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This work develops and illustrates a new method of calculating "chemically accurate" electronic wavefunctions (and energies) via a truncated full configuration interaction (CI) procedure which arguably circumvents the large matrix…

Chemical Physics · Physics 2022-12-21 Stephen J. Cotton

A new state specific correlation correction to configuration interaction singles (CIS) excitation energies is preseted using coupled cluster perturbation theory (CCPT). General expressions for CIS-CCPT are derived and expanded explicitly to…

Chemical Physics · Physics 2015-06-19 Jason N. Byrd , Victor F. Lotrich , Rodney J. Bartlett

In this paper, we study a suitable experimental design of electrochemical impedance spectroscopy (EIS) to reduce the number of frequency points while not significantly affecting the uncertainties of the estimated cell's equivalent circuit…

Systems and Control · Electrical Eng. & Systems 2025-01-13 Vladimir Sovljanski , Mario Paolone , Sylvain Tant , Damien Pierre Sainflou

Atomistic electronic structure calculations are performed to study the coherent inter-dot couplings of the electronic states in a single InGaAs quantum dot molecule. The experimentally observed excitonic spectrum [12] is quantitatively…

Mesoscale and Nanoscale Physics · Physics 2013-08-01 Muhammad Usman , Yui-Hong Matthias Tan , Hoon Ryu , Shaikh S. Ahmed , Hubert Krenner , Timothy B. Boykin , Gerhard Klimeck

Some typical overlap/potential energy integrals which occur in the use of extended Hylleraas-configuration interaction (E-Hy-CI) functions with Slater-type orbital (STO) basis for two-electron atomic structure calculations, have been…

Atomic Physics · Physics 2019-01-23 B Padhy

The electromagnetically induced transparency (EIT) phenomenon in earlier universe is considered. We evaluated the elementary processes of the single scattering of photon on the hydrogen atom with the purpose of their use in the tasks of the…

Atomic Physics · Physics 2022-02-10 D. Solovyev , V. K. Dubrovich

A strict bidimensional (strict-2D) exact-exchange (EE) formalism within the framework of density-functional theory (DFT) has been developed and applied to the case of an electron gas subjected to a strong perpendicular magnetic field, that…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 D. Miravet , C. R. Proetto

We numerically study models of $\mathrm{H}_2$ and $\mathrm{LiH}$ molecules, aligned collinearly with the linear polarization of the external field, to elucidate the possible role of correlation in the enhanced-ionization phenomena.…

Atomic Physics · Physics 2016-01-06 S. Chattopadhyay , S. Bauch , L. B. Madsen

Using large-scale, real-time quantum dynamics calculations, we present a detailed analysis of electronic excitation transfer (EET) mechanisms in a multi-particle plasmonic nanoantenna system. Specifically, we utilize real-time,…

Mesoscale and Nanoscale Physics · Physics 2018-03-06 Niranjan V. Ilawe , M. Belén Oviedo , Bryan M. Wong

The future electron-ion collider (EIC) will produce the first-ever high energy collisions between electrons and a wide range of nuclei, opening a new era in the study of cold nuclear matter. Quarks and gluons produced in these collisions…

High Energy Physics - Phenomenology · Physics 2025-10-03 Kyle Devereaux , Wenqing Fan , Weiyao Ke , Kyle Lee , Ian Moult

We systematically develop the full quantum theory for the electromagnetic induced transparency (EIT) and slow light properties in ultracold Bose and Fermi gases. It shows a very different property from the classical theory which assumes…

Quantum Gases · Physics 2015-06-05 H. H. Jen , Bo Xiong , Ite A. Yu , Daw-Wei Wang

We propose a general approach to reducing basis set incompleteness error in electron correlation energy calculations. The correction is computed alongside the correlation energy in a single calculation by modifying the electron interaction…

In this short paper, the validity of Koopmans' theorem in the Hartree-Fock theory at non-zero temperature (Hartree-Fock statistical theory) is investigated. It is shown that Koopmans' theorem does not apply in the grand-canonical ensemble,…

Atomic Physics · Physics 2015-05-28 Jean-Christophe Pain

Extensions of the eikonal approximation to low energy (20MeV/nucleon typically) are studied. The relation between the dynamical eikonal approximation (DEA) and the continuum-discretized coupled-channels method with the eikonal approximation…

Nuclear Theory · Physics 2014-09-25 Tokuro Fukui , Kazuyuki Ogata , Pierre Capel

The treatment of atomic anions with Kohn-Sham density functional theory (DFT) has long been controversial since the highest occupied molecular orbital (HOMO) energy, $E_{HOMO}$, is often calculated to be positive with most approximate…

Chemical Physics · Physics 2019-03-20 Lindsey N. Anderson , M. Belén Oviedo , Bryan M. Wong

We report a detailed investigation on the properties of correlation spectra for cold atoms under the condition of Electromagnetically Induced Transparency (EIT). We describe the transition in the system from correlation to anti-correlation…

An eikonal expansion is used to provide systematic corrections to the eikonal approximation through order $1/k^2$, where $k$ is the wave number. Electron wave functions are obtained for the Dirac equation with a Coulomb potential. They are…

Nuclear Theory · Physics 2015-05-13 J. A. Tjon , S. J. Wallace

Perhaps the simplest first-principles approach to electronic structure is to fit the charge distribution of each orbital pair and use those fits wherever they appear in the entire electron-electron (EE) interaction energy. The charge…

Chemical Physics · Physics 2015-11-10 Brett I Dunlap , Mark C Palenik

Application of the convergent close-coupling (CCC) method to electron-impact ionization of the ground state of atomic hydrogen is considered at incident energies of 15.6, 17.6, 20, 25, 27.2, 30, 54.4, 150 and 250 eV. Total through to fully…

Atomic Physics · Physics 2015-06-26 Igor Bray

We use Kohn-Sham spin-density-functional theory to study the statistics of ground-state spin and the spacing between conductance peaks in the Coulomb blockade regime for both 2D isolated and realistic quantum dots. We make a systematic…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Hong Jiang , Denis Ullmo , Weitao Yang , Harold U. Baranger