcanti , J. A. Vaccaro

This article is written in memory of Pierre Hohenberg with appreciation for his deep commitment to the basic principles of theoretical physics. I summarize recent developments in the theory of dislocation-enabled deformation of crystalline…

Materials Science · Physics 2019-02-20 J. S. Langer
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