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Optical atomic clocks are the most accurate measurement devices ever constructed and have found many applications in fundamental science and technology. The use of highly charged ions (HCI) as a new class of references for highest accuracy…

Recent experimental progress in cooling, trapping, and quantum logic spectroscopy of highly-charged ions (HCIs) made HCIs accessible for high resolution spectroscopy and precision fundamental studies. Based on these achievements, we explore…

Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in…

Atomic Physics · Physics 2018-12-06 M. G. Kozlov , M. S. Safronova , J. R. Crespo López-Urrutia , P. O. Schmidt

Attempts are made to unify gravity with the other three fundamental forces of nature. As suggested by higher dimensional models, this unification may require space and time variation of some dimensionless fundamental constants. In this…

Atomic Physics · Physics 2023-02-15 Yan-Mei Yu , B. K. Sahoo , Bing-Bing Suo

We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

Optical clocks have garnered widespread attention due to their unparalleled precision in time-frequency standards, geodetic measurements, and fundamental physics research. Among emerging developments, highly charged ion (HCI)-based optical…

Atomic Physics · Physics 2025-04-29 Shaolong Chen , Zhiqiang Zhou , Guosheng Zhang , Jun Xiao , Yao Huang , Kelin Gao , Hua Guan

We examine energy level-crossings of fine-structure (FS) levels in the heavier highly charged ions (HCIs) with $d^6$ and $d^8$ configurations. From the analysis, we find that some of these HCIs are tailor-made for atomic clocks with quality…

Atomic Physics · Physics 2023-07-28 Yan-mei Yu , B. K. Sahoo

Highly charged ions (HCIs) are promising candidates for the next generation of atomic clocks, owing to their tightly bound electron cloud, which significantly suppresses the common environmental disturbances to the quantum oscillator. Here…

We propose here a few selective highly charged ions (HCIs), namely Ni$^{12+}$ and Cu$^{13+}$, Pd$^{12+}$ and Ag$^{13+}$, that not only promise to be very high accurate optical clocks below $10^{-19}$ uncertainties, but also offer quality…

Atomic Physics · Physics 2018-04-25 Yan-mei Yu , B. K. Sahoo

Highly charged ions (HCIs) combine compact electronic structure with strong relativistic effects, offering both robustness against external perturbations and enhanced sensitivity to variations of the fine-structure constant. Recent advances…

Atomic Physics · Physics 2026-02-17 S. G. Porsev , M. S. Safronova

An ultra-stable optical clock based on coherent population trapping effect of alkaline-earth ions, such as Ca$^+$, Sr$^+$, Ba$^+$, is analyzed here. The proposed transitions use the odd isotopes, so that the frequency shift is insensitive…

Optics · Physics 2009-04-03 Z. H. Lu , L. J. Wang

Recent theoretical works have proposed atomic clocks based on narrow optical transitions in highly charged ions. The most interesting candidates for searches of new physics are those which occur at rare orbital crossings where the shell…

Highly charged ions (HCIs) have drawn significant interest in quantum metrology and in search for new physics. Among these, Ni12+ is considered as one of the most promising candidates for the next generation of HCI optical clocks, due to…

Highly charged ions (HCIs) are insensitive to external perturbations and are attractive for the development of ultrastable clocks. However, only a few HCI candidates are known to provide optical clock transitions. In this Letter, we show…

Atomic Physics · Physics 2025-01-07 Chunhai Lyu , Christoph H. Keitel , Zoltán Harman

Precision spectroscopy of atomic systems is an invaluable tool for the advancement of our understanding of fundamental interactions and symmetries. Recently, highly charged ions (HCI) have been proposed for sensitive tests of physics beyond…

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Level crossings in the ground state of ions occur when the nuclear charge Z and ion charge Z_ion are varied along an isoelectronic sequence until the two outermost shells are nearly degenerate. We examine all available level crossings in…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

We review a number of highly charged ions which have optical transitions suitable for building extremely accurate atomic clocks. This includes ions from Hf$^{12+}$ to U$^{34+}$, which have the $4f^{12}$ configuration of valence electrons,…

Atomic Physics · Physics 2015-06-23 V. A. Dzuba , V. V. Flambaum

We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground $^{3}P_{J}$ fine structure manifold…

Atomic Physics · Physics 2022-10-06 Saleh O. Allehabi , S. M. Brewer , V. A. Dzuba , V. V. Flambaum , K. Beloy

We evaluate the feasibility of using magnetic-dipole (M1) transitions in highly-charged ions as a basis of an optical atomic clockwork of exceptional accuracy. We consider a range of possibilities, including M1 transitions between clock…

Atomic Physics · Physics 2015-06-23 V. I. Yudin , A. V. Taichenachev , A. Derevianko
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