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The atomic motion in molecular crystals, such as high-pressure hydrogen or hybrid organic-inorganic perovskites, is very complex due to quantum anharmonic effects. In addition, these materials accommodate rotational degrees of freedom. All…

Materials Science · Physics 2024-10-04 Antonio Siciliano , Lorenzo Monacelli , Francesco Mauri

Most material properties of great physical interest are directly related to nuclear dynamics, e.g. the ionic thermal conductivity, Raman/IR vibrational spectra, inelastic X-ray, and Neutron scattering. A theory able to compute from first…

Statistical Mechanics · Physics 2021-03-31 Lorenzo Monacelli , Francesco Mauri

The self-consisted harmonic approximation (SCHA) allows the computation of free energy of anharmonic crystals considering both quantum and thermal fluctuations. Recently, a stochastic implementation of the SCHA has been developed, tailored…

Materials Science · Physics 2018-08-01 Lorenzo Monacelli , Ion Errea , Matteo Calandra , Francesco Mauri

The Self-Consistent Harmonic Approximation (SCHA) has been utilized to investigate quantum and thermal phase transitions within magnetic models and, more recently, in spintronic applications. The SCHA methodology involves utilizing simple…

Strongly Correlated Electrons · Physics 2026-03-25 G. C. Villela , A. R. Moura

The efficient and accurate calculation of how ionic quantum and thermal fluctuations impact the free energy of a crystal, its atomic structure, and phonon spectrum is one of the main challenges of solid state physics, especially when strong…

We consider the thermal softening of crystals due to anharmonicity. Self-consistent methods find a maximum temperature for a stable crystal, which gives an upper bound to the melting temperature. Previous workers have shown that the…

Statistical Mechanics · Physics 2007-05-23 M. J. W. Dodgson , V. B. Geshkenbein , M. V. Feigel'man , G. Blatter

We study the two-dimensional Bose-Hubbard model with anisotropic hopping. Focusing on the effects of anisotropy on the superfluid properties such like the helicity modulus and the normal-to-superfluid (Berezinskii-Kosterlitz-Thouless, BKT)…

Quantum Gases · Physics 2014-12-02 Jhih-Shih You , Hao Lee , Shiang Fang , Miguel A. Cazalilla , Daw-Wei Wang

Harmonic calculations based on density-functional theory are generally the method of choice for the description of phonon spectra of metals and insulators. The inclusion of anharmonic effects is, however, delicate as it relies on…

Materials Science · Physics 2015-06-17 Ion Errea , Matteo Calandra , Francesco Mauri

The self-consistent harmonic approximation is an effective harmonic theory to calculate the free energy of systems with strongly anharmonic atomic vibrations, and its stochastic implementation has proved to be an efficient method to study,…

Materials Science · Physics 2017-07-26 Raffaello Bianco , Ion Errea , Lorenzo Paulatto , Matteo Calandra , Francesco Mauri

The self-energy functional theory (SFT) is generalized to describe the real-time dynamics of correlated lattice-fermion models far from thermal equilibrium. This is achieved by means of a reformulation of the original equilibrium theory in…

Strongly Correlated Electrons · Physics 2013-10-21 Felix Hofmann , Martin Eckstein , Enrico Arrigoni , Michael Potthoff

In the paper we describe the modification of self-consistent harmonic approximation for quantum S=1 systems. This method has a number of advantages in comparison with usual SCHA. We apply the method to two-dimensional ferromagnets with…

Strongly Correlated Electrons · Physics 2007-05-23 D. V. Spirin

Quantum nuclear effects and anharmonicity impact a wide range of functional materials and their properties. One of the most powerful techniques to model these effects is the Stochastic Self-Consistent Harmonic Approximation (SSCHA).…

Superconductivity · Physics 2025-01-22 Francesco Belli , Eva Zurek

We consider quantum nonlinear many-body systems with dissipation described within the Caldeira-Leggett model, i.e., by a nonlocal action in the path integral for the density matrix. Approximate classical-like formulas for thermodynamic…

Statistical Mechanics · Physics 2009-10-31 A. Cuccoli , A. Fubini , V. Tognetti , R. Vaia

A linearized Vlasov-Poisson system of equations is transformed into a Schr\"{o}dinger equation, which is used to demonstrate that the fluctuation theorem holds for the relative stochastic entropy, defined in terms of the probability density…

Plasma Physics · Physics 2025-08-11 Hideo Sugama

We discuss differences in simulation results that arise between the use of either the thermal energy or the entropy as an independent variable in smoothed particle hydrodynamics (SPH). In this context, we derive a new version of SPH that…

Astrophysics · Physics 2009-11-07 Volker Springel , Lars Hernquist

The noncrossing approximation (NCA) is generalized to the multi-channel Kondo-spin Hamiltonian with arbitrary anisotropic exchange couplings and an external magnetic field, and applied -- in the framework of Matveev's mapping -- to the…

Strongly Correlated Electrons · Physics 2009-11-07 Eran Lebanon , Avraham Schiller , Vilen Zevin

A new method of approximation scheme with potential application to a general interacting quantum system is presented. The method is non-perturbative, self- consistent, systematically improvable and uniformly applicable for arbitrary…

Quantum Physics · Physics 2008-06-13 Nabaghan Santi

We introduce a non perturbative general approximation scheme (NGAS) that can handle interactions of any strength in quantum theory. This approach starts with an input Hamiltonian that can be solved exactly. The interaction effects are then…

Quantum Physics · Physics 2025-10-09 B. P. Mahapatra

The self-consistent Gaussian approximation (SCGA) for classical spin systems described by a completely anisotropic D-component vector model is proposed, which takes into account fluctuations of the molecular field and thus is a next step…

Statistical Mechanics · Physics 2009-10-31 D. A. Garanin

We define correlational (von Neumann) entropy for an individual quantum state of a system whose time-independent hamiltonian contains random parameters and is treated as a member of a statistical ensemble. This entropy is representation…

chao-dyn · Physics 2013-01-16 Valentin V. Sokolov , B. Alex Brown , Vladimir Zelevinsky
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