Related papers: Periodic phase-separation during meniscus-guided d…
Capillary suspensions are three-phase mixtures containing a solid particulate phase, a continuous liquid phase, and a second immiscible liquid forming capillary bridges between particles. Capillary suspensions are encountered in a wide…
The surface directed spinodal decomposition of a binary liquid confined inside cylindrical pore is investigated using molecular dynamics simulation. One component of the liquid wets the pore surface while the other remains neutral. A…
Liposomes that achieve a heterogeneous and spatially organized surface through phase separation have been recognized to be a promising platform for delivery purposes. However, their design and optimization through experimentation can be…
The phase-separation process of a binary mixture with order-parameter-dependent mobility under shear flow is numerically studied. The ordering is characterized by an alternate stretching and bursting of domains which produce oscillations in…
We investigate the domain growth and phase separation of hydrodynamically-correct binary immiscible fluids of differing viscosity as a function of minority phase concentration in both two and three spatial dimensions using dissipative…
Defects play a key role in deciding the mechanisms and kinetics of phase transformations. In this paper, we show how dislocations influence phase separation in alloys with miscibility gap. Specifically, depending on the ratio of pipe…
We use molecular dynamics (MD) to simulate an unstable homogeneous mixture of binary fluids (AB), confined in a slit pore of width $D$. The pore walls are assumed to be flat and structureless, and attract one component of the mixture (A)…
A thin water film evaporating from a cleaved mica substrate undergoes a first-order phase transition between two values of film thickness. During evaporation, the interface between the two phases develops a fingering instability similar to…
Evaporating suspensions of colloidal particles lead to the formation of a variety of patterns, ranging from a left-over ring of a dried coffee drop to uniformly distributed solid pigments left behind wet paint. To characterize the…
Spontaneous liquid-liquid phase separation is commonly understood in terms of phenomenological mean-field theories. These theories correctly predict the structural features of the fluid at sufficiently long time scales and wavelengths.…
Hypothesis: Immiscible liquids are commonly used to achieve unique functions in many applications, where the breakup of compound droplets in airflow is an important process. Due to the existence of the liquid-liquid interface, compound…
We present a phenomenological treatment of diffusion-driven martensitic phase transformations in multi-component crystalline solids that arise from non-convex free energies in mechanical and chemical variables. The treatment describes…
We examine the dynamics of two-dimensional colloidal systems using numerical simulations of a system with a drive applied to a thin region in the middle of the sample to produce a local shear. For a monodisperse colloidal assembly, we find…
When a binary fluid demixes under a slow temperature ramp, nucleation, coarsening and sedimentation of droplets lead to an oscillatory evolution of the phase separating system. The advection of the sedimenting droplets is found to be…
New insights into phase separation in colloidal suspensions are provided via a new dynamical theory based on the Polydisperse Lattice-Gas model. The model gives a simplified description of polydisperse colloids, incorporating a hard-core…
The evaporation of particle-laden droplets on engineered surfaces underpins a wide range of technologies, from printed electronics to biosensing. While the influence of substrate topography on passive particle deposition is well…
Drops in contact with swollen, elastomeric substrates can induce a capillary-mediated phase separation in wetting ridges. Using laser scanning confocal microscopy, we visualize phase separation of oligomeric silicone oil from a crosslinked…
In this thesis, we study the interplay of phase separation and wetting in multicomponent systems. For this purpose, we have examined the phase separation pattern of a binary mixture (AB) in presence of stationary spherical particles (C)…
Desorption of deposited species plays a role in determining the evolution of surface morphology during crystal growth when the desorption time constant is short compared to the time to diffuse to a defect site, step edge or kink. However,…
We study the phase equilibria of a fluid confined in an open capillary slit formed when a wall of finite length $H$ is brought a distance $L$ away from a second macroscopic surface. This system shows rich phase equilibria arising from the…