English
Related papers

Related papers: Factorized Quadruples and a Predictor of Higher-Le…

200 papers

Molecular fragment or embedding methods are powerful techniques for overcoming scalability limitations in electronic structure theory by dividing large molecular systems into individual units that are small enough to be treated using…

Chemical Physics · Physics 2017-08-14 Jason N. Byrd , Robert W. Molt, , Rodney J. Bartlett , Beverly A. Sanders

A system of patchy colloidal particles interacting with a solute that can associate multiple times in any direction is a useful model for patchy colloidal mixtures. Despite the simplicity of the interaction, because of the presence of…

Soft Condensed Matter · Physics 2016-01-19 Artee Bansal , D. Asthagiri , K. R. Cox , Walter G. Chapman

We present several coupled-cluster calculations of ground and excited states of 4He and 16O employing methods from quantum chemistry. A comparison of coupled cluster results with the results of exact diagonalization of the hamiltonian in…

It remains a prime question of how to describe the optical properties of large molecular clusters accurately. Quantum chemical methods capture essential electronic details but are infeasible for entire clusters, while optical simulations…

Precision tests of QCD perturbation theory are not readily available from experimental data. The main reasons are systematic uncertainties due to the confinement of quarks and gluons, as well as kinematical constraints which limit the…

High Energy Physics - Lattice · Physics 2017-04-05 Stefan Sint

In this paper, we reanalyze the top-quark pair production at the next-to-next-to-leading order (NNLO) in QCD at future $e^+e^-$ colliders by using the Principle of Maximum Conformality (PMC) method. The PMC renormalization scales in…

High Energy Physics - Phenomenology · Physics 2024-02-06 Jin Ma , Sheng-Quan Wang , Ting Sun , Jian-Ming Shen , Xing-Gang Wu

We investigate the optimization of flexible tailored real-space Jastrow factors for use in the transcorrelated (TC) method in combination with highly accurate quantum chemistry methods such as initiator full configuration interaction…

Quantum chemistry simulations offer a cost-effective way for computational design of BODIPY photosensitizers with potential use in photodynamic therapy (PDT). However, accurate predictions of photophysical properties, such as excitation…

Reliable theoretical predictions of noncovalent interaction energies, which are important e.g. in drug-design and hydrogen-storage applications, belong to longstanding challenges of contemporary quantum chemistry. In this respect, the…

Chemical Physics · Physics 2016-06-06 Matúš Dubecký , René Derian , Petr Jurečka , Lubos Mitas , Pavel Hobza , Michal Otyepka

We construct predictions for top quark pair differential distributions at hadron colliders that combine state-of-the-art NNLO QCD calculations with double resummation at NNLL' accuracy of threshold logarithms arising from soft gluon…

High Energy Physics - Phenomenology · Physics 2018-06-07 Michal Czakon , Andrea Ferroglia , David Heymes , Alexander Mitov , Ben D. Pecjak , Darren J. Scott , Xing Wang , Li Lin Yang

The quantum Drude oscillator (QDO) is an efficient yet accurate coarse-grained approach that has been widely used to model electronic and optical response properties of atoms and molecules, as well as polarization and dispersion…

Exascale computing could soon enable a predictive theory of nuclear structure and reactions rooted in the Standard Model, with quantifiable and systematically improvable uncertainties. Such a predictive theory will help exploit experiments…

In the last decade, the quantum chemical version of the density matrix renormalization group (DMRG) method has established itself as the method of choice for calculations of strongly correlated molecular systems. Despite its favourable…

Chemical Physics · Physics 2016-11-15 Libor Veis , Andrej Antalík , Jiří Brabec , Frank Neese , Örs Legeza , Jiří Pittner

We introduce a multimodel approach to solve coupled cluster equations, employing a quasi Newton algorithm for the ground state and an Olsen algorithm for the excited states. In these algorithms, both of which can be viewed as Newton…

Chemical Physics · Physics 2020-07-15 Eirik F. Kjønstad , Sarai D. Folkestad , Henrik Koch

In this paper, the twist-3 two parton corrections in charmless $B\to PP$ decays are shown to be factorizable under the QCD factorization approach. The factorizability of the twist-3 two parton corrections is constructed on the following…

High Energy Physics - Phenomenology · Physics 2008-03-06 Tsung-Wen Yeh

A novel approach to rapidly converging high-level coupled-cluster (CC) energetics in an automated fashion is proposed. The key idea is an adaptive selection of the excitation manifolds defining higher-than-two-body components of the cluster…

Chemical Physics · Physics 2023-08-25 Karthik Gururangan , Piotr Piecuch

For noncovalent interactions (NCIs), the CCSD(T) coupled cluster method is widely regarded as the `gold standard'. With localized orbital approximations, benchmarks for ever larger NCI complexes are being published; yet tantalizing evidence…

Chemical Physics · Physics 2025-03-13 Vladimir Fishman , Michał Lesiuk , Jan M. L. Martin , A. Daniel Boese

A new perturbative approach to canonical equation-of-motion coupled-cluster theory is presented using coupled-cluster perturbation theory. A second-order M{\o}ller-Plesset partitioning of the Hamiltonian is used to obtain the well known…

Chemical Physics · Physics 2015-07-09 Jason N. Byrd , Varun Rishi , Ajith Perera , Rodney J. Bartlett

We review applicability of QCD factorization theorem to multiple scattering in deeply inelastic lepton-nucleus scattering. We show why A^{1/3}-type nuclear enhancement can be calculated consistently in perturbative QCD. We derive the…

High Energy Physics - Phenomenology · Physics 2009-10-31 Xiaofeng Guo , Jianwei Qiu

We report on the first results for the second-order perturbation theory correction to the ground-state energy of a nuclear many-body system in a continuum quantum Monte Carlo calculation. Second-order (and higher) perturbative corrections…

Nuclear Theory · Physics 2023-11-10 Ryan Curry , Joel E. Lynn , Kevin E. Schmidt , Alexandros Gezerlis