Related papers: Cavity-modified electronic interactions in molecul…
We propose an optomechanical scheme for reaching quantum entanglement in vibration polaritons. The system involves $N$ molecules, whose vibrations can be fairly entangled with plasmonic cavities. We find that the vibration-photon…
Developing theoretical frameworks for vibrational strong coupling (VSC) beyond the single-mode approximation is crucial for a comprehensive understanding of experiments with planar Fabry-P\'erot cavities. Herein, a generalized cavity…
We propose a scheme involving a Cooper pair transistor (CPT) embedded in a superconducting microwave cavity, where the CPT serves as a charge tunable quantum inductor to facilitate ultra-strong coupling between photons in the cavity and a…
Collective strong coupling of molecular ensembles to optical cavities opens a route to modifying matter through genuinely collective electronic correlations. Yet even in the absence of a cavity, Coulomb correlations are notoriously…
We propose a theoretical scheme to generate nonreciprocal bipartite entanglement between a cavity mode and vibrational modes in a molecular cavity optomechanical system. Our system consists of $\mathcal{N}$ molecules placed inside a…
Dressing quantum states of matter with virtual photons can create exotic effects ranging from vacuum-field modified transport to polaritonic chemistry, and may drive strong squeezing or entanglement of light and matter modes. The…
Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify…
Nonadiabatic phenomena are investigated in the rovibrational motion of molecules confined in an infrared cavity. Conical intersections (CIs) between vibrational polaritons, similar to CIs between electronic polaritonic surfaces, are found.…
We develop a comprehensive theoretical model for the interaction strength between a pair of exciton-polaritons in microcavity devices. Ab initio numerical calculations for dipolar polaritons in one dimension are used as a starting point to…
The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…
We develop a quantum mechanical formalism to treat the strong coupling between an electromagnetic mode and a vibrational excitation of an ensemble of organic molecules. By employing a Bloch-Redfield-Wangsness approach, we show that the…
We consider an optomechanical cavity with a movable end-mirror as a quantum mechanical oscillator (MO) containing an interacting cigar-shaped Bose-Eisenstein condensate (BEC). It is assumed that both the MO and the BEC interact with the…
Optical resonators have shown outstanding abilities to tailor chemical landscapes through enhanced light-matter interaction between confined optical modes and molecule vibrations. We propose a theoretical model to study cooperative…
Cavity dressing of molecular vibrational dynamics expands the role of characteristic vibrations as spectroscopic markers of underlying ultrafast dynamics. Interacting vibrational modes exhibit a pronounced excited state delocalization due…
Cavity optomechanics aims to establish optical control over vibrations of mechanical systems, to heat, cool or to drive them toward coherent, or nonclassical states. This field was recently extended to include molecular optomechanics, which…
Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…
An exactly solvable model of a trapped interacting Bose-Einstein condensate (BEC) coupled in the dipole approximation to a quantized light mode in a cavity is presented. The model can be seen as a generalization of the harmonic-interaction…
Phonon polaritons (PPs) in van der Waals (vdW) materials can strongly enhance light-matter interactions at mid-infrared frequencies, owing to their extreme infrared field confinement and long lifetimes. PPs thus bear potential for achieving…
We consider theoretically the optomechanical interaction of several mechanical modes with a single quantized cavity field mode for linear and quadratic coupling. We focus specifically on situations where the optical dissipation is the…
Molecular polaritons, hybrid light-matter states resulting from strong cavity coupling of optical transitions, may provide a new route to guide chemical reactions. However, demonstrations of cavity-modified reactivity in clean benchmark…