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The 8 eV first nuclear excited state in $^{229}$Th is a candidate for implementing an nuclear clock. Doping $^{229}$Th into ionic crystals such as CaF$_2$ is expected to suppress non-radiative decay, enabling nuclear spectroscopy and the…

Motivated by recent experimental breakthroughs toward a realization of a solid-state Thorium-229 nuclear clock, we review the technology, basic physics motivation, and limitations of the present generation of atomic clocks. We then discuss…

Atomic Physics · Physics 2025-11-18 Steven M. Girvin , Leo Radzihovsky

The 7.8 eV nuclear isomer transition in 229 Thorium has been suggested as an etalon transition in a new type of optical frequency standard. Here we discuss the construction of a "solid-state nuclear clock" from Thorium nuclei implanted into…

We have grown $^{232}$Th:CaF$_2$ and $^{229}$Th:CaF$_2$ single crystals for investigations on the VUV laser-accessible first nuclear excited state of $^{229}$Th. To reach high doping concentrations despite the extreme scarcity (and…

Thorium-229, with its exceptionally low-energy nuclear excited state, is a key candidate for developing nuclear clocks. $^{229}$Th-doped CaF$_2$ crystals, benefiting from calcium fluoride's wide band gap, show great promise as solid-state…

Solid-state $^{229}$Th nuclear clocks are set to provide new opportunities for precision metrology and fundamental physics. Taking advantage of a nuclear transition's inherent low sensitivity to its environment, orders of magnitude more…

After nearly fifty years of searching, the vacuum ultraviolet $^{229}$Th nuclear isomeric transition has recently been directly laser excited [1,2] and measured with high spectroscopic precision [3]. Nuclear clocks based on this transition…

Thorium-doped LiCaAlF$_6$ and LiSrAlF$_6$ (Th:LiCAF and Th:LiSAF) are promising crystals for a solid-state nuclear clock based on the 8 eV transition in $^{229}$Th; however, their complex crystal structures complicate understanding the…

Materials Science · Physics 2026-01-13 Martin Pimon , Tobias Kirschbaum , Thorsten Schumm , Adriana Pálffy , Andreas Grüneis

We study thorium-doped CaF$_2$ crystals as a possible platform for optical spectroscopy of the Th-229 nuclear isomer transition. We anticipate two major sources of background signal that might cover the nuclear spectroscopy signal:…

Instrumentation and Detectors · Physics 2016-01-05 Simon Stellmer , Matthias Schreitl , Thorsten Schumm

Solid-state $^{229}$Th nuclear clocks require a host material whose band gap is larger than the 8.4 eV nuclear transition energy. As such, excitation of the $^{229}$Th nuclear state has so far only been demonstrated in metal fluorides,…

We report the scintillation and timing performance of a new developed 200 * 20 mm * 20 mm large size barium fluoride crystal doped with 3at% yttrium (BaF2:Y) to enhance the application for high time resolution. This doping effectively…

Instrumentation and Detectors · Physics 2025-02-24 Zeyu Huang , Jing Zhang , Shiming Zou , Mingkuan Yuan , Jiawei Xu , Xiyang Wang , Shiqing Xie , Jinhui Chen , Junfeng Chen , Xiaolong Wang

Building on recent advances of the embedded cluster approach combined with multiconfigurational theory, this work investigates the electronic states in thorium-doped CaF2 crystals. Th:CaF2 is currently establishing as a promising material…

Materials Science · Physics 2024-10-15 Kamil Nalikowski , Valera Veryazov , Kjeld Beeks , Thorsten Schumm , Marek Krosnicki

We demonstrate a scheme for optical cycling in the polar, diatomic molecule strontium monofluoride (SrF) using the $X ^2\Sigma^+\toA^2\Pi_{1/2}$ electronic transition. SrF's highly diagonal Franck-Condon factors suppress vibrational…

Atomic Physics · Physics 2015-05-14 E. S. Shuman , J. F. Barry , D. R. Glenn , D. DeMille

In this paper results of scintillation properties measurements of pure and Ce3+-doped strontium fluoride crystals are presented. We measure light output, scintillation decay time profile and temperature stability of light output. X-ray…

Materials Science · Physics 2016-06-07 R. Shendrik , E. A. Radzhabov , A. I. Nepomnyashchikh

Results of absolute light output measurements on strontium and barium fluoride doped with PrF$_3$ and CeF$_3$ are presented and compared with scintillators having well-known light output (NaI-Tl, CsI-Tl, BGO). For pure SrF$_2$ crystal we…

Materials Science · Physics 2015-06-11 Roman Shendrik , Evgeny Radzhabov

We have recently described a novel method for the construction of a solid-state optical frequency reference based on doping $^{229}$Th into high energy band-gap crystals. Since nuclear transitions are far less sensitive to environmental…

We report the first demonstration of solid-state optical refrigeration of a Ho-doped material. A 1 mol% Ho-doped Yttrium Lithium Fluoride (YLF) crystal is cooled by mid-IR laser radiation, and its external quantum efficiency and parasitic…

Quantum state-resolved spectroscopy of the low energy thorium-229 nuclear transition was recently achieved. The five allowed transitions within the electric quadrupole structure were measured to the kilohertz level in a calcium fluoride…

The nucleus of 229Thorium presents a unique isomer state of very low energy and long lifetime, current estimates are around 7.8 eV and seconds to hours respectively. This nuclear transitions therefore is a promising candidate for a novel…

Atomic Physics · Physics 2013-04-18 G. A. Kazakov , M. Schreitl , G. Winkler , J. H. Sterba , G. Steinhauser , T. Schumm

We report the thermoelectric properties (Seebeck coefficient, thermal conductivity, and electrical resistivity) of lightly doped single crystals of (001)-oriented SrTiO3 (STO). Hall effect measurements show that electron doping around 10^-5…

Strongly Correlated Electrons · Physics 2012-11-08 P. L. Bach , V. Leborán , V. Pardo , A. S. Botana , D. Baldomir , F. Rivadulla
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