English
Related papers

Related papers: Numerical Analysis of the Complete Active-Space Ex…

200 papers

We present an implementation of equation of motion coupled-cluster singles and doubles (EOM-CCSD) theory using periodic boundary conditions and a plane wave basis set. Our implementation of EOM-CCSD theory is applied to study $F$-centers in…

Materials Science · Physics 2021-02-09 Alejandro Gallo , Felix Hummel , Andreas Irmler , Andreas Grüneis

The congruent transformation of the electronic Hamiltonian is developed to address the electron correlation problem in many-electron systems. The central strategy presented in this method is to perform transformation on the electronic…

Chemical Physics · Physics 2012-12-21 Jennifer M. Elward , Johannes Hoja , Arindam Chakraborty

We theoretically show that the initial coherence plays a crucial role in enhancing the speed of excitation energy transfer (EET) in Fenna-Matthews-Olson (FMO) complex. We choose a simplistic eight-level model considering all the…

Biological Physics · Physics 2017-09-25 Davinder Singh , Shubhrangshu Dasgupta

Studies of cold atom collisions and few-body interactions often require the energy dependence of the scattering phase shift, which is usually expressed in terms of an effective-range expansion. We use accurate coupled-channel calculations…

Quantum Gases · Physics 2014-04-25 Caroline L. Blackley , Paul S. Julienne , Jeremy M. Hutson

A new state of matter, an excitonic insulator (EI) state, was predicted to emerge from Bose-Einstein condensation of electron-hole pairs. Some candidate materials were suggested but it has been elusive to confirm its existence. Recent works…

Strongly Correlated Electrons · Physics 2021-05-12 Jin Mo Bok , Jungseek Hwang , Han-Yong Choi

An in-principle exact working equation to compute electronic affinity and ionization Fukui functions is derived within the $N$-centered (Nc) ensemble extension of density functional theory (DFT). It circumvents the kernel derivative…

Chemical Physics · Physics 2026-02-12 Lucien Dupuy , Emmanuel Fromager

This paper derives and demonstrates a new, purely density-based ab initio approach for calculation of the energies and properties of many-electron systems. It is based upon the discovery of relationships that govern the "mechanics" of the…

Chemical Physics · Physics 2024-09-04 James C. Ellenbogen

Ground-state electronic structure calculations using Kohn-Sham density functional theory (KS-DFT) offer an unprecedented balance between efficiency and accuracy, now paradigmatic to the fields of quantum chemistry and condensed matter…

Chemical Physics · Physics 2026-04-14 Lucien Dupuy , Toni Chiti , Jérémy Morere , Emmanuel Fromager

This article solves two major tasks that frequently arise in the theory of electron collisions with a target molecular cation. First, it extends the energy-dependent frame transformation treatment(EDFT), which is needed to map fixed-nuclei…

Chemical Physics · Physics 2025-11-25 David Hvizdos , Roman Curik , Chris H Greene

To examine the applicability of the time-dependent density-functional theory (TDDFT) for treating the electron-nucleus coupling in excited states, we calculate the strength distribution associated with the pi-pi* transition in ethylene. The…

Chemical Physics · Physics 2007-05-23 G. F. Bertsch , J. Giansiracusa , K. Yabana

Accepting that there is a mass gap above the electroweak scale, the Electroweak Effective Theory (EWET) is an appropriate tool to describe this situation. Since the EWET couplings contain information on the unknown high-energy dynamics, we…

High Energy Physics - Phenomenology · Physics 2017-04-05 Ignasi Rosell , Antonio Pich , Joaquin Santos , Juan Jose Sanz-Cillero

Since in coupled-cluster (CC) theory ground-state and excitation energies are eigenvalues of a non-Hermitian matrix, these energies can in principle take on complex values. In this paper we discuss the appearance of complex energy values in…

Chemical Physics · Physics 2022-01-12 Simon Thomas , Florian Hampe , Stella Stopkowicz , Jürgen Gauss

We study the energy distribution in the extended resonant level model at equilibrium. Previous investigations [Phys. Rev. B {\bf 89}, 161306 (2014), Phys. Rev. B {\bf 93}, 115318 (2016)] have found, for a resonant electronic level…

Mesoscale and Nanoscale Physics · Physics 2016-07-26 Maicol A. Ochoa , Anton Bruch , Abraham Nitzan

We derive analytical expressions for the correlation functions of the electronic conductance fluctuations of an open quantum dot under several conditions. Both the variation of energy and that of an external parameter such as an applied…

Mesoscale and Nanoscale Physics · Physics 2017-03-22 J. G. G. S. Ramos , A. L. R. Barbosa , B. V. Carlson , T. Frederico , M. S. Hussein

We perform total energy calculations based on the tight-binding Hamiltonian scheme (i) to study the structural properties and energetics of the extended {311} defects depending upon their dimensions and interstitial concentrations and (ii)…

Materials Science · Physics 2009-10-28 Jeongnim Kim , John W. Wilkins , Furrukh S. Khan , Andrew Canning

In this paper we analyze how radiation effects influence the correlation functions, the excess energy, and in turn the electron correlation energy of the quantized electron gas at temperature $T=0$. To that aim we resort to a statistical…

Statistical Mechanics · Physics 2020-08-26 Johan S. Høye , Enrique Lomba

We propose an efficient deterministic method to calculate the full configuration interaction (FCI) ground state energy. This method leverages the sparseness of the Lanczos basis vectors that span the Krylov subspace associated with the…

Chemical Physics · Physics 2024-01-08 Lijun Wang

An extended bosonic coherent basis has been shown by Chen to provide numerically exact solutions of the finite-size Dicke model. The advantages in employing this basis, as compared with the photon number (Fock) basis, are exhibited to be…

Quantum Physics · Physics 2015-06-18 Miguel Angel Bastarrachea-Magnani , Jorge G. Hirsch

We derive the ground-state energy for a small number of ultracold atoms in an isotropic harmonic trap using effective quantum field theory (EFT). Atoms are assumed to interact through pairwise energy-independent and energy-dependent…

Quantum Gases · Physics 2014-10-29 X. Y. Yin , D. Blume , P. R. Johnson , E. Tiesinga

Energy-energy correlators (EECs) provide a sensitive probe of both perturbative and nonperturbative dynamics in relativistic heavy-ion collisions. Jet-medium interactions enhance particle multiplicity within the jet cone, which must be…

Nuclear Theory · Physics 2026-05-12 Rushil Saraswat , Aditya Prasad Dash , Huan Zhong Huang , Gang Wang , Xin-Nian Wang , Zhong Yang