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In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

Quantum Physics · Physics 2017-06-28 Thibaut Josset

The problem of estimating entropy production from incomplete information in stochastic thermodynamics is essential for theory and experiments. Whereas a considerable amount of work has been done on this topic, arguably, most of it is…

Statistical Mechanics · Physics 2024-12-17 Pedro E. Harunari , Carlos E. Fiore , Andre C. Barato

We derive a generalization of Ehrenfest theorem valid for open quantum systems. From this result, we identify three contributions to the evolution of expected values: i) the explicit time dependence of the observable, ii) the…

Quantum Physics · Physics 2025-02-27 Andrés Vallejo , Alejandro Romanelli , Virginia Feldman , Raúl Donangelo

Meixner's historical remark in 1969 "... it can be shown that the concept of entropy in the absence of equilibrium is in fact not only questionable but that it cannot even be defined...." is investigated from today's insight. Several…

Statistical Mechanics · Physics 2018-10-17 Wolfgang Muschik

Thermodynamics have been applied to astronomy, biology, psychology, some social systems and so on. But, various evolutions from astronomy to biology and social systems cannot be only increase of entropy. When fluctuations are magnified due…

General Physics · Physics 2009-10-06 Yi-Fang Chang

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

Quantum Physics · Physics 2009-11-13 Qi-Ren Zhang

Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…

Statistical Mechanics · Physics 2020-11-17 Stefan Floerchinger , Tobias Haas

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

Non-extensive systems do not allow to go to the thermodynamic limit. Therefore we have to reformulate statistical mechanics without invoking the thermodynamical limit. I.e. we have to go back to Pre-Gibbsian times. We show that Boltzmann's…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos

The foundations of the Boltzmann-Gibbs (BG) distributions for describing equilibrium statistical mechanics of systems are examined. Broadly, they fall into: (i) probabilistic paaroaches based on the principle of equal a priori probability…

Statistical Mechanics · Physics 2009-11-10 A. K. Rajagopal , Sumiyoshi Abe

In economics, construction of perfect models in a way that would be comparable to the standards customary in physical sciences is generally not feasible. In particular, the observed value for an economic equilibrium may deviate…

Probability · Mathematics 2026-01-05 Esa Nummelin , Elja Arjas

The present work deals with three alternative generalized Bekenstein-Hawking formulation of thermodynamical parameters namely entropy and temperature for the universal thermodynamical system bounded by a horizon in the frame work of…

General Physics · Physics 2017-02-21 Subhajit Saha , Subenoy Chakraborty

Born's rule is the recipe for calculating probabilities from quantum mechanical amplitudes. There is no generally accepted derivation of Born's rule from first principles. In this paper, it is motivated from assumptions that link the…

Quantum Physics · Physics 2024-11-05 Per Östborn

It is known that in thermal systems of finite size that are subject to second order phase transitions and until the spontaneous symmetry breaking is completed, the fluctuations of the order parameter obey to the dynamics of critical…

Statistical Mechanics · Physics 2023-05-09 Y. Contoyiannis , P. Papadopoulos , L. Matiadou , S. G. Stavrinides , M. Hanias , S. M. Potirakis

A plethora of natural, artificial and social systems exist which do not belong to the Boltzmann-Gibbs (BG) statistical-mechanical world, based on the standard additive entropy $S_{BG}$ and its associated exponential BG factor. Frequent…

Statistical Mechanics · Physics 2016-06-29 Constantino Tsallis

In earlier work we presented a foundation for the Second Law of Classical Thermodynamics in terms of the Entropy Principle. More precisely, we provided an empirically accessible axiomatic derivation of an entropy function defined on all…

Mathematical Physics · Physics 2015-06-16 Elliott H. Lieb , Jakob Yngvason

The dynamics of molecular collisions in a macroscopic body are encoded by the parameter Thermodynamic entropy - a statistical measure of the number of molecular configurations that correspond to a given macrostate. Directionality in the…

Populations and Evolution · Quantitative Biology 2020-05-22 Lloyd Demetrius , Christian Wolf

We present a new outlook on the climate system thermodynamics, studying some of its macroscopic properties in terms of the 1st and 2nd laws of thermodynamics. We review and clarify the notion of efficiency of the climate system by…

Atmospheric and Oceanic Physics · Physics 2011-10-11 Valerio Lucarini

I explore the possibility that the laws of physics might be laws of inference rather than laws of nature. What sort of dynamics can one derive from well-established rules of inference? Specifically, I ask: Given relevant information…

General Relativity and Quantum Cosmology · Physics 2009-11-07 Ariel Caticha
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