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Sub-nanometer aqueous clusters containing a single trivalent metal cation can exhibit charge-induced structural instabilities. Here, we present computational evidence that clusters containing a single \ce{Fe^{3+}}, \ce{Lu^{3+}}, or…

Soft Condensed Matter · Physics 2025-07-15 Jihong Shi , Han Nguyen , Mateo Pescador Arboleda , Styliani Consta

We report on the non-trivial nanoscale kinetics of the deposition of novel complex oxide heterostructures composed of a unit-cell thick correlated metal LaNiO3 and dielectric LaAlO3. The multilayers demonstrate exceptionally good…

Strongly Correlated Electrons · Physics 2015-05-18 M. Kareev , S. Prosandeev , Jian Liu , B. Gray , P. Ryan , A. Kareev , Eun Ju Moon , J. Chakhalian

This study investigates the interfacial tension, fluid mobility, and crystallization behavior of various saline and additive-modified solutions in a microfluidic chip environment, simulating pore-scale processes during CO2 injection. The…

We use molecular dynamics simulations to probe hydration, ion spacing, and cation-anion interaction in two sulfonated polysulfones with different ion distributions along the polymer backbone. At room temperature, these polymers remain in a…

Soft Condensed Matter · Physics 2021-01-15 Britannia Vondrasek , Chengyuan Wen , Shengfeng Cheng , Judy S. Riffle , John J. Lesko

The relative importance of atomic defects and electron transfer in explaining conductivity at the crystalline LaAlO3/SrTiO3 interface has been a topic of debate. Metallic interfaces with similar electronic properties produced by amorphous…

The organization of water molecules and ions between charged mineral surfaces determines the stability of colloidal suspensions and the strength of phase-separated particulate gels. In this article we assemble a density functional that…

Soft Condensed Matter · Physics 2024-05-15 Thomas Petersen

We initiate a holographic study of coupling-dependent heavy ion collisions by analysing for the first time the effects of leading-order, inverse coupling constant corrections. In the dual description, this amounts to colliding gravitational…

High Energy Physics - Theory · Physics 2017-07-20 Sašo Grozdanov , Wilke van der Schee

The paper analyzes theoretically the influence of fullerenes on the characteristics of $\mathrm{Al/C}_{60}$ composites. The molecular dynamics method is used to study the dependences of density and stiffness constants on the concentration…

Mesoscale and Nanoscale Physics · Physics 2024-03-12 V. V. Reshetniak , A. V Aborkin , A. V. Filippov

Nanoscaling interstitial metal hydrides offers opportunities for hydrogenation applications by enhancing kinetics, increasing surface area, and allowing for tunable properties. The introduction of interfaces impacts hydrogen absorption…

Understand the nature of liquid structure and its evolution under different conditions is a major challenge in condensed physics and materials science. Here, we report a pressure-induced structure change spanning a wide pressure range in…

Materials Science · Physics 2025-01-28 X. Z. Yan , Y. M. Chen , Hua Y. Geng , Y. F. Wang , Y. Sun , L. L. Zhang , H. Wang , Y. L. Xu

We study ion condensation onto a patterned surface of alternating charges. The competition between self-energy and ion-surface interactions leads to the formation of ionic crystalline structures at low temperatures. We consider different…

Statistical Mechanics · Physics 2009-11-13 Yuri S. Velichko , Francisco J. Solis , Sharon M. Loverde , Monica Olvera de la Cruz

Molecular electronics is a fascinating area of research with the ability to tune device properties by a chemical tailoring of organic molecules. However, molecular electronics devices often suffer from dispersion and lack of reproducibility…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Nicolas Clement , David Guerin , Stephane Pleutin , Sylvie Godey , Dominique Vuillaume

MXene and its derivatives have attracted considerable attention for potential application in energy storage like batteries and supercapacitors owing to its ultrathin metallic structures. However, the complexity of the ionic and electronic…

Materials Science · Physics 2022-04-20 Qiye Guan , Hejin Yan , Yongqing Cai

Water scarcity is a dilemma facing much of the global population. Cation intercalation desalination (CID) cells, which use intercalation host compounds (IHCs) in combination with ion-exchange membranes (IEMs), could aid in addressing this…

Chemical Physics · Physics 2016-12-28 Kyle C. Smith

To form a conducting layer at the interface between the oxide insulators LaAlO3 and SrTiO3, the LaAlO3 layer on the SrTiO3 substrate must be at least four unit-cells-thick. The LaAlO3 SrTiO3 heterointerface thus formed exhibits various…

The unique structural properties of interfacial water are at the heart of a vast range of important processes in electrochemistry, climate science, and biophysics. At interfaces, water molecules exhibit preferential orientations and an…

Carbon dioxide hydrates are ice-like nonstoichiometric inclusion solid compounds with importance to global climate change, and gas transportation and storage. The thermodynamic and kinetic mechanisms that control carbon dioxide nucleation…

One of the most promising applications in nanoscience is the design of new materials to improve water permeability and selectivity of nanoporous membranes. Understanding the molecular architecture behind these fascinating structures and how…

Soft Condensed Matter · Physics 2021-09-10 João P. K. Abal , Rodrigo F. Dillenburg , Mateus H. Köhler , Marcia C. Barbosa

CaCO3 crystals' physical properties, such as polymorphism and hence the reflectivity and stability, are critical factors of their qualities in industrial applications. Factors such as additives and substrates that influence CaCO3…

Materials Science · Physics 2012-11-01 Taylor Evans

Biphasic interfaces are complex but fascinating regimes that display a number of properties distinct from those of the bulk. The CO$_2$-H$_2$O interface, in particular, has been the subject of a number of studies on account of its…

Materials Science · Physics 2025-02-13 Samuel G. H. Brookes , Venkat Kapil , Christoph Schran , Angelos Michaelides