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We have studied the extended Hubbard model in the atomic limit. The Hamiltonian analyzed consists of the effective on-site interaction U and the intersite density-density interactions Wij (both: nearest-neighbour and…

Strongly Correlated Electrons · Physics 2015-03-17 Konrad Kapcia , Stanisław Robaszkiewicz

The metal-insulator transition and unconventional metallic transport in vanadium dioxide (VO$_2$) are investigated with a combination of spectroscopic ellipsometry and reflectance measurements. The data indicates that electronic…

Strongly Correlated Electrons · Physics 2009-11-11 M. M. Qazilbash , K. S. Burch , D. Whisler , D. Shrekenhamer , B. G. Chae , H. T. Kim , D. N. Basov

We investigate the changes in the infrared response due to charge carriers introduced by electrostatic doping of the correlated insulator vanadium dioxide (VO2) integrated in the architecture of the field effect transistor. Accumulation of…

Strongly Correlated Electrons · Physics 2009-11-13 M. M. Qazilbash , Z. Q. Li , V. Podzorov , M. Brehm , F. Keilmann , B. G. Chae , H. T. Kim , D. N. Basov

We present and discuss results of a density functional theory (DFT) study of a perfect UO2 crystals and He atoms in octahedral interstitial positions. We have calculated basic bulk crystal properties and He incorporation energies into the…

Materials Science · Physics 2019-03-27 Denis Gryaznov , Eugene Heifets , Eugene Kotomin

Stochastic and mixed stochastic-deterministic density functional theory (DFT) are promising new approaches for the calculation of the equation-of-state and transport properties in materials under extreme conditions. In the intermediate warm…

Computational Physics · Physics 2023-09-27 Vidushi Sharma , Lee A. Collins , Alexander J. White

In the spirit of recently developed LDA+U and LDA+DMFT methods we implement a combination of density functional theory in its local density approximation (LDA) with a $k$- and $\omega -$dependent self-energy found from diagrammatic…

Strongly Correlated Electrons · Physics 2018-04-17 Sergey Y. Savrasov , Giacomo Resta , Xiangang Wan

Controlling electronic population through chemical doping is one way to tip the balance between competing phases in materials with strong electronic correlations. Vanadium dioxide exhibits a first-order phase transition at around 338 K…

While the phase diagrams of the one- and multi-orbital Hubbard model have been well studied, the physics of real Mott insulators is often much richer, material dependent, and poorly understood. In the prototype Mott insulator…

Strongly Correlated Electrons · Physics 2018-09-06 Frank Lechermann , Noam Bernstein , I. I. Mazin , Roser Valentí

We present a systematic density-functional theory study of the effects of strain on the structural and electronic properties in vanadium dioxide (VO$_2$), with particular emphasis on its effect on the relative stability of the metallic…

Materials Science · Physics 2025-10-14 Peter Mlkvik , Lena Geistlich , Nicola A. Spaldin , Claude Ederer

Vanadium dioxide undergoes a first order metal-insulator transition at 340 K. In this work, we develop and carry out state of the art linear scaling DFT calculations refined with non-local dynamical mean-field theory. We identify a complex…

Strongly Correlated Electrons · Physics 2012-07-11 Cedric Weber , David D. O'Regan , Nicholas D. M. Hine , Mike C. Payne , Gabriel Kotliar , Peter B. Littlewood

Transition metal oxides such as vanadium dioxide (VO$_2$), niobium dioxide (NbO$_2$), and titanium sesquioxide (Ti$_2$O$_3$) are known to undergo a temperature-dependent metal-insulator transition (MIT) in conjunction with a structural…

Accurate computational predictions of band gaps are of practical importance to the modeling and development of semiconductor technologies, such as (opto)electronic devices and photoelectrochemical cells. Among available electronic-structure…

Materials Science · Physics 2021-03-16 Nicole E. Kirchner-Hall , Wayne Zhao , Yihuang Xiong , Iurii Timrov , Ismaila Dabo

We investigated the magnetic and electric properties of nanometer-sized vanadium dioxide (VO$_2$) particles. VO$_2$ nanoparticles were formed by milling VO$_2$ powder. We measured the magnetic field dependence of the magnetization of the…

Materials Science · Physics 2024-04-05 Tsuyoshi Hatano , Akihiro Fukawa , Hiroki Yamamoto , Keiichirou Akiba , Kouichi Takase

Accurate modeling in the warm dense matter regime is a persistent challenge with the most detailed models such as quantum molecular dynamics and path integral Monte Carlo being immensely computationally expensive. Density functional theory…

Materials Science · Physics 2024-09-04 Sameen Yunus , David A. Strubbe

The band structure and electronic properties in a series of vinylene-linked heterocyclic conducting polymers are investigated using density functional theory (DFT). In order to accurately calculate electronic band gaps, we utilize hybrid…

Materials Science · Physics 2015-03-13 Bryan M. Wong , Joseph G. Cordaro

The widely-used Kohn-Sham implementation of density functional theory (DFT) maps a system of interacting electrons onto an auxiliary non-interacting one and is presumably inaccurate for strongly correlated materials. We present a concrete…

Strongly Correlated Electrons · Physics 2024-05-31 Jamin Kidd , Ruiqi Zhang , Shao-Kai Jian , Jianwei Sun

We present a detailed infrared study of the insulator-to-metal transition (IMT) in vanadium dioxide (VO2) thin films. Conventional infrared spectroscopy was employed to investigate the IMT in the far-field. Scanning near-field infrared…

Dynamical Mean-Field Theory (DMFT) has established itself as a reliable and well-controlled approximation to study correlation effects in bulk solids and also two-dimensional systems. In combination with standard density-functional theory…

Atomic and Molecular Clusters · Physics 2015-05-30 V. Turkowski , A. Kabir , N. Nayyar , Talat S. Rahman

A new implementation is proposed for including van der Waals (vdW) interactions in Density Functional Theory (DFT) using the Maximally-Localized Wannier functions (MLWFs), which is free from empirical parameters. With respect to the…

Chemical Physics · Physics 2019-05-22 Pier Luigi Silvestrelli , Alberto Ambrosetti

The optical properties of vanadium dioxide ($VO_2$) can be tuned via metal-insulator transition. In this work different types of one-dimensional photonic structure-based microcavities that embed vanadium dioxide have been studied in the…

Optics · Physics 2022-08-30 Francesco Scotognella